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Analyzing rate-performance data in battery electrodes is greatly facilitated by access to simple analytical models. Here we describe a number of simple equations for fitting capacity-rate data. These equations output fit parameters, such as…

Applied Physics · Physics 2020-02-04 Jonathan Coleman , Ruiyuan Tian

An important objective of designing lithium-ion rechargeable battery cells is to maximize their rate performance without compromising the energy density, which is mainly achieved through computationally expensive numerical simulations at…

Materials Science · Physics 2020-05-05 Fan Wang , Ming Tang

For battery electrodes, measured capacity decays as charge/discharge current is increased. Such rate-performance is important from a practical perspective and is usually characterised via galvanostatic charge-discharge measurements.…

Lithium-ion batteries dominate battery research and industry due to their long research history and high energy density. However, increasing demand and limited lithium resources have raised lithium prices and battery costs, motivating…

Materials Science · Physics 2025-12-17 Caolin Ua Tuiscint , Jonathan N Coleman

The prediction of battery rate performance traditionally relies on computation-intensive numerical simulations. While simplified analytical models have been developed to accelerate the calculation, they usually assume battery performance to…

Materials Science · Physics 2024-04-09 Hongxuan Wang , Fan Wang , Ming Tang

Batteries are nonlinear dynamical systems that can be modeled by Porous Electrode Theory models. The aim of optimal fast charging is to reduce the charging time while keeping battery degradation low. Most past studies assume that model…

Systems and Control · Electrical Eng. & Systems 2024-10-14 Minsu Kim , Joachim Schaeffer , Marc D. Berliner , Berta Pedret Sagnier , Rolf Findeisen , Richard D. Braatz

Some rate of oxidation and reduction side-reactions will inevitably coexist in most rechargeable batteries, contributing to reversible and irreversible self-discharge. While parasitic reduction traps electrons, parasitic oxidation donates…

Chemical Physics · Physics 2026-02-17 Marco-Tulio F. Rodrigues

Higher loading of active electrode materials is desired in batteries, especially those based on conversion reactions, for enhanced energy density and cost efficiency. However, increasing active material loading in electrodes can cause…

Machine Learning · Computer Science 2024-12-30 Vidushi Sharma , Andy Tek , Khanh Nguyen , Max Giammona , Murtaza Zohair , Linda Sundberg , Young-Hye La

Recent data-driven approaches have shown great potential in early prediction of battery cycle life by utilizing features from the discharge voltage curve. However, these studies caution that data-driven approaches must be combined with…

Applications · Statistics 2020-10-16 Valentin Sulzer , Peyman Mohtat , Suhak Lee , Jason B. Siegel , Anna G. Stefanopoulou

An isothermal porous-electrode model of a discharging lead-acid battery is presented, which includes an extension of concentrated-solution theory that accounts for excluded-volume effects, local pressure variation, and a detailed…

Chemical Physics · Physics 2020-06-05 Valentin Sulzer , S. Jon Chapman , Colin P. Please , David A. Howey , Charles W. Monroe

Metal anodes provide the highest energy density in batteries. However, they still suffer from electrode/electrolyte interface side reactions and dendrite growth, especially under fast-charging conditions. In this paper, we consider a…

Materials Science · Physics 2025-07-29 Hamed Taghavian , Viktor Vanoppen , Erik Berg , Peter Broqvist , Jens Sjölund

The rapid charging and/or discharging of electrochemical cells can lead to localized depletion of electrolyte concentration. This depletion can significantly impact the system's time dependent resistance. For systems with porous electrodes,…

Chemical Physics · Physics 2017-12-27 James W. Palko , Ali Hemmatifar , Juan G. Santiago

Battery degradation modes influence the aging behavior of Li-ion batteries, leading to accelerated capacity loss and potential safety issues. Quantifying these aging mechanisms poses challenges for both online and offline diagnostics in…

Signal Processing · Electrical Eng. & Systems 2024-12-16 Yuanhao Cheng , Hanyu Bai , Yichen Liang , Xiaofan Cui , Weiren Jiang , Ziyou Song

The optimization of the electrode manufacturing process is important for upscaling the application of Lithium Ion Batteries (LIBs) to cater for growing energy demand. In particular, LIB manufacturing is very important to be optimized…

Machine Learning · Computer Science 2023-07-13 Marc Duquesnoy , Chaoyue Liu , Vishank Kumar , Elixabete Ayerbe , Alejandro A. Franco

Control of systems of automated guided vehicles involves action planning at many levels. For efficient control of these systems, accurate estimation of cost parameters (speed, energy, task completion performance, \textit{et~cetera} is…

Robotics · Computer Science 2018-08-24 Pragna Das , Lluís Ribas Xirgo

In Li-ion batteries the electrochemical potential drives the redox reactions occurring at the interface between electrolyte and storage material, typically active particles for porous electrodes, allowing Li ions intercalation/extraction…

Applied Physics · Physics 2022-03-15 M. Magri , B. Boz , L. Cabras , A. Salvadori

Ultrahigh rate performance of active particles used in lithium-ion battery electrodes has been revealed by single-particle measurements, which indicates a huge potential for developing high-power batteries. However, the charging/discharging…

Chemical Physics · Physics 2022-07-25 Ruoyu Xiong , Mengyuan Zhou , Longhui Li , Jia Xu , Maoyuan Li , Bo Yan , Dequn Li , Yun Zhang , Huamin Zhou

Fast charging of lithium-ion batteries has gained extensive research interests, but most of existing methods are either based on simple rule-based charging profiles or require explicit battery models that are non-trivial to identify…

Systems and Control · Electrical Eng. & Systems 2023-04-18 Kaixiang Zhang , Kaian Chen , Xinfan Lin , Yusheng Zheng , Xunyun Yin , Xiaosong Hu , Ziyou Song , Zhaojian Li

Electrochemical and equivalent-circuit modelling are the two most popular approaches to battery simulation, but the former is computationally expensive and the latter provides limited physical insight. A theoretical middle ground would be…

Chemical Physics · Physics 2020-06-05 Valentin Sulzer , S. Jon Chapman , Colin P. Please , David A. Howey , Charles W. Monroe

Currently, the characterization of electric energy storage units used for power system operation and planning models relies on two major assumptions: charge and discharge efficiencies, and power limits are constant and independent of the…

Systems and Control · Electrical Eng. & Systems 2024-12-20 Alvaro Gonzalez-Castellanos , David Pozo , Aldo Bischi
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