Related papers: Interstellar dimethyl ether gas-phase formation: a…
Observations of star forming environments revealed that the abundances of some deuterated interstellar molecules are markedly larger than the cosmic D/H ratio of 10-5. Possible reasons for this pointed to grain surface chemistry. How- ever,…
CO2 is one of the dominant components of the interstellar ice. Recent observations show CO2 exists more abundantly in polar (H2O-dominated) ice than in apolar (H2O-poor) ice. CO2 ice formation is primarily attributed to the reaction between…
An extensive search for the complex molecule trans-ethyl methyl ether towards several hot core regions has been performed. Using the IRAM 30m telescope and the SEST 15m we looked at several frequencies where trans-ethyl methyl ether has…
The chemical evolution in high-mass star-forming regions is still poorly constrained. Studying the evolution of deuterated molecules allows to differentiate between subsequent stages of high-mass star formation regions due to the strong…
Understanding gas-grain chemistry of deuterium in star-forming objects may help to explain their history and present state. We aim to clarify how processes in ices affect the deuterium fractionation. In this regard, we investigate a…
Star-forming regions host a large and evolving suite of molecular species. Molecular transition lines, particularly of complex molecules, can reveal the physical and dynamical environment of star formation. We aim to study the large-scale…
We develop the theory of radiative association of an atom and a diatomic molecule within a close-coupling framework. We apply it to the formation of H$_3^-$ after the low energy collision (below 0.5 eV) of H$_2$ with H$^-$. Using recently…
The methylidyne cation (CH$^+$) and the methyl cation (CH$_3^+$) are building blocks of organic molecules, yet their coupled formation and excitation mechanisms remain mainly unprobed. The James Webb Space Telescope (JWST), with its high…
Small organic molecules are thought to provide building blocks for the formation of complex interstellar polycyclic aromatic hydrocarbons (PAHs). However, the underlying chemical mechanisms remain unclear, particularly concerning the role…
We investigate the role of carbon monoxide ice in the chemical evolution of prestellar cores using astrochemical rate equation models. We constrain the ratios of the binding energies on CO ice and H$_{2}$O ice for a series of adsorbates…
Experimental and computational chemistry are two disciplines to conduct research in Astrochemistry, providing essential reference data for both astronomical observations and modeling. These approaches not only mutually support each other,…
We report the first sub-arc second (0.65$\arcsec$ $\times$ 0.51$\arcsec$) image of the dimethyl ether molecule, (CH$_{3}$)$_{2}$O, toward the Orion Kleinmann-Low nebula (Orion--KL). The observations were carried at 43.4 GHz with the…
The millimeter-wave rotational transition line ($J_K = 1_0 - 0_0$) of deuterated methane CH$_3$D has tentatively been detected toward the low-mass Class 0 protostar IRAS 04368+2557 in L1527 with the Heinrich Hertz Submillimeter Telescope.…
APEX single-dish observations at sub-millimeter wavelengths toward a sample of massive star-forming regions reveal that C2H is almost omni-present toward all covered evolutionary stages from Infrared Dark Clouds via High-Mass Protostellar…
Formation of interstellar complex organic molecules is currently thought to be dominated by the barrierless coupling between radicals on the interstellar icy grain surfaces. Previous standard DFT results on the reactivity between CH$_3$ and…
My thesis work aims to study the inter-relation between various physical and chemical conditions in a wide range of astrophysical environments. Our studied regions range from the super-hot regions (i.e., nebular, photon-dominated, or…
Solid state astrochemical reaction pathways have the potential to link the formation of small nitrogen-bearing species, like NH3 and HNCO, and prebiotic molecules, specifically amino acids. To date, the chemical origin of such small…
Cold cores in interstellar molecular clouds represent the very first phase in star formation. The physical conditions of these objects are studied in order to understand how molecular clouds evolve and how stellar masses are determined. The…
We report the detection of interstellar methoxymethanol (CH$_3$OCH$_2$OH) in ALMA Bands 6 and 7 toward the MM1 core in the high-mass star-forming region NGC 6334I at ~0.1" - 1" spatial resolution. A column density of 4(2) x $10^{18}$…
Interstellar carbonaceous dust is mainly formed in the innermost regions of circumstellar envelopes around carbon-rich asymptotic giant branch (AGB) stars. In these highly chemically stratified regions, atomic and diatomic carbon, along…