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The fundamental quantity governing the mechanical and thermodynamic properties of a crystalline solid is its electronic charge density. Yet, its direct use for the rapid prediction of materials properties remains challenging due to its high…

Materials Science · Physics 2026-05-11 Kammampati Sai Kumar , Albert Linda , Shubham Kumar Maurya , Somnath Bhowmick

We present an efficient and accurate implementation of hybrid exchange-correlation (XC) functionals in the SIESTA code, enabling large-scale simulations based on Hartree-Fock-type exact exchange combined with strictly localized numerical…

We outline the general framework of machine learning (ML) methods for multi-scale dynamical modeling of condensed matter systems, and in particular of strongly correlated electron models. Complex spatial temporal behaviors in these systems…

Strongly Correlated Electrons · Physics 2022-01-06 Puhan Zhang , Sheng Zhang , Gia-Wei Chern

The construction of meta generalized gradient approximations based on the density matrix expansion (DME) is considered as one of the most accurate technique to design semilocal exchange energy functionals in two-dimensional density…

Materials Science · Physics 2018-05-09 Abhilash Patra , Subrata Jana , Prasanjit Samal

Most torsional barriers are predicted to high accuracy (about 1kJ/mol) by standard semilocal functionals, but a small subset has been found to have much larger errors. We create a database of almost 300 carbon-carbon torsional barriers,…

Chemical Physics · Physics 2021-02-16 Seungsoo Nam , Eunbyol Cho , Kieron Burke , Eunji Sim

Hohenberg and Kohn have proven that the electronic energy and the one-particle electron density can, in principle, be obtained by minimizing an energy functional with respect to the density. While decades of theoretical work have produced…

Deep convolutional neural networks achieve remarkable visual recognition performance, at the cost of high computational complexity. In this paper, we have a new design of efficient convolutional layers based on three schemes. The 3D…

Computer Vision and Pattern Recognition · Computer Science 2017-01-25 Min Wang , Baoyuan Liu , Hassan Foroosh

Mapping an atomistic configuration to an $N$-point correlation of a field associated with the atomic positions (e.g. an atomic density) has emerged as an elegant and effective solution to represent structures as the input of…

Chemical Physics · Physics 2020-10-07 Jigyasa Nigam , Sergey Pozdnyakov , Michele Ceriotti

Electron charge density distribution of materials is one of the key quantities in computational materials science as theoretically it determines the ground state energy and practically it is used in many materials analyses. However, the…

Computational Physics · Physics 2019-11-13 Sheng Gong , Tian Xie , Taishan Zhu , Shuo Wang , Eric R. Fadel , Yawei Li , Jeffrey C. Grossman

In the present study, the capabilities of a new Convolutional Neural Network (CNN) model are explored with the paramount objective of reconstructing the temperature field of wall-bounded flows based on a limited set of measurement points…

Fluid Dynamics · Physics 2022-02-02 Victor Coppo Leite , Elia Merzari , Roberto Ponciroli , Lander Ibarra

We present first empirical results from our ongoing investigation of distribution shifts in image data used for various computer vision tasks. Instead of analyzing the original training and test data, we propose to study shifts in the…

Computer Vision and Pattern Recognition · Computer Science 2022-01-24 Paul Gavrikov , Janis Keuper

Fractional occupation numbers can be used in density functional theory to create a symmetric Kohn-Sham potential, resulting in orbitals with degenerate eigenvalues. We develop the corresponding perturbation theory and apply it to a system…

Materials Science · Physics 2016-09-09 Mark C. Palenik , Brett I. Dunlap

Machine-learned potentials (MLPs) trained on ab initio data combine the computational efficiency of classical interatomic potentials with the accuracy and generality of the first-principles method used in the creation of the respective…

Chemical Physics · Physics 2024-08-07 Leonid Kahle , Benoit Minisini , Tai Bui , Jeremy T. First , Corneliu Buda , Thomas Goldman , Erich Wimmer

Double hybrid (DH) density functionals are amongst the most accurate density functional approximations developed so far, largely due to incorporation of correlation effects from unoccupied orbitals via second order perturbation theory…

Chemical Physics · Physics 2018-05-07 Diptarka Hait , Martin Head-Gordon

A semi-relativistic density-functional theory that includes spin-orbit couplings and Zeeman fields on equal footing with the electromagnetic potentials, is an appealing framework to develop a unified first-principles computational approach…

Materials Science · Physics 2017-09-13 S. Pittalis , G. Vignale , F. G. Eich

We present the idea and illustrate potential benefits of having a tool chain of closely related regular, unscreened and screened hybrid exchange-correlation (XC) functionals, all within the consistent formulation of the van der Waals…

Existing ultrasound deconvolution approaches unrealistically assume, primarily for computational reasons, that the convolution model relies on a spatially invariant kernel and circulant boundary conditions. We discard both restrictions and…

Signal Processing · Electrical Eng. & Systems 2021-09-21 Mihai I. Florea , Adrian Basarab , Denis Kouamé , Sergiy A. Vorobyov

Deep learning has achieved remarkable success in processing and managing unstructured data. However, its "black box" nature imposes significant limitations, particularly in sensitive application domains. While existing interpretable machine…

Machine Learning · Computer Science 2025-02-11 Wen-Dong Jiang , Chih-Yung Chang , Show-Jane Yen , Diptendu Sinha Roy

In this work we have studied a new functional for the correlation energy obtained from the exact-exchange (EXX) approximation within time-dependent density functional theory (TDDFT). Correlation energies have been calculated for a number of…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 Maria Hellgren , Ulf von Barth

A central pursuit in theoretical chemistry is the accurate simulation of photochemical reactions, which are governed by nonadiabatic transitions through conical intersections. Machine learning has emerged as a transformative tool for…