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Bulk black phosphorus (BP) consists of puckered layers of phosphorus atoms. Few-layer BP, obtained from bulk BP by exfoliation, is an emerging candidate as a channel material in post-silicon electronics. A deep understanding of its physical…

We report on experimental demonstration of a new type of nanoelectromechanical resonators based on black phosphorus crystals. Facilitated by a highly efficient dry transfer technique, crystalline black phosphorus flakes are harnessed to…

Mesoscale and Nanoscale Physics · Physics 2015-04-07 Zenghui Wang , Hao Jia , Xuqian Zheng , Rui Yang , Zefang Wang , G. J. Ye , X. H. Chen , Jie Shan , Philip X. -L. Feng

The liquid-phase exfoliation (LPE) of black phosphorus (BP) is a strategic route for the large-scale production of phosphorene and few-layer BP (FL-BP) flakes. The exploitation of this exfoliated material in cutting-edge technologies, e.g.,…

Recently rediscovered black phosphorus is a layered semiconductor with promising electronic and photonic properties. Dynamic control of its bandgap can enable novel device applications and allow for the exploration of new physical…

Mesoscale and Nanoscale Physics · Physics 2017-04-21 Bingchen Deng , Vy Tran , Hao Jiang , Cheng Li , Yujun Xie , Qiushi Guo , Xiaomu Wang , He Tian , Han Wang , Judy J. Cha , Qiangfei Xia , Li Yang , Fengnian Xia

Black phosphorus is an infrared layered material. Its bandgap complements other widely studied two-dimensional materials: zero-gap graphene and visible/near-infrared gap transition metal dichalcogenides. Though highly desirable, a…

Mesoscale and Nanoscale Physics · Physics 2017-02-07 Guowei Zhang , Shenyang Huang , Andrey Chaves , Chaoyu Song , V. Ongun Özçelik , Tony Low , Hugen Yan

Few-layer and thin film forms of layered black phosphorus (BP) have recently emerged as a promising material for applications in high performance nanoelectronics and infrared optoelectronics. Layered BP thin film offers a moderate bandgap…

Mesoscale and Nanoscale Physics · Physics 2014-11-17 Han Wang , Xiaomu Wang , Fengnian Xia , Luhao Wang , Hao Jiang , Qiangfei Xia , Matthew L. Chin , Madan Dubey , Shu-jen Han

Black phosphorus is a very promising material for telecommunication due to its direct bandgap and strong resonant absorption in near-infrared wavelength range. However, ultrafast nonlinear photonic applications relying on the ultrafast…

The electronic structure and functionality of 2D materials is highly sensitive to structural morphology, opening the possibility for manipulating material properties, but also making predictable and reproducible functionality challenging.…

Mesoscale and Nanoscale Physics · Physics 2022-10-26 Prakriti P. Joshi , Ruiyu Li , Joseph L. Spellberg , Liangbo Liang , Sarah B. King

The interlayer breathing and shear modes in few-layer black phosphorus are investigated for their symmetry and lattice dynamical properties. The symmetry groups for the even-layer and odd-layer few-layer black phosphorus are utilized to…

Materials Science · Physics 2014-12-25 Jin-Wu Jiang , Bing-Shen Wang , Harold S. Park

The ease of integration coupled with large second-order nonlinear coefficient of atomically thin layered 2D materials presents a unique opportunity to realize second-order nonlinearity in silicon compatible integrated photonic system.…

Optics · Physics 2017-10-11 Taylor Fryett , Alan Zhan , Arka Majumdar

Two-dimensional crystals have emerged as a new class of materials with novel properties that may impact future technologies. Experimentally identifying and characterizing new functional two-dimensional materials in the vast material pool is…

Materials Science · Physics 2015-06-18 Likai Li , Yijun Yu , Guo Jun Ye , Qingqin Ge , Xuedong Ou , Hua Wu , Donglai Feng , Xian Hui Chen , Yuanbo Zhang

Black phosphorus (BP), an emerging two-dimensional (2D) material with intriguing optical properties, forms a promising building block in optics and photonics devices. In this work, we propose a simple structure composed of BP sandwiched by…

Optics · Physics 2019-09-18 Tingting Liu , Xiaoyun Jiang , Chaobiao Zhou , Shuyuan Xiao

Black phosphorus (BP) is a two-dimensional layered material composed of phosphorus atoms. Recently, it was demonstrated that external perturbations such as an electric field close the band gap in few-layer BP, and can even induce a band…

Mesoscale and Nanoscale Physics · Physics 2019-03-11 Jiho Jang , Seongjin Ahn , Hongki Min

Analyzing porous (nano)materials by the atom probe tomography has been notoriously difficult. The electrostatic pressure intensifies stress at voids which results in premature failure of the specimen, and the electrostatic field…

Materials Science · Physics 2022-07-27 Se-Ho Kim , Ayman A. El-Zoka , Baptiste Gault

Polystyrene-based phosphorene nanocomposites were prepared by a solvent blending procedure allowing the embedding of black phosphorus (BP) nanoflakes in the polymer matrix. Raman spectroscopy, X Ray Diffraction and TEM microscopy were…

Introducing hierarchical pore structure to microporous materials such as metal-organic frameworks (MOFs) can be beneficial for reactions where the rate of reaction is limited by low rates of diffusion or high pressure drop. This…

Materials Science · Physics 2019-04-25 Huan V. Doan , Asel Sartbaeva , Jean-Charles Eloi , Sean Davis , Valeska P. Ting

Wet etching is an essential and complex step in semiconductor device processing. Metal-Assisted Chemical Etching (MacEtch) is fundamentally a wet but anisotropic etching method. In the MacEtch technique, there are still a number of…

Applied Physics · Physics 2017-06-26 Lucia Romano , Joan Vila-Comamalab , Konstantins Jefimovs , Marco Stampanoni

Atomically thin black phosphorus (BP) is a promising two-dimensional material for fabricating electronic and optoelectronic nano-devices with high mobility and tunable bandgap structures. However, the charge-carrier mobility in few-layer…

Nanophotonic devices with moir\'e superlattice is currently attracting broad interest due to the unique periodicity and high efficiency control of photons. Till now, experimental investigations mainly focus on the single layer device, i.e.,…

Optics · Physics 2025-03-07 Qing Wang , Yuhang Li , Shaofeng Wang , Shuo Cao , Xiulai Xu , Chenjiang Qian

The integration of van der Waals (vdW) materials into photonic devices has laid out a foundation for many new quantum and optoelectronic applications. Despite tremendous progress in the nanofabrication of photonic building blocks from vdW…