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Two-photon absorption (TPA) and other nonlinear interactions of molecules with time-frequency-entangled photon pairs (EPP) has been predicted to display a variety of fascinating effects. Therefore, their potential use in practical…

Quantum Physics · Physics 2021-09-15 Michael G. Raymer , Tiemo Landes , Andrew H. Marcus

When a low flux of time-frequency-entangled photon pairs (EPP) illuminates a two-photon transition, the rate of two-photon absorption (TPA) can be enhanced considerably by the quantum nature of photon number correlations and frequency…

Recent investigations suggest that the use of non-classical states of light, such as entangled photon pairs, may open new and exciting avenues in experimental two-photon absorption spectroscopy. Despite several experimental studies of…

Entangled two-photon absorption (eTPA) has been recognized as a potentially powerful tool for the implementation of ultra-sensitive spectroscopy. Unfortunately, there exists a general agreement in the quantum optics community that…

Quantum Physics · Physics 2025-01-31 Áulide Martínez-Tapia , Roberto de J. León-Montiel

Nonlinear spectroscopy and microscopy techniques are ubiquitous in a wide range of applications across physics and biology. However, these usually rely on high-powered pulsed laser systems. A promising alternative is to exploit entangled…

Over the last 50 years entangled photon pairs have received attention for use in lowering the flux in two-photon absorption imaging and spectroscopy. Despite this, evidence for entangled two-photon absorption (ETPA) effects remain highly…

In virtual-state spectroscopy, information about the energy-level structure of an arbitrary sample is retrieved by Fourier transforming sets of measured two-photon absorption probabilities of entangled photon pairs where the degree of…

Quantum Physics · Physics 2021-08-04 Lutz Mertenskötter , Kurt Busch , Roberto de J. León-Montiel

While two-photon absorption (TPA) and other forms of nonlinear interactions of molecules with isolated time-frequency-entangled photon pairs (EPP) have been predicted to display a variety of fascinating effects, their potential use in…

Entangled two-photon absorption (ETPA) may be a viable technique to continuously drive an excited state population in plasma for high-bandwidth spectroscopy measurements of localized plasma turbulence or impurity density. Classical…

We introduce a method for determining the sensitivity of any given Entangled Two-Photon Absorption (ETPA) measurement. By modeling all signal and noise contributions to the measurement, we derive a single numerical value that describes the…

Quantum Physics · Physics 2025-12-23 René Pollmann , Franz Roeder , Christine Silberhorn , Benjamin Brecht

We discuss how two-photon absorption (TPA) of squeezed and coherent states of light can be detected in measurements of the transmitted light fields. Such measurements typically suffer from competing loss mechanisms such as experimental…

Quantum Physics · Physics 2022-05-24 Shahram Panahiyan , Carlos Sánchez Muñoz , Maria V. Chekhova , Frank Schlawin

It is well known that energy-time entanglement can enhance two photon absorption (TPA) by simultaneously optimizing the two photon resonance and the coincidence rate of photons at the absorber. However, the precise relation between…

Quantum Physics · Physics 2021-08-31 Baihong Li , Holger F. Hofmann

The phenomenon of Entangled Two-Photon Absorption (ETPA) presents a persistent controversy in the literature, evidenced by a wide disparity in the reported values for the $\sigma_E$ cross-sections. Much of this discrepancy is attributed to…

Quantum Physics · Physics 2025-12-02 Pablo Yepiz-Graciano , Gabriel Ramos-Ortiz , Roberto Ramírez-Alarcón

We numerically analyze the use of intense entangled twin beams for ultra-sensitive spectroscopic measurements in chemical and biological systems. The examined scheme makes use of intense frequency-modulated (chirped) entangled beams to…

Quantum Physics · Physics 2018-05-16 Jiří Svozilík , Jan Peřina , Roberto de J. León-Montiel

We experimentally demonstrate two-photon absorption (TPA) with broadband down-converted light (squeezed vacuum). Although incoherent and exhibiting the statistics of a thermal noise, broadband down-converted light can induce TPA with the…

Quantum Physics · Physics 2011-12-06 Barak Dayan , Avi Pe'er , Asher A. Friesem , Yaron Silberberg

Broadband energy-time entanglement can be used to enhance the rate of two-photon absorption (TPA) by combining a precise two-photon resonance with a very short coincidence time. Because of this short coincidence time, broadband TPA is not…

Quantum Physics · Physics 2023-12-04 Baihong Li , Holger F. Hofmann

Entangled two-photon absorption can enable a linear scaling of fluorescence emission with the excitation power. In comparison to classical two-photon absorption with a quadratic scaling, this can allow fluorescence imaging or…

Two-photon excited fluorescence (TPEF) is a standard technique in modern microscopy but still affected by photo-damage of the probe. It was proposed that TPEF can be enhanced by using entangled photons, but has proven to be challenging.…

Quantum Physics · Physics 2013-10-17 Andreas Jechow , Michael Seefeldt , Henning Kurzke , Axel Heuer , Ralf Menzel

Recently, different experimental methods to investigate the entangled two-photon absorption (ETPA) process in a variety of materials have been reported. The present work reports on a different approach on which the ETPA process is detected…

Quantum Physics · Physics 2022-02-15 Freiman Triana-Arango , Gabriel Ramos-Ortiz , Roberto Ramírez-Alarcón

We present an analytical quantum theoretic model for non-resonant molecular two-photon absorption (TPA) of broadband, spectrally multi-mode squeezed vacuum, including low-gain (isolated entangled photon pairs or EPP) and high-gain (bright…

Quantum Physics · Physics 2022-08-10 Michael G. Raymer , Tiemo Landes
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