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We present a method for the calculation of electronic structure of systems that contain tens of thousands of atoms. The method is based on the division of the system into mutually overlapping fragments and the representation of the…

Materials Science · Physics 2011-03-09 Nenad Vukmirović , Lin-Wang Wang

Orbital-free density functional theory promises to deliver linear-scaling electronic structure calculations. This requires the knowledge of the non-interacting kinetic-energy density functional (KEDF), which should be accurate and must…

Materials Science · Physics 2024-12-12 Michael A. J. Mitchell , Teresa Del Aguila Ferrandis , Stefano Sanvito

The dimensionality of an electronic quantum system is decisive for its properties. In 1D electrons form a Luttinger liquid and in 2D they exhibit the quantum Hall effect. However, very little is known about the behavior of electrons in…

Mesoscale and Nanoscale Physics · Physics 2021-02-23 S. N. Kempkes , M. R. Slot , S. E. Freeney , S. J. M. Zevenhuizen , D. Vanmaekelbergh , I. Swart , C. Morais Smith

We formulate Wannier orbital overlap population and Wannier orbital Hamilton population to describe the contribution of different orbitals to electron distribution and their interactions. These methods, which are analogous to the well known…

Computational Physics · Physics 2021-03-31 Sudipta Kundu , Satadeep Bhattacharjee , Seung-Cheol Lee , Manish Jain

Conceiving a molecule as composed of smaller molecular fragments, or subunits, is one of the pillars of the chemical and physical sciences, and leads to productive methods in quantum chemistry. Using a fragmentation scheme, efficient…

Chemical Physics · Physics 2015-04-14 Martín A. Mosquera , Adam Wasserman

The one-particle reduced density-matrix (1-RDM) functional theory is a promising alternative to density-functional theory (DFT) that uses the 1-RDM rather than the electronic density as a basic variable. However, long-standing challenges…

Quantum Physics · Physics 2024-08-20 Matthieu Vladaj , Quentin Marécat , Bruno Senjean , Matthieu Saubanère

Modern nanotechnology allows producing, depending on application, various quantum nanostructures with the desired properties. These properties are strongly influenced by the confinement potential which can be modified, e.g., by electrical…

Mesoscale and Nanoscale Physics · Physics 2012-09-19 Elzbieta Zipper , Marcin Kurpas , Maciej M. Maska

Multiresolution analysis of electronic structure affords the opportunity to capture the full physics of atomic cores in a systematically improvable manner. Applying new techniques, we demonstrate for the first time that multiresolution…

Condensed Matter · Physics 2009-11-07 Torkel D. Engeness , T. A. Arias

An effective operational approach to quantum mechanics is to focus on the evolution of wave-packets, for which the wave-function can be seen in the semi-classical regime as representing a classical motion dressed with extra degrees of…

Quantum Physics · Physics 2023-08-23 Etera R. Livine

Quantum phase is not a direct observable and is usually determined by interferometric methods. We present a method to map complete electron wave functions, including internal quantum phase information, from measured single-state probability…

Mesoscale and Nanoscale Physics · Physics 2008-03-19 Christopher R. Moon , Laila S. Mattos , Brian K. Foster , Gabriel Zeltzer , Wonhee Ko , Hari C. Manoharan

Scattering of electromagnetic waves by many small particles of arbitrary shapes is reduced rigorously to solving linear algebraic system of equations bypassing the usual usage of integral equations. The matrix elements of this linear…

Mathematical Physics · Physics 2009-11-11 A. G. Ramm

In this paper, we propose an orbital iteration based parallel approach for electronic structure calculations. This approach is based on our understanding of the single-particle equations of independent particles that move in an effective…

Numerical Analysis · Mathematics 2014-11-06 Xiaoying Dai , Xingao Gong , Aihui Zhou , Jinwei Zhu

We propose a physically based analytical compact model to calculate Eigen energies and Wave functions which incorporates penetration effect. The model is applicable for a quantum well structure that frequently appears in modern nano-scale…

We present a plane wave/pseudopotential implementation of the method to calculate electron transport properties of nanostructures. The conductance is calculated via the Landauer formula within formalism of Green's functions. Nonorthogonal…

Materials Science · Physics 2009-11-11 Zhenyu Li , D. S. Kosov

We establish necessary and sufficient conditions for the N-representability of the universal one-electron reduced density matrix functional. Functionals satisfying these conditions are guaranteed to yield variational upper bounds on the…

Quantum Physics · Physics 2026-04-08 Jannis Erhard , Paul W. Ayers

We devise a nonlocal correlation energy functional that describes the entire range of dispersion interactions in a seamless fashion using only the electron density as input. The new functional is considerably simpler than its predecessors…

Chemical Physics · Physics 2010-12-27 Oleg A. Vydrov , Troy Van Voorhis

Electron correlations in molecules can be divided in short range dynamical correlations, long range Van der Waals type interactions and near degeneracy static correlations. In this work we analyze for a one-dimensional model of a…

Chemical Physics · Physics 2014-05-13 K. J. H. Giesbertz , R. van Leeuwen

Representation learning for the electronic structure problem is a major challenge of machine learning in computational condensed matter and materials physics. Within quantum mechanical first principles approaches, Kohn-Sham density…

Materials Science · Physics 2024-04-24 Bowen Hou , Jinyuan Wu , Diana Y. Qiu

We present a method for total energy minimizations and molecular dynamics simulations based either on tight-binding or on Kohn-Sham hamiltonians. The method leads to an algorithm whose computational cost scales linearly with the system…

Condensed Matter · Physics 2009-10-22 Francesco Mauri , Giulia Galli

The projection of the eigenfunctions obtained in standard plane-wave first-principle electronic-structure calculations into atomic-orbital basis sets is proposed as a formal and practical link between the methods based on plane waves and…

Condensed Matter · Physics 2009-10-28 Daniel Sanchez-Portal , Emilio Artacho , Jose M. Soler