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A general procedure for the optimization of atomic density-fitting basis functions is designed with the balance between accuracy and numerical stability in mind. Given one-electron wavefunctions and energies, weights are assigned to the…

Chemical Physics · Physics 2020-10-13 Dimitri N. Laikov

The last several decades have seen significant advances in the theoretical modeling of materials within the fields of solid-state physics and materials science, but many methods commonly applied to this problem struggle to capture strong…

Strongly Correlated Electrons · Physics 2025-04-07 Anna O. Schouten , Simon Ewing , David A. Mazziotti

We provide a simple scheme for predicting the electronic structure of van-der-Waals bound systems, based on the mere knowledge of the electronic structure of the subunits. We demonstrate this with the example of nano-peapods, consisting of…

Materials Science · Physics 2013-01-21 Matus Milko , Peter Puschnig , Claudia Draxl

Wannier functions that are maximally localized help in understanding many properties of crystalline materials. In the absence of topological obstructions, they are at least exponentially localized. In some cases such as flat-band…

Mesoscale and Nanoscale Physics · Physics 2021-07-30 Pratik Sathe , Fenner Harper , Rahul Roy

We introduce a highly-parallelizable architecture for estimating parameters of compact binary coalescence using gravitational-wave data and waveform models. Using a spherical harmonic mode decomposition, the waveform is expressed as a sum…

General Relativity and Quantum Cosmology · Physics 2015-08-06 C. Pankow , P. Brady , E. Ochsner , R. O'Shaughnessy

The accuracy of a single s-orbital representation of Cu towards enabling multi-thousand atom ab initio calculations of electronic structure is evaluated in this work. If an electrostatic compensation charge of approximately 0.3 electrons…

Materials Science · Physics 2015-09-04 Ganesh Hegde , R. Chris Bowen

We give exact formulae for a wide family of complexity measures that capture the organization of hidden nonlinear processes. The spectral decomposition of operator-valued functions leads to closed-form expressions involving the full…

Statistical Mechanics · Physics 2013-09-17 James P. Crutchfield , Christopher J. Ellison , Paul M. Riechers

We discuss a method for determining the optimally-localized set of generalized Wannier functions associated with a set of Bloch bands in a crystalline solid. By ``generalized Wannier functions'' we mean a set of localized orthonormal…

Materials Science · Physics 2009-10-30 Nicola Marzari , David Vanderbilt

As the study of three-hadron physics from lattice QCD matures, it is necessary to develop proper analysis tools in order to reliably study a variety of phenomena, including resonance spectroscopy and nuclear structure. Reconstructing the…

High Energy Physics - Phenomenology · Physics 2023-12-04 Andrew W. Jackura , Raúl A. Briceño

We present the Unit Region Encoding of floorplans, which is a unified and compact geometry-aware encoding representation for various applications, ranging from interior space planning, floorplan metric learning to floorplan generation…

Computer Vision and Pattern Recognition · Computer Science 2025-01-22 Huichao Zhang , Pengyu Wang , Manyi Li , Zuojun Li , Yaguang Wu

We derive an analytical expression for the scattering of a scalar wave from a perfectly conducting self-affine one dimensional surface in the framework of the Kirchhoff approximation. We show that most of the results can be recovered via a…

Other Condensed Matter · Physics 2009-11-10 Ingve Simonsen , Damien Vandembroucq , Stephane Roux

Our paper [Phys. Rev. A 93, 052512 (2016)], proposing a novel form of single determinant wave function that admits non-idempotent 1-electron density matrices, has recently received a Comment [Phys. Rev. A ??, 0????? (2017)] suggesting a…

Chemical Physics · Physics 2017-08-22 Hubertus J. J. van Dam

A new reference state for density functional theory, termed the independent atom ansatz, is introduced in this work. This ansatz allows for the exact representation of electron density in terms of non-interacting, atom-localized orbitals.…

Chemical Physics · Physics 2024-05-03 Alexander V. Mironenko

The wave function of a composite system is defined in relativity on a space-time surface. In the explicitly covariant light-front dynamics, reviewed in the present article, the wave functions are defined on the plane $\omega \cd x=0$, where…

Nuclear Theory · Physics 2011-07-19 J. Carbonell , B. Desplanques , V. A. Karmanov , J. -F. Mathiot

We generalize the treatment of the electronic spin degrees of freedom in density functional calculations to the case where the spin vector variables employed in the definition of the energy functional can vary in any direction in space. The…

Other Condensed Matter · Physics 2007-05-23 Juan E. Peralta , Gustavo E. Scuseria , Michael J. Frisch

Kinetic energy functionals of the electronic density are used to model large systems in the context of density functional theory, without the need to obtain electronic wavefunctions. We discuss the problems associated with the application…

Condensed Matter · Physics 2009-11-07 Nicholas Choly , Efthimios Kaxiras

While analytic calculations may give access to complex-valued electromagnetic field data which allow trivial access to envelope and phase information, the majority of numeric codes uses a real-valued represantation. This typically increases…

Plasma Physics · Physics 2019-03-07 Alexander Blinne , Stephan Kuschel , Stefan Tietze , Matt Zepf

In this work we investigate the Wigner localization of two interacting electrons at very low density in two and three dimensions using the exact diagonalization of the many-body Hamiltonian. We use our recently developed method based on…

Strongly Correlated Electrons · Physics 2021-10-13 Miguel Escobar Azor , Estefania Alves , Stefano Evangelisti , J. Arjan Berger

Deep neural networks have become a highly accurate and powerful wavefunction ansatz in combination with variational Monte Carlo methods for solving the electronic Schr\"odinger equation. However, despite their success and favorable scaling,…

Computational Physics · Physics 2023-03-20 Michael Scherbela , Leon Gerard , Philipp Grohs

Molecular electronic spectra can be represented in the time domain as auto-correlation functions of the initial vibrational wavepacket. We present a derivation of the harmonic vibrational auto-correlation function that is valid for both…

Chemical Physics · Physics 2022-10-05 P. Bryan Changala , Nadav Genossar , Joshua H. Baraban
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