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The rising demand for high-performing batteries requires new technological concepts. To facilitate fast charge and discharge, hierarchically structured electrodes offer short diffusion paths in the active material. However, there are still…

Numerical simulations are a powerful tool for the development and improvement of Li-ion batteries. Modeling the mass transport of the involved electrolytic solutions requires precise determination of the corresponding electrolyte…

Chemical Physics · Physics 2024-11-21 Lukas Lehnert , Maryam Nojabaee , Arnulf Latz , Birger Horstmann

Investigating the correlations between dynamic and static storage properties of nanoporous electrodes is beneficial for further progress of supercapacitors-based technologies. While the dependence of the capacitance on the pores' sizes is…

Statistical Mechanics · Physics 2021-05-21 Timur Aslyamov , Konstantin Sinkov , Iskander Akhatov

Lithium-ion technologies are increasingly employed to electrify transportation and provide stationary energy storage for electrical grids, and as such their development has garnered much attention. However, their deployment is still…

Physics and Society · Physics 2021-04-26 Micah S. Ziegler , Jessika E. Trancik

Identifying overpotential components of electrochemical systems enables quantitative analysis of polarization contributions of kinetic processes under practical operating conditions. However, the inherently coupled kinetic processes lead to…

Chemical Physics · Physics 2022-07-25 Ruoyu Xiong , Yue Yu , Shuyi Chen , Maoyuan Li , Longhui Li , Mengyuan Zhou , Wen Zhang , Bo Yan , Dequn Li , Hui Yang , Yun Zhang , Huamin Zhou

The development of novel electrolytes and electrodes for supercapacitors is hindered by a gap of several orders of magnitude between experimentally measured and theoretically predicted charging timescales. Here, we propose an electrode…

Chemical Physics · Physics 2020-02-26 Cheng Lian , Mathijs Janssen , Honglai Liu , René van Roij

Accurately predicting aging of lithium-ion batteries would help to prolong their lifespan, but remains a challenge owing to the complexity and interrelation of different aging mechanisms. As a result, aging prediction often relies on…

The sustainable mobility trend touches the racing world as well, from the hybridization of Formula 1 (F1) and Le Mans Hypercars to the fully electric Formula E racing class. In this scenario, the research community is studying how to push…

Systems and Control · Electrical Eng. & Systems 2024-06-10 Giorgio Riva , Stefano Radrizzani , Giulio Panzani

With the importance of Li-ion and emerging alternative batteries to our electric future, predicting new sustainable materials, electrolytes and complete cells that safely provide high performance, long life, energy dense capability is…

Materials Science · Physics 2022-07-26 Alex Grant , Colm O'Dwyer

It is shown that continuously occurring electrolyte-reduction reaction on freshly-exposed electrode surfaces during lithiation/delithiation cycles causes the lowering of cycling efficiency, and hence, capacity fade in well-cycled silicon…

Materials Science · Physics 2020-02-19 Vijay A. Sethuraman

Silicon-containing lithium-ion batteries can exhibit capacity gain early in life, which makes forecasting future cell behavior difficult. We have observed these anomalous trends even in conditions where known mechanisms, such as overhang…

Chemical Physics · Physics 2026-02-17 Marco-Tulio F. Rodrigues , Charles McDaniel , Stephen E. Trask , Daniel P. Abraham

We investigate the ability of a homogeneous collection of deferrable energy loads to behave as a battery; that is, to absorb and release energy in a controllable fashion up to fixed and predetermined limits on volume, charge rate and…

Systems and Control · Computer Science 2016-10-07 Daria Madjidian , Mardavij Roozbehani , Munther A. Dahleh

Next-generation lithium-ion batteries with silicon anodes have positive characteristics due to higher energy densities compared to state-of-the-art graphite anodes. However, the large volume expansion of silicon anodes can cause high…

Numerical Analysis · Mathematics 2024-04-03 R. Schoof , G. F. Castelli , W. Dörfler

Electrolyte filling is a time-critical step during battery manufacturing that also affects the battery performance. The underlying physical phenomena during filling mainly occur on the pore scale and are hard to study experimentally. In…

Two dimensional materials show great potential for use in battery electrodes and are believed to be particularly promising for high-rate applications. However, there does not seem to be much hard evidence for the superior rate-performance…

Mesoscale and Nanoscale Physics · Physics 2019-12-06 Ruiyuan Tian , Madeleine Breshears , Dominik V Horvath , Jonathan N Coleman

Modelling the ionic transport in battery cells requires precise parametrization of the involved electrolytes. For carbonate-based electrolytes, however, the evaluation of their parameters suffers from interphase effects between the bulk…

Electrode manufacturing is at the core of the lithium ion battery (LIB) fabrication process. The electrode microstructure and the electrochemical performance are determined by the adopted manufacturing parameters. However, in view of the…

Chemical Physics · Physics 2022-06-14 Chaoyue Liu , Teo Lombardo , Jiahui Xu , Alain C. Ngandjong , Alejandro A. Franco

Ultracapacitors are rapidly being adopted for use for a wide range of electrical energy storage applications. While ultracapacitors are able to deliver high rates of charge and discharge, they are limited in the amount of energy stored. The…

Materials Science · Physics 2010-05-14 Meryl D. Stoller , Rodney S. Ruoff

Fracture of lithium-ion battery electrodes is found to contribute to capacity fade and reduce the lifespan of a battery. Traditional fracture models for batteries are restricted to consideration of a single, idealised particle; here,…