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The electrocaloric (EC) effect offers a promising energy-efficient and clean cooling technology. We present the first direct measurements of EC temperature change in a new family of EC fluids, ferroelectric nematic liquid crystals (FNLCs),…

Giant electrocaloric (EC) effect is observed in BaTiO3 multilayer thick film structure. The temperature change is as high as 4.0 oC under an applied electric field of 352 kV/cm. Most importantly, the EC effect is found to depend on the…

Materials Science · Physics 2015-05-18 Yang Bai , Guang-Ping Zheng , San-Qiang Shi

Solid-state cooling applications based on the electrocaloric (EC) effect are particularly promising from a technological point of view due to their downsize scalability and natural implementation in circuitry. However, EC effects typically…

Materials Science · Physics 2023-07-19 César Menéndez , Claudio Cazorla

An applied electric field can reversibly change the temperature of an electrocaloric material under adiabatic conditions, and the effect is strongest near phase transitions. This phenomenon has been largely ignored because only small…

Materials Science · Physics 2009-11-11 A. Mischenko , Q. Zhang , J. F. Scott , R. W. Whatmore , N. D. Mathur

The electrocaloric effect (ECE) offers a promising alternative to the traditional gas compressing refrigeration due to its high efficiency and environmental friendliness. The unusual negative electrocaloric effect refers to the adiabatic…

Materials Science · Physics 2023-07-14 Xingyue Ma , Mingxing Chen , Jun-Ming Liu , Di Wu , Yurong Yang

The electrocaloric (EC) effect is the reversible change in temperature and/or entropy of a material when it is subjected to an adiabatic electric field change. Our tight-binding calculations linked to Fermi statistics, show that the EC…

Mesoscale and Nanoscale Physics · Physics 2021-01-11 Natalia Cortés , Oscar Negrete , Francisco J. Peña , Patricio Vargas

Electrocaloric (EC) materials show promise in eco-friendly solid-state refrigeration and integrable on-chip thermal management. While direct measurement of EC thin-films still remains challenging, a generic theoretical framework for…

Materials Science · Physics 2021-04-21 Yuping Shi , Limin Huang , Ai Kah Soh , George J. Weng , Shuangyi Liu , Simon A. T. Redfern

Recent findings of a large electrocaloric (EC) effect in polymeric and inorganic ferroelectric materials open a potential possibility of development of solid-state cooling or heating devices of new generation with better energy efficiency…

CuInP2S6 (CIPS) is an emerging layered material that exhibits ferrielectric ordering well above room temperature (Curie temperature TC ~ 315 K). When synthesized with Cu deficiencies, CIPS spontaneously segregates into CuInP2S6 and…

Materials Science · Physics 2021-11-02 Rahul Rao , Ryan Selhorst , Benjamin S. Conner , Michael A. Susner

Using the previously developed model we study the electrocaloric effect (ECE) in antiferroelectric crystals of squaric acid. At low temperatures, the polarization reorientation by the electric field applied along the crystallographic $a$…

Materials Science · Physics 2023-03-15 A. P. Moina

The electrocaloric effect refers to the temperature change in a material when an electric field is applied or removed. Significant breakthroughs revealed its potential for solid-state cooling technologies in past decades. These devices…

Mesoscale and Nanoscale Physics · Physics 2025-04-10 Jean Spièce , Valentin Fonck , Charalambos Evangeli , Phil S. Dobson , Jonathan M. R. Weaver , Pascal Gehring

The electrocaloric (EC) effect and energy storage properties of eco-friendly ferroelectric Ba0.9Sr0.1Ti1-xSnxO3 (BSTS-x) ceramics prepared by the conventional solid-state reaction method were studied. Significant energy efficiency exceeding…

The electrocaloric effect (ECE) in normal and relaxor ferroelectrics is investigated in the framework of a thermodynamic approach based on the Maxwell relation and a Landau-type free energy model. The static dielectric response of relaxors…

Disordered Systems and Neural Networks · Physics 2015-05-20 R. Pirc , Z. Kutnjak , R. Blinc , Q. M. Zhang

We show that the electrocaloric (EC) effect -- e.g., the temperature change experienced by an insulator upon application of an electric bias -- lends itself to a straightforward interpretation when expressed as a Taylor series in the…

Materials Science · Physics 2020-12-09 Mónica Graf , Jorge Íñiguez

Ferroelectrics are attractive candidate materials for environmentally friendly solid state refrigeration free of greenhouse gases. Their thermal response upon variations of external electric fields is largest in the vicinity of their phase…

Materials Science · Physics 2016-05-20 G. G. Guzmán-Verri , P. B. Littlewood

The electrocaloric effect (ECE), i.e., the reversible temperature change due to the adiabatic variation of the electric field, is of great interest due to its potential technological applications. Based on entropy arguments, we present a…

Materials Science · Physics 2023-04-28 Lucas Squillante , Isys F. Mello , A. C. Seridonio , Mariano de Souza

We have recently observed a giant electrocaloric effect (12 K in 25 V) in 350 nm sol-gel Pb Zr_0.95 Ti_0.05 O_3 films near the ferroelectric Curie temperature of 242oC. Here we demonstrate a giant electrocaloric effect (5 K in 25 V) in 260…

Materials Science · Physics 2009-11-11 A. S. Mischenko , Q. Zhang , R. W. Whatmore , N. D. Mathur

The coexistence of multiple structural phases and field induced short-range to long-range order transition in ferroelectric materials, leads to a strong electrocaloric effect (ECE) and electrical energy storage density (Wrec) in the…

Perovskite-type Ba0.9Sr0.1Ti0.9Sn0.1O3(BSTSn) ceramic was synthesized by the sol gel method. The P E hysteresis loops were recorded at different temperatures to investigate the ferroelectric and energy storage properties of BSTSn ceramic.…

Materials Science · Physics 2023-06-13 S. Khardazi , H. Zaitouni , S. Belkhadir , D. Mezzane , M. Amjoud , Y. Gagou , B. Asbani , I. Lukyanchuk , S. Terenchuk

There is a surge of interest in developing environmentally friendly cooling technology based on the solid--state electrocaloric effect (ECE). Here, we point out that negative ECE with a fast cooling rate ($\approx$10$^{11}$ K/s) can be…

Materials Science · Physics 2018-02-07 Yubo Qi , Shi Liu , Aaron M. Lindenberg , Andrew M. Rappe
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