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Understanding the response of ceramics operating in extreme environments is of interest for a variety of applications. Ab initio molecular dynamic simulations have been used to investigate the effect of structure and $B$-site (=Ti, Zr)…

Materials Science · Physics 2019-06-04 Michel Sassi , Tiffany Kaspar , Kevin M. Rosso , Steven R. Spurgeon

An eutectic LiCl/KCl flux method in a horizontal configuration has been used to grow a series of homogeneous Fe$_{1+\delta}$Se$_{1-x}$Te$_x$ single crystals of high quality with 0.5 $\leq$ $x$ $\leq$ 1. Compared with previously used…

The pyrochlore magnet $\rm Yb_2Ti_2O_7$ has been proposed as a quantum spin ice candidate, a spin liquid state expected to display emergent quantum electrodynamics with gauge photons among its elementary excitations. However, $\rm…

Strongly Correlated Electrons · Physics 2018-06-20 Gabriele Sala , Dalini D. Maharaj , Matthew B. Stone , Hanna A. Dabkowska , Bruce D. Gaulin

We investigate sputtering of a Ti3SiC2 compound target at temperatures ranging from RT (no applied external heating) to 970 oC as well as the influence of the sputtering power at 850 oC for the deposition of Ti3SiC2 films on Al2O3(0001)…

The methodology of single crystal growth of metastable $\beta$-Ti alloy TIMETAL LCB in an optical floating zone furnace is presented in this paper. Chemical compositions of both precursor material and single crystals were checked. It was…

Materials Science · Physics 2018-03-21 Jana Šmilauerová , Jiří Pospíšil , Petr Harcuba , Václav Holý , Miloš Janeček

The TiO2 rich part of the (1-x) SrO + x TiO2 phase diagram 0.5 <= x <= 1.0 was redetermined and the eutectic point between SrTiO3 and TiO2 was found at x_eut=0.7700+/-0.0001; T_eut=(1449+/-3) deg C. From TiO2 rich melt solutions, x=0.75…

Materials Science · Physics 2017-11-06 Christo Guguschev , Detlef Klimm , Frank Langhans , Zbigniew Galazka , Dirk Kok , Uta Juda , Reinhard Uecker

Single crystals of (Eu$_{1-x}$Ba$_x$)O have been grown in a molten barium-magnesium metal flux at temperatures up to 1000{\deg}C, producing single crystals of (Eu$_{1-x}$Ba$_x$)O with barium doping levels ranging from $x=0.03$ to $x=0.25$.…

Materials Science · Physics 2017-01-18 Daniel C. Ramirez , Tiglet Besara , Jeffrey B. Whalen , Theo Siegrist

High-temperature indium flux growth was applied to prepare single crystals of GdRh$_2$Si$_2$ by a modified Bridgman method leading to mm-sized single crystals with a platelet habitus. Specific heat and susceptibility data of GdRh$_2$Si$_2$…

Strongly Correlated Electrons · Physics 2016-12-05 Kristin Kliemt , Cornelius Krellner

We report the X-ray study for the pyrochlore oxide Cd2Re2O7. Two symmetry-lowering structural transitions were observed at Ts1=200K and Ts2=120K. The former is of the second order from the ideal cubic pyrochlore structure with space group…

Strongly Correlated Electrons · Physics 2009-11-07 Jun-Ichi Yamaura , Zenji Hiroi

CuFeO$_2$ single crystals up to 50 mm in length and up to 10 mm in diameter were grown by the optical floating-zone method. Stoichiometric polycrystalline rods with a diameter of 6-12 mm were used as feed materials to produce crystals of…

Materials Science · Physics 2020-01-07 Nora Wolff , Tobias Schwaigert , Dietmar Siche , Darrell G. Schlom , Detlef Klimm

Large high-quality single crystals of Bi2Sr2Can-1CunO2n+4+d (n = 2, 3) were successfully grown using an improved traveling solvent floating zone (TSFZ) method, which features a slow growth rate and steep temperature gradient along the…

Superconductivity · Physics 2007-05-23 Takao Watanabe , Takenori Fujii , Azusa Matsuda

This paper reports on the structural and optical properties of Co-doped TiO2 thin films grown onto (0001) Al2O3 substrates by non-reactive pulsed laser deposition (PLD) using argon as buffer gas. It is shown that by keeping constant the…

Materials Science · Physics 2013-07-09 S. Rout , N. Popovici , S. Dalui , M. L. Paramês , R. C. Silva , A. J. Silvestre , O. CondE

Lattice constant of Bi$_2$Se$_3$ and Sb$_2$Te$_3$ crystals is determined by X-ray powder diffraction measurement in a wide temperature range. Linear thermal expansion coefficients ($\alpha$) of the crystals are extracted, and considerable…

We study the finite-temperature transition in a model XY antiferromagnet on a pyrochlore lattice, which describes the pyrochlore material Er2Ti2O7. The ordered magnetic structure selected by thermal fluctuations is six-fold degenerate.…

Strongly Correlated Electrons · Physics 2014-04-15 M. E. Zhitomirsky , P. C. W. Holdsworth , R. Moessner

Strontium titanate (SrTiO$_{3}$, STO) stands out as a promising material for various electronic applications thanks to its exceptional dielectric properties. Molecular beam epitaxy is one of the few techniques which allows epitaxial growth…

The low-temperature thermodynamic properties of the frustrated pyrochlore Tb$_{2+x}$Ti$_{2-x}$O$_{7+y}$ have been studied using the single crystal of $x=0.005$ sitting in a long range ordered phase in the $x$-$T$ phase diagram. We observed…

Strongly Correlated Electrons · Physics 2017-04-25 H. Takatsu , T. Taniguchi , S. Kittaka , T. Sakakibara , H. Kadowaki

We present here temperature-dependent Raman, x-ray diffraction and specific heat studies between room temperature and 12 K on single crystals of spin-ice pyrochlore compound $Dy_2Ti_2O_7$ and its non-magnetic analogue $Lu_2Ti_2O_7$. Raman…

Materials Science · Physics 2009-11-13 Surajit Saha , Surjeet Singh , B. Dkhil , S. Dhar , R. Suryanarayanan , G. Dhalenne , A. Revcolevschi , A. K. Sood

In the present study, structural changes due to gradual doping of Sr in BaTiO3 were investigated by both x-ray and neutron powder diffraction techniques. Ba1-xSrxTiO3 (x=0.0, 0.5 and 1.0) samples were synthesized by PVA evaporation method…

Materials Science · Physics 2020-07-03 I. B. Elius , B. M. Asif , J. Maudood , T. K. Datta , A. K. M. Zakaria , S. Hossain , M. S. Aktar , I. Kamal

We have grown a YCrO$_3$ single crystal by the floating-zone method and studied its temperature-dependent crystalline structure and magnetization by X-ray powder diffraction and PPMS DynaCool measurements. All diffraction patterns were well…

Strongly Correlated Electrons · Physics 2024-03-08 Qian Zhao , Yinghao Zhu , Si Wu , Junchao Xia , Pengfei Zhou , Kaitong Sun , Hai-Feng Li

In this letter, we report growth and characterization of bulk Bi2Se3 single crystals. The studied Bi2Se3 crystals are grown by self flux method through solid state reaction from high temperature (950C) melt of constituent elements and slow…