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Multiferroics, defined for those multifunctional materials in which two or more kinds of fundamental ferroicities coexist, have become one of the hottest topics of condensed matter physics and materials science in recent years. The…

Materials Science · Physics 2015-05-13 K. F. Wang , J. -M. Liu , Z. F. Ren

Intertwined ionic conduction and ferroelectric (FE) switching in HfO2 lead to extensive focuses. To describe its fundamental phenomena, we present a free-energy model describing the potential of ferroelectrics with successive FE switching…

Materials Science · Physics 2023-11-06 Guo-Dong Zhao , Xingen Liu , Zhongshan Xu , Wei Ren , Xiaona Zhu , David Wei Zhang , Shaofeng Yu

A series of polycrystalline pyrochlore rare-earth titanate Ho_{2-x}Cr_xTi_2O_7 are synthesized in order to enhance the ferroelectricity of pyrochlore Ho2Ti2O7. For the sample close to the doping level x=0.4, a giant enhancement of…

Materials Science · Physics 2010-07-27 X. W. Dong , S. Dong , K. F. Wang , J. G. Wan , J. -M. Liu

Multiferroic particulate composites have been fabricated by taking the morphotropic phase boundary composition of ferroelectric phase Bi(Ni1/2Ti1/2)O3-PbTiO3 and magnetic phase (Ni,Zn)Fe2O4. The ferroelectric phase has coexisting monoclinic…

Materials Science · Physics 2018-08-06 Rishikesh Pandey , Uma Shankar , Sher Singh Meena , Akhilesh Kumar Singh

HfO2, a simple binary oxide, holds ultra-scalable ferroelectricity integrable into silicon technology. Polar orthorhombic (Pbc21) form in ultra-thin-films ascribes as the plausible root-cause of the astonishing ferroelectricity, which has…

The coexistence of multiple ferroic orders, i.e. multiferroicity, is a scarce property to be found in materials. Historically, this state has been found mainly in 3-dimensional complex oxides, but so far this state has still been elusive…

Ferroelectric control of altermagnetism in momentum space has been studied widely, while the control of magnetism in real space of altermagnets are still rare. We present a design rule to identify multiferroicity in n=2 Ruddlesden-Popper…

Materials Science · Physics 2025-08-20 Ying Zhou , Hui-Min Zhang , Cheng-Ao Ji , Hongjun Xiang , Shuai Dong , James M. Rondinelli , Xue-Zeng Lu

Sm$_2$Ti$_2$O$_7$, a member of rare-earth titanate pyrochlores, exhibits dipolar-octupolar antiferromagnetism below $T_N$ = 0.35 K. We observed two ferroelectric transitions at 182 ($T_{FE1}$) and 52 K ($T_{FE2}$), significantly higher than…

Materials Science · Physics 2024-07-30 S. Mukherjee , O. Ivashko , S. Majumdar , A. Kumar , S. Giri

Two-dimensional (2D) magnets have broad application prospects in the spintronics, but how to effectively control them with a small electric field is still an issue. Here we propose that 2D magnets can be efficiently controlled in a…

Mesoscale and Nanoscale Physics · Physics 2022-02-01 Ping Li , Xue-Song Zhou , Zhi-Xin Guo

The ground-state structural and electronic properties of ferroelectric BiFeO$_3$ are calculated using density functional theory within the local spin-density approximation and the LSDA+U method. The crystal structure is computed to be…

Materials Science · Physics 2007-05-23 J. B. Neaton , C. Ederer , U. V. Waghmare , N. A. Spaldin , K. M. Rabe

Unconventional ferroelectricity, robust at reduced nanoscale sizes, exhibited by hafnia-based thin-films presents tremendous opportunities in nanoelectronics. However, the exact nature of polarization switching remains controversial. Here,…

Magnetoelectric multiferroics in which ferroelectricity and magnetism coexist have attracted extensive attention because they provide great opportunities for the mutual control of electric polarization by magnetic fields and magnetization…

Materials Science · Physics 2013-04-25 Fen Wang , Tao Zou , Li-Qin Yan , Yi Liu , Young Sun

The recent observation of a ferroelectric-like structural transition in metallic LiOsO$_3$ has generated a flurry of interest in the properties of polar metals. Such materials are thought to be rare because free electrons screen out the…

Materials Science · Physics 2016-02-29 Nicole A. Benedek , Turan Birol

Increasing demands for electric field-tunable electric, magnetic, and orbital (EMO) materials has renewed interests in ferroelectricity and its coupling to EMO properties in complex perovskite oxides. The historic design strategy to achieve…

Materials Science · Physics 2012-04-12 James M. Rondinelli , Craig J. Fennie

Wurtzite-type nitrides have recently emerged as promising candidates for ferroelectric applications, yet their magnetic counterparts remain largely unexplored. Here, we establish MnSiN$_2$ and MnGeN$_2$ as aristotypes of a new multiferroic…

Materials Science · Physics 2025-09-09 Steven M. Baksa , Lin-Ding Yuan , Stephen D. Wilson , James M. Rondinelli

Due to the strong coupling between magnetism and ferroelectricity, $(\mathrm{ND}_4)_2\mathrm{FeCl}_5\cdot\mathrm{D}_2\mathrm{O}$ exhibits several intriguing magnetic and electric phases. In this letter, we include high-order onsite spin…

Materials Science · Physics 2021-08-25 Shaozhi Li , Randy S. Fishman

In this contribution to the special issue on multiferroics we focus on multiferroicity driven by different forms of charge ordering. We will present the generic mechanisms by which charge ordering can induce ferroelectricity in magnetic…

Materials Science · Physics 2011-07-22 Jeroen van den Brink , Daniel I. Khomskii

We have fabricated PbTiO$_{3}$/SrRuO$_{3}$ superlattices with ultra-thin SrRuO$_{3}$ layers. Due to the superlattice geometry, the samples show a large anisotropy in their electrical resistivity, which can be controlled by changing the…

Materials Science · Physics 2015-06-03 S. J. Callori , J. Gabel , D. Su , J. Sinsheimer , M. V. Fernandez-Serra , M. Dawber

We propose a method of controlling the metal-insulator transition of one perovskite material at its interface with a another ferroelectric material based on first principle calculations. The operating principle is that the rotation of…

Materials Science · Physics 2016-03-11 Xu He , Kui-juan Jin , Chen Ge , Zhong-shui Ma , Guo-zhen Yang

Pronounced anisotropy of magnetic properties and complex magnetic order of a new oxi-halide compound Co7(TeO3)4Br6 has been investigated by powder and single crystal neutron diffraction, magnetization and ac susceptibility techniques.…

Materials Science · Physics 2013-05-29 M. Prester , I. Zivkovic , O. Zaharko , D. Pajic , P. Tregenna-Piggott , H. Berger