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A complete set of spectroscopic data is indispensable when using Rydberg states of trapped ions for quantum information processing. We carried out Rydberg series spectroscopy for $nS_{1/2}$ states with $38 \leq n \leq 65$ and for $nD_{5/2}$…

Atomic Physics · Physics 2022-08-25 Justas Andrijauskas , Jonas Vogel , Arezoo Mokhberi , Ferdinand Schmidt-Kaler

We present absolute-frequency measurements for the transitions from the 6s$_{1/2}$ ground state of $^{133}$Cs to $n$p$_{1/2}$ and $n$p$_{3/2}$ Rydberg states. The transition frequencies are determined by one-photon UV spectroscopy in…

Resonant energy transfer between cold Rydberg atoms was used to determine Rydberg atom energy levels, at precisions approaching those obtainable in microwave spectroscopy. Laser cooled Rb atoms from a magneto-optical trap were optically…

Atomic Physics · Physics 2007-05-23 K. Afrousheh , P. Bohlouli-Zanjani , J. A. Petrus , J. D. D. Martin

We report new frequency-comb-based measurements of Ca Rydberg energy levels. Counter-propagating laser beams at 390 nm and 423 nm excite Ca atoms from the $4s^2~^1\mbox{S}_0$ ground state to $4sns~^1\mbox{S}_0$ Rydberg levels with $n$…

Atomic Physics · Physics 2023-01-04 Chanhyun Pak , Matthew J. Schlitters , Scott D. Bergeson

We make absolute frequency measurements of Cs Rydberg transitions, $\vert 6S_{1/2}, F=3 \rangle \rightarrow \vert nS_{1/2}~(n=23\rm{-}90)\rangle$ and $\vert nD_{3/2,5/2}~(n=21\rm{-}90)\rangle$, with an accuracy of less than $ 72\,\rm kHz$.…

We demonstrate excitation of a single trapped cold $^{40}$Ca$^+$ ion to Rydberg levels by laser radiation in the vacuum-ultraviolet at 122 nm wavelength. Observed resonances are identified as 3d$^2$D$_{3/2}$ to 51 F, 52 F and…

Quantum Physics · Physics 2015-10-28 T. Feldker , P. Bachor , M. Stappel , D. Kolbe , R. Gerritsma , J. Walz , F. Schmidt-Kaler

Ground state cooling and coherent manipulation of ions in an rf-(Paul) trap is the prerequisite for quantum information experiments with trapped ions. With resolved sideband cooling on the optical S1/2 - D5/2 quadrupole transition we have…

$^{133}\text{Ba}^+$ has been identified as an attractive ion for quantum information processing due to the unique combination of its spin-1/2 nucleus and visible wavelength electronic transitions. Using a microgram source of radioactive…

Quantum Physics · Physics 2017-09-13 David Hucul , Justin E. Christensen , Eric R. Hudson , Wesley C. Campbell

We present absolute-frequency measurements in ultracold 39K samples of the transitions from the ground state to np Rydberg states. A global nonlinear regression of the np1/2 and np3/2 term values yields an improved wave number of…

High precision variational calculations in Hylleraas coordinates are presented for all singlet and triplet $P$-states of helium up to principal quantum number $n = 35$ with a uniform accuracy of 1 part in $10^{22}$ for the nonrelativistic…

Atomic Physics · Physics 2025-10-27 G. W. F. Drake , Aaron T. Bondy , Oliver P. Hallett , Benjamin C. Najem

We present new measurements of quantum defects and core polarizabilities in cesium ($^{133}$Cs), based on transition frequency measurements between Rydberg states ($14 \leq n \leq 38$) obtained through terahertz (THz) and radio-frequency…

Atomic Physics · Physics 2025-06-03 Gianluca Allinson , Lucy A. Downes , Kevin J. Weatherill , C. Stuart Adams

We investigate single ions of $^{40}Ca^+$ in Paul traps for quantum information processing. Superpositions of the S$_{1/2}$ electronic ground state and the metastable D$_{5/2}$ state are used to implement a qubit. Laser light on the…

We report the measurement of the ionization energy of the $^{85}\text{Rb}_2$ molecule through resonantly enhanced 2-photon ionization in a supersonic beam. The first photon excites the $X^1\Sigma_g^+ (v_X = 0)\rightarrow B^1\Pi_u (v_B = 2)$…

We demonstrate the excitation of ions to the Rydberg state $22F$ by vacuum ultraviolet radiation at a wavelength of $123\,\text{nm}$ combined with the coherent manipulation of the optical qubit transition in $^{40}\text{Ca}^+$. With a…

Quantum Physics · Physics 2017-11-13 P. Bachor , T. Feldker , J. Walz , F. Schmidt-Kaler

We report the laser cooling of a single $^{40}\text{Ca}^+$ ion in a Penning trap to the motional ground state in one dimension. Cooling is performed in the strong binding limit on the 729-nm electric quadrupole $S_{1/2}\leftrightarrow…

Atomic Physics · Physics 2016-04-13 J. F. Goodwin , G. Stutter , R. C. Thompson , D. M. Segal

In this work, we precisely measure the transition energies between the Rydberg state n$\text{D}_{5/2}$ to the nearby Rydberg states $(\e{n}+2)\text{P}_{3/2}$, $(\e{n}-2)\text{F}_{7/2}$ for the range $41\leq \e{n}\leq46$. This was done by…

We demonstrate resolved sideband laser cooling of a single 40Ca+ ion in a macroscopic linear radio frequency trap with a radial diagonal electrode spacing of 7 mm and an rf drive frequency of just 3.7 MHz. For an oscillation frequency of…

Atomic Physics · Physics 2012-05-11 G. Poulsen , Y. Miroshnychenko , M. Drewsen

We present precise measurements of the quantum defects of cesium $n$F$_J$ Rydberg levels. We employ high-precision microwave spectroscopy of $(n+2)\mathrm{D}_{5/2}\rightarrow n\mathrm{F}_{5/2,7/2}$ transitions for $n=45$ to 50 in a…

Atomic Physics · Physics 2023-08-10 Jingxu Bai , Yuechun Jiao , Rong Song , Jiabei Fan , Jianming Zhao , Suotang Jia , Georg Raithe

Using optical Ramsey interferometry, we precisely measure the laser-induced AC-stark shift on the $S_{1/2}$ -- $D_{5/2}$ "quantum bit" transition near 729 nm in a single trapped $^{40}$Ca$^+$ ion. We cancel this shift using an additional…

Atomic Physics · Physics 2016-09-08 H. Haeffner , S. Gulde , M. Riebe , G. Lancaster , C. Becher , J. Eschner , F. Schmidt-Kaler , R. Blatt

We compute the Rydberg spectrum of a single Ca$^+$ ion in a Paul trap by incorporating various internal and external coupling terms of the ion to the trap in the Hamiltonian. The coupling terms include spin-orbit coupling in Ca$^+$, charge…

Atomic Physics · Physics 2020-05-29 Mariusz Pawlak , H. R. Sadeghpour
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