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In this paper, we provide a graphic formulation of non-isothermal reaction systems and show that a non-isothermal detailed balanced network system converges (locally) asymptotically to the unique equilibrium within the invariant manifold…

Dynamical Systems · Mathematics 2020-10-01 Zhou Fang , Arjan van der Schaft , Chuanhou Gao

It is essential that mesoscopic simulations of reactive systems reproduce the correct statistical distributions at thermodynamic equilibrium. By considering a compressible fluctuating hydrodynamics (FHD) simulation method of ideal gas…

We consider viscous, heat conducting mixtures of molecularly miscible chemical species forming a fluid in which the constituents can undergo chemical reactions. Assuming a common temperature for all components, we derive a closed system of…

Fluid Dynamics · Physics 2016-04-01 Dieter Bothe , Wolfgang Dreyer

Relevant and fundamental concepts of the statistical mechanical theory of classical liquids are ordinarily introduced in the context of the description of thermodynamic equilibrium states. This makes explicit reference to probability…

Statistical Mechanics · Physics 2024-01-30 O. Joaquín-Jaime , R. Peredo-Ortiz , M. Medina-Noyola , L. F. Elizondo-Aguilera

According to contemporary views, equilibrium constant is relevant only to true thermodynamic equilibria in isolated systems with one chemical reaction. The paper presents a novel formula that ties-up equilibrium constant and chemical system…

Chemical Physics · Physics 2008-02-11 B. Zilbergleyt

The question of characterization of the degree of non-equilibrium activity in active matter systems is studied in the context of a stochastic microswimmer model driven by a chemical cycle. The resulting dynamical properties and entropy…

Statistical Mechanics · Physics 2024-05-27 Michalis Chatzittofi , Jaime Agudo-Canalejo , Ramin Golestanian

The toy model of a particle on a vertical rotating circle in the presence of uniform gravitational/ magnetic fields is explored in detail. After an analysis of the classical mechanics of the problem we then discuss the quantum mechanics…

Quantum Physics · Physics 2009-10-31 Sayan Kar , Avinash Khare

The measurement and interpretation of isotopic yield ratios in heavy ion reactions at intermediate and high energies are discussed and the usefulness of these observables for establishing equilibrium properties and for determining…

Nuclear Experiment · Physics 2007-05-23 J. Pochodzalla , W. Trautmann

We consider the problem of constructing a thermodynamic theory of non-equilibrium steady states as a formal extension of the equilibrium theory. Specifically, studying a particular system, we attempt to construct a phenomenological theory…

Statistical Mechanics · Physics 2009-06-11 Glenn C. Paquette

We report the complete statistical treatment of a system of particles interacting via Newtonian forces in continuous boundary-driven flow, far from equilibrium. By numerically time-stepping the force-balance equations of a model fluid we…

Statistical Mechanics · Physics 2015-05-14 R. M. L. Evans , R. A. Simha , A. Baule , P. D. Olmsted

Information is physical, and for a physical theory to be universal, it should model observers as physical systems, with concrete memories where they store the information acquired through experiments and reasoning. Here we address these…

Quantum Physics · Physics 2023-02-15 Ladina Hausmann , Nuriya Nurgalieva , Lídia del Rio

In ultra-relativistic heavy-ion collisions a strongly interacting complex system of quarks and gluons is formed. The nature of the system so created and the mechanism of multi-particle production in these collisions may be revealed by…

High Energy Physics - Phenomenology · Physics 2023-10-18 Sheetal Sharma , Salman Khurshid Malik , Zarina Banoo , Ramni Gupta

Focusing on isolated macroscopic systems, described either in terms of a quantum mechanical or a classical model, our two key questions are: In how far does an initial ensemble (usually far from equilibrium and largely unknown in detail)…

Statistical Mechanics · Physics 2013-11-13 Peter Reimann , Mykhaylo Evstigneev

A complete derivation, from first principles, of the reaction-rate formula for a generic reaction taking place in an out of equilibrium quantum-field system is given. It is shown that the formula involves no finite-volume correction. Each…

High Energy Physics - Theory · Physics 2009-10-31 A. Niegawa , K. Okano , H. Ozaki

We distinguish a mechanical representation of the world in terms of point masses with positions and momenta and the chemical representation of the world in terms of populations of different individuals, each with intrinsic stochasticity,…

Statistical Mechanics · Physics 2019-05-07 Hong Qian

Dynamic properties of chemical reactions and appropriate relationships for open chemical equilibrium are discussed in approach of the chemical dynamics. New way to calculate composition of chemical systems in open equilibrium, based on the…

Chemical Physics · Physics 2007-05-23 B. Zilbergleyt

The behavior of some stochastic chemical reaction networks is largely unaffected by slight inaccuracies in reaction rates. We formalize the robustness of state probabilities to reaction rate deviations, and describe a formal connection…

Computational Complexity · Computer Science 2009-01-28 David Soloveichik

Non-symmetric rectangular correlation matrices occur in many problems in economics. We test the method of extracting statistically meaningful correlations between input and output variables of large dimensionality and build a toy model for…

Data Analysis, Statistics and Probability · Physics 2018-08-01 Małgorzata Snarska

To describe the nonequilibrium states of a system we introduce a new thermodynamic parameter - the lifetime of a system. The statistical distributions which can be obtained out of the mesoscopic description characterizing the behaviour of a…

Statistical Mechanics · Physics 2007-05-23 V. V. Ryazanov , S. G. Shpyrko

The statistical mechanics of a one-dimensional Ising model in thermal equilibrium is well-established, textbook material. Yet, when driven far from equilibrium by coupling two sectors to two baths at different temperatures, it exhibits…

Statistical Mechanics · Physics 2014-12-09 Nicholas Borchers , Michel Pleimling , R. K. P. Zia
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