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The microscopic doping mechanism behind the superconductor-to-insulator transition of a thin film of YBa2Cu3O7 was recently identified as due to the migration of O atoms from the CuO chains of the film. Here we employ density-functional…

Superconductivity · Physics 2024-06-19 Lorenzo A. Mariano , Roberta Poloni

The interplay between the quasi 1-dimensional CuO-chains and the 2-dimensional CuO2 planes of YBa2Cu3O6+x (YBCO) has been in focus for a long time. Although the CuO-chains are known to be important as charge reservoirs that enable…

Here we study the effect of Ca doping on charge transfer mechanism of polycrystalline YBa2Cu3O7-{\delta} compound. The samples of composition Y1-xCaxBa2Cu3O7-{\delta} (x = 0.00, 0.05, 0.10, 0.20 and 0.30) are synthesized through standard…

Superconductivity · Physics 2012-07-10 Shiva Kumar Singh , M. Husain , V. P. S. Awana

The mechanism of field-effect doping in the "123" high critical temperature superconductors (HTS) has been investigated by x-ray absorption spectroscopy in the presence of an electric field. We demonstrate that holes are created at the CuO…

Strongly Correlated Electrons · Physics 2008-12-07 M. Salluzzo , G. Ghiringhelli , J. C. Cezar , N. B. Brookes , G. M. De Luca , F. Fracassi , R. Vaglio

Charge redistribution in high-Tc superconductors due to structural defects or interfaces is known to be crucial for electronic applications as the band structure is modified on a local scale. In order to investigate these effects in more…

Superconductivity · Physics 2009-11-13 Udo Schwingenschloegl , Cosima Schuster

Resonant optical excitation of apical oxygen vibrational modes in the normal state of underdoped YBa2Cu3O6+x induces a transient state with optical properties similar to those of the equilibrium superconducting state. Amongst these, a…

The effect of Co-Ga paired substitution on the superconducting properties of YBa2Cu3O7-d (Y-123) has been investigated by X-ray diffraction, ac susceptibility,dc resistivity and oxygen content measurements. We report in this paper the…

Superconductivity · Physics 2009-11-10 Anjana Dogra , S. Rayaprol , N. A. Shah , D. G. Kuberkar

YBa2Cu3Ox, the first superconductor discovered with Tc higher than 77 K, is among the most complex cuprates having both CuO chains and plains in the structure. YBa2Cu3O7 (YBCO) exhibits slightly overdoped behavior and further doping is…

Solid state ionic approaches for modifying ion distributions in getter/oxide heterostructures offer exciting potentials to control material properties. Here we report a simple, scalable approach allowing for total control of the…

We study a model of YBa2Cu3O(6+y) to investigate the influence of oxygen ordering and doping imbalance on the critical temperature Tc(y) and to elucidate a possible origin of well-known feature of YBCO phase diagram: the 60-K plateau.…

Superconductivity · Physics 2009-11-11 T. A. Zaleski , T. K. Kopec

Practical high temperature superconductors must be textured to minimize the reduction of the critical current density $J_{gb}$ at misoriented grain boundaries. Partial substitution of Ca for Y in $YBa_2Cu_3O_{7-\delta}$ has shown…

Materials Science · Physics 2007-05-23 Xueyan Song , George Daniels , D. Matt Feldmann , Alex Gurevich , David Larbalestier

Doping of strongly layered ionic oxides is an established paradigm for creating novel electronic behavior. This is nowhere more apparent than in superconductivity, where doping gives rise to high temperature superconductivity in cuprates…

Superconductivity · Physics 2013-07-17 E. R. Ylvisaker , W. E. Pickett

We present a joint experimental and theoretical study of the electronic structure of the cuprate chain systems A_(1-x)CuO_2 (A=Ca,Sr,Ba), as measured using O-K and Cu-L_3 x-ray absorption spectroscopy. The doping-dependent behaviour in…

Strongly Correlated Electrons · Physics 2009-09-25 Z. Hu , S. -L. Drechsler , J. Malek , H. Rosner , R. Neudert , M. Knupfer , M. S. Golden , J. Fink , J. Karpinski , G. Kaindl , C. Hellwig , Ch. Jung

We report systematic studies of structural, microstructural and transport properties of Y1-xCaxBa2Cu3O7-d bulk samples with 0.20 x 0.0. The partial substitution of Ca2+ at Y3+ site in YBa2Cu3O7-d leads towards slightly overdoped regime,…

Superconductivity · Physics 2009-11-10 Rajiv Giri , H. K. Singh , O. N. Srivastava , V. P. S. Awana , Anurag Gupta , B. V. Kumaraswamy , H. Kishan

The mechanism behind superconductivity suppression induced by Pr substitutions in YBa$_2$Cu$_3$O$_{7-\delta}$ (YBCO) has been a mystery since its discovery: in spite of being isovalent to Y$^{3+}$ with a small magnetic moment, it is the…

The electronic structure of YBa2Cu3O6+x and La2-xSrxCuO4 for various values of x has been investigated using hard x-ray photoemission spectroscopy. The experimental results establish that the cleaving of YBa2Cu3O6+x compounds occurs…

We measure the nuclear quadrupole resonance (NQR) signal on the Zn site in nearly optimally doped YBa$_2$Cu$_3$O$_{6.92}$, when Cu is substituted by 3\% of isotopically pure $^{67}$Zn. We observe that Zn creates large insulating islands,…

Superconductivity · Physics 2015-08-20 Damjan Pelc , Miroslav Požek , Vito Despoja , Denis K. Sunko

Electrolyte gating is widely used to induce large carrier density modulation on solid surfaces to explore various properties. Most of past works have attributed the charge modulation to electrostatic field effect. However, some recent…

The thermodynamics of the superconducting transition is studied as a function of doping using high-resolution expansivity data of YBa2Cu3Ox single crystals and Monte-Carlo simulations of the anisotropic 3D-XY model. We directly show that Tc…

Superconductivity · Physics 2009-10-31 C. Meingast , V. Pasler , P. Nagel , A. Rykov , S. Tajima , P. Olsson

A structural phase transformation in the CuO_2 planes of YBa_2Cu_3O_x has been observed at the onset of the overdoped regime, x=6.95. We have measured as a function of x the dimpling in the CuO_2 planes by EXAFS, and the O2,3 in-phase…

Superconductivity · Physics 2009-10-30 E. Kaldis , J. Röhler , E. Liarokapis , N. Poulakis , K. Conder , P. W. Loeffen
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