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High entropy oxides (HEOs) can possess long-range ordered magnetic states despite their extreme chemical disorder. Very little is known about how the different chemical constituents in HEOs contribute to the emergence of these magnetic…

Spectra of x-ray absorption and magnetic circular dichroism were measured at M4,5(3d) and L2,3(2p) edges of Ce in multilayers [Ce(1-x)Six/Fe]xn, with x between 0.1 and 0.65. The study uncovers the highly correlated nature of this layered…

Strongly Correlated Electrons · Physics 2024-11-28 M. Münzenberg , W. Felsch , P. Schaaf

Spin-orbit coupling and breaking of inversion symmetry are necessary ingredients to enable a pure spin current-based manipulation of the magnetization via the spin-orbit torque effect. Currently, magnetic insulator oxides with…

Using first-principles density functional calculations, we perform a comparative study of two Fe based spinel compounds, FeCr2S4 and FeSc2S4. Though both systems contain an orbitally active A site with an Fe2+ ion, their properties are…

Strongly Correlated Electrons · Physics 2011-02-04 S. Sarkar , T. Maitra , Roser Valentí , T. Saha-Dasgupta

Transition-metal ions with $5d^2$ electronic configuration in a cubic crystal field are prone to have a vanishing dipolar magnetic moment but finite higher-order multipolar moments, and they are expected to exhibit exotic physical…

Strongly Correlated Electrons · Physics 2025-07-16 J. Okamoto , G. Shibata , Yu. S. Posonov , H. Hayashi , K. Yamaura , H. Y. Huang , A. Singh , C. T. Chen , A. Tanaka , S. V. Streltsov , D. J. Huang , A. Fujimori

We investigated the spin excitations of magnetoelectric $\text{LiFePO}_4$ by THz absorption spectroscopy in magnetic fields up to 33$\,$T. By studying their selection rules, we found not only magnetic-dipole, but also electric-dipole active…

The electronic ground state of Ca3LiOsO6 was recently considered within an intermediate coupling regime that revealed J=3/2 spin-orbit entangled magnetic moments. Through inelastic neutron scattering and density functional theory we…

Strongly Correlated Electrons · Physics 2017-11-29 S. Calder , D. J. Singh , V. O. Garlea , M. D. Lumsden , Y. G. Shi , K. Yamaura , A. D. Christianson

The angular dependence (x-ray linear dichroism) of the Cr K pre-edge in MgAl2O4:Cr3+ spinel is measured by means of x-ray absorption near edge structure spectroscopy (XANES) and compared to calculations based on density functional theory…

Spin- and angle-resolved resonant (Ce $4d\to4f$) photoemission spectra of a monolayer Ce on Fe(110) reveal spin-dependent changes of the Fermi-level peak intensities. That indicate a spin-dependence of $4f$ hybridization and, thus, of $4f$…

Strongly Correlated Electrons · Physics 2007-05-23 Yu. S. Dedkov , M. Fonin , Yu. Kucherenko , S. L. Molodtsov , U. Rüdiger , C. Laubschat

We investigate the magnetic properties of archetypal transition-metal oxides MnO, FeO, CoO and NiO under very high pressure by x-ray emission spectroscopy at the K\beta line. We observe a strong modification of the magnetism in the megabar…

Strongly Correlated Electrons · Physics 2009-11-11 A. Mattila , J. -P. Rueff , J. Badro , G. Vanko , A. Shukla

Magnetic circular dichroism (MCD) in the x-ray absorption spectroscopy (XAS) at the L2,3 edges for almost entire series of rare-earth (RE) elements in RE2Fe14B, is studied experimentally and theoretically. By a quantitative comparison of…

Strongly Correlated Electrons · Physics 2009-10-31 K. Fukui , H. Ogasawara , A. Kotani , I. Harada , H. Maruyama , N. Kawamura , K. Kobayashi , J. Chaboy , A. Marcelli

Evolution of composite spin-orbital order and coupled spin-orbital excitations is studied in a variety of $d^4$ systems with $n$=$4$ electrons in the $t_{2g}$ orbital sector using the generalised self-consistent + fluctuations approach for…

Strongly Correlated Electrons · Physics 2025-04-30 Shahid Ahmad , Harshvardhan Parmar , Shubhajyoti Mohapatra , Avinash Singh

NaOsO3 hosts a rare manifestation of a metal-insulator transition driven by magnetic correlations, placing the magnetic exchange interactions in a central role. We use resonant inelastic x-ray scattering to directly probe these magnetic…

BiFeO$_3$ is a multiferroic material featuring ferroelectricity and noncollinear antiferromagnetism. Definitive and efficient control of the characteristic spin texture of BiFeO$_3$ is attractive for emerging quantum devices. In this…

Materials Science · Physics 2025-09-04 Aseem Rajan Kshirsagar , Sven Reichardt

The origin of magnetic anisotropy in magnetic compounds is a longstanding issue in solid state physics and nonmagnetic ligand ions are considered to contribute little to magnetic anisotropy. Here, we introduce the concept of ligand driven…

We address a systematic microscopic theory of spin-dependent electric polarization in 3d oxides starting with a generic three-site two-hole cluster. A perturbation scheme realistic for 3d oxides is applied which implies the quenching of…

Strongly Correlated Electrons · Physics 2009-11-13 A. S. Moskvin , S. -L. Drechsler

X-ray absorption spectroscopy (XAS) as well as x-ray magnetic circular dichroism (XMCD) and magnetization of hybrid pyrochlore Eu2-xFexTi2O7 were investigated, where the rare earth Eu (4f) was replaced with transition metal Fe (3d) to…

High-resolution resonant inelastic x-ray scattering (RIXS) measurements ($\Delta$E = 46 meV) have been performed on Cd$_2$Os$_2$O$_7$ through the metal-to-insulator transition (MIT). A magnetic excitation at 125 meV evolves continuously…

Low-energy electron excitation spectra were measured on a single crystal of a typical iron-based superconductor PrFeAsO$_{0.7}$ using resonant inelastic X-ray scattering (RIXS) at the Fe-$L_3$ edge. Characteristic RIXS features are clearly…

Strongly Correlated Electrons · Physics 2016-07-18 T. Nomura , Y. Harada , H. Niwa , K. Ishii , M. Ishikado , S. Shamoto , I. Jarrige

Density functional based simulations are employed to explore magnetoelectric effects in iron-based oxides, showing a unique layered structure. We theoretically predict CaFeO2 to be a promising magnetoelectric, showing…

Strongly Correlated Electrons · Physics 2015-06-15 Kunihiko Yamauchi , Tamio Oguchi , Silvia Picozzi