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First principle calculations were performed to study the ground state electronic properties of Barium titanate within the density functional theory (DFT). In our DFT computations, we used Vosko-Wilk-Nusair correlation energy functional and…

Materials Science · Physics 2007-05-23 Hong-Jian Feng , Fa-Min Liu

Electronic correlations associated with incipient magnetism have long been recognized as an important factor in stabilizing the largest atomic volume $\delta$ phase of plutonium, yet their strength compared to those in the rare earths and…

Strongly Correlated Electrons · Physics 2022-01-10 M. Wartenbe , P. H. Tobash , J. Singleton , L. E. Winter , S. Richmond , N. Harrison

Plutonium-based compounds establish an ideal platform for exploring the interplay between long-standing itinerant-localized 5$f$ states and strongly correlated electronic states. In this paper, we exhaustively investigate the correlated…

Strongly Correlated Electrons · Physics 2023-09-21 Haiyan Lu , Li Huang

We investigate the violation of the first Hund's rule in 4$d$ and 5$d$ transition metal oxides that form solids of dimers. Bonding states within these dimers reduce the magnetization of such materials. We parametrize the dimer formation…

Strongly Correlated Electrons · Physics 2019-01-16 Malte Harland , Alexander I. Poteryaev , Sergey V. Streltsov , Alexander I. Lichtenstein

By combining the local density approximation (LDA) with dynamical mean field theory (DMFT), we report a systematic analysis of the spectral properties of $\delta$-plutonium with varying $5f$ occupancy. The LDA Hamiltonian is extracted from…

Strongly Correlated Electrons · Physics 2009-11-13 Jian-Xin Zhu , A. K. McMahan , M. D. Jones , T. Durakiewicz , J. J. Joyce , J. M. Wills , R. C. Albers

The debate whether uranium 5f electrons are closer to being localized or itinerant in the ferromagnetic compound UGa2 is not yet fully settled. The experimentally determined magnetic moments are large, approximately 3 Bohr magnetons,…

Strongly Correlated Electrons · Physics 2021-07-14 Banhi Chatterjee , Jindrich Kolorenc

We investigate the normal state of the superconducting compound PuCoGa$_5$ using the combination of density functional theory (DFT) and dynamical mean field theory (DMFT), with the continuous time quantum Monte Carlo (CTQMC) and the…

Strongly Correlated Electrons · Physics 2018-08-01 W. H. Brito , S. Choi , Y. X. Yao , G. Kotliar

Since their discovery nearly a decade ago, plutonium-based superconductors have attracted considerable interest, which is now heightened by the latest discovery of superconductivity in PuCoIn5. In the framework of density functional theory…

Strongly Correlated Electrons · Physics 2015-05-28 Jian-Xin Zhu , P. H. Tobash , E. D. Bauer , F. Ronning , B. L. Scott , K. Haule , G. Kotliar , R. C. Albers , J. M. Wills

The {\em around-mean-field} LSDA+U correlated band theory is applied to investigate the electronic and magnetic structure of $fcc$-Pu-Am alloys. Despite a lattice expansion caused by the Am atoms, neither tendency to 5$f$ localization nor…

Strong electronic correlations, emerging from the parent Mott insulator phase, are key to copper-based high temperature superconductivity (HTS). By contrast, the parent phase of iron-based HTS is never a correlated insulator. But this…

Using a first-principles approach based on density functional theory and dynamical mean field theory, we study the electronic properties of a new candidate polar metal SrEuMo$_2$O$_6$. Its electronic structure shares similarities with…

Strongly Correlated Electrons · Physics 2015-07-02 Gianluca Giovannetti , Danilo Puggioni , James M. Rondinelli , Massimo Capone

We present a detailed quantum mechanical non empirical DFT investigation of the energy-optimized geometries, phase stabilities and electronic properties of bulk Pt3N, PtN and PtN2 in a set of twenty different crystal structures. Structural…

Materials Science · Physics 2013-01-24 Mohammed S. H. Suleiman , Daniel P. Joubert

The magnetic ground states of $R_2$Ru$_2$O$_7$ and $A_2$Ru$_2$O$_7$ with $R=$ Pr, Gd, Ho, and Er, as well as $A=$ Ca, Cd are predicted devising a combination of the cluster-multipole (CMP) theory and spin-density-functional theory (SDFT).…

Strongly Correlated Electrons · Physics 2022-02-22 Marie-Therese Huebsch , Yuske Nomura , Shiro Sakai , Ryotaro Arita

Correlation effects are important for making predictions in the delta phase of Pu. Using a realistic treatment of the intra-atomic Coulomb correlations we address the long-standing problem of computing ground state properties. The…

Strongly Correlated Electrons · Physics 2016-08-31 S. Savrasov , MPI Stuttgart , G. Kotliar , Rutgers New Jersey

Plutonium dihydride and trihydride show strikingly similar crystal structures when viewed as close-packed Pu planes with ABC and AB stacking, respectively. The similarity serves as a framework for density functional theory (DFT)…

Materials Science · Physics 2013-07-03 Sven P. Rudin

Hybrid density functionals, which replaces a fraction of density functional theory (DFT) exchange with exact Hartree-Fock (HF) exchange, have been used to study the structural, magnetic, and electronic properties of delta-Plutonium. The…

Materials Science · Physics 2009-11-13 Raymond Atta-Fynn , Asok K. Ray

A combination of Density Functional Theory and the Dynamical Mean Field theory (DMFT) is used to calculate the magnetic susceptibility, heat capacity, and the temperature dependence of the valence band photoemission spectra. The…

Strongly Correlated Electrons · Physics 2008-05-13 C. A. Marianetti , K. Haule , G. Kotliar , M. J. Fluss

We report a quantum phase transition between orbital-selective Mott states, with different localized orbitals, in a Hund's metals model. Using the density matrix renormalization group, the phase diagram is constructed varying the electronic…

Strongly Correlated Electrons · Physics 2014-12-09 Julian Rincon , Adriana Moreo , Gonzalo Alvarez , Elbio Dagotto

We show how in multi-band materials, the Hund's coupling plays a crucial role in tuning the degree of electronic correlation. While in half-filled systems it enhances the correlations, in all other cases it pushes the boundary for the Mott…

Strongly Correlated Electrons · Physics 2011-06-02 Luca de' Medici

We study the effects of electron-electron interactions and hole doping on the electronic structure of Cu-doped NaFeAs using the density functional theory plus dynamical mean-field theory (DFT+DMFT) method. In particular, we employ an…

Strongly Correlated Electrons · Physics 2021-04-14 S. L. Skornyakov , V. I. Anisimov , I. Leonov