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We present a multi-scale computational approach that combines atomistic spin models with the cluster multipole (CMP) method. The CMP method enables a systematic and accurate generation of complex non-collinear magnetic structures using…

Materials Science · Physics 2025-03-06 Juba Bouaziz , Takuya Nomoto , Ryotaro Arita

Multi-configurational wave-function theory (MC-WFT) that combines complete active space self-consistent field (CASSCF) approach with subsequent state interaction (SI) treatment of spin-orbit coupling (SOC), abbreviated as CASSCF-SO, plays…

Chemical Physics · Physics 2025-03-11 Zhe-Bin Guan , Hong Jiang

Dynamical Mean-Field Theory (DMFT) has established itself as a reliable and well-controlled approximation to study correlation effects in bulk solids and also two-dimensional systems. In combination with standard density-functional theory…

Atomic and Molecular Clusters · Physics 2015-05-30 V. Turkowski , A. Kabir , N. Nayyar , Talat S. Rahman

Magnetite has attracted increasing attention in recent years due to its promising and diverse applications in biomedicine. Theoretical modelling can play an important role in understanding magnetite-based nanomaterials at the atomic scale…

Materials Science · Physics 2019-03-27 Hongsheng Liu , Gotthard Seifert , Cristiana Di Valentin

While the traditional local-density approximation (LDA) cannot describe Mott insulators, {\it ab-initio} determination of the Hubbard $U$, for example, limits LDA-plus dynamical mean field theory (DMFT) approaches. Here, we attempt to…

Strongly Correlated Electrons · Physics 2009-02-12 M. S. Laad , L. Hozoi , L. Craco

We explore the derivation of interatomic exchange interactions in ferromagnets within density-functional theory (DFT) and the mapping of DFT results onto a spin Hamiltonian. We delve into the problem of systems comprising atoms with strong…

Materials Science · Physics 2013-10-10 Marjana Lezaic , Phivos Mavropoulos , Gustav Bihlmayer , Stefan Blügel

We present in full detail a newly developed formalism enabling density functional perturbation theory (DFPT) calculations from a DFT+$U$ ground state. The implementation includes ultrasoft pseudopotentials and is valid for both insulating…

Strongly Correlated Electrons · Physics 2020-02-21 Andrea Floris , Iurii Timrov , Burak Himmetoglu , Nicola Marzari , Stefano de Gironcoli , Matteo Cococcioni

The existence of band gaps in Mott insulators such as perovskite oxides with partially filled 3d shells has been traditionally explained in terms of strong, dynamic inter-electronic repulsion codified by the on-site repulsion energy U in…

Materials Science · Physics 2019-07-24 Julien Varignon , Manuel Bibes , Alex Zunger

A description of non-collinear magnetism in the framework of spin-density functional theory is presented for the exact exchange energy functional which depends explicitly on two-component spinor orbitals. The equations for the effective…

We re-examine the commonly used density functional theory plus Hubbard \textit{U} (DFT$+U$) method for the case of non-collinear magnets. While many studies neglect to explicitly include the exchange correction parameter \textit{J}, or…

Strongly Correlated Electrons · Physics 2025-06-10 Eric Bousquet , Nicola Spaldin

We review recent results on the properties of materials with correlated electrons obtained within the LDA+DMFT approach, a combination of a conventional band structure approach based on the local density approximation (LDA) and the…

Strongly Correlated Electrons · Physics 2015-03-13 J. Kunes , I. Leonov , M. Kollar , K. Byczuk , V. I. Anisimov , D. Vollhardt

High-performance batteries, heterogeneous catalysts and next-generation photovoltaics often centrally involve transition metal oxides (TMOs) that undergo charge or spin-state changes. Demand for accurate DFT modeling of TMOs has increased…

Materials Science · Physics 2024-01-23 Lórien MacEnulty , David D. O'Regan

In search of the ferromagnetic insulators for spintronic device applications, we have studied the electronic, optical, and magnetic properties ofLa2CrNiO6(LCNO) using the first principle density functional theory (DFT)and monte carlo…

Materials Science · Physics 2021-09-28 Tushar Kanti Bhowmik , T. P Sinha

We present systematic quantitative description of the magnetoconductance of the split-gate quantum wires. Accounting for the exchange and correlation interactions within the spin density function theory (DFT) leads to the lifting of the…

Mesoscale and Nanoscale Physics · Physics 2009-05-26 I. V. Zozoulenko , S. Ihnatsenko

We propose and implement a novel hybrid meta-heuristic optimization algorithm for the identification of non-collinear global ground-states in magnetic systems. The inputs to this optimization scheme are directly from non-collinear density…

Materials Science · Physics 2023-10-03 Guy C. Moore , Matthew K. Horton , Kristin A. Persson

We revisit the electronic structure of Ni, using the density functional theory (DFT) and dynamical mean-field theory (DMFT) for the theoretical description of its electronic structure properties along with finite-temperature magnetism. Our…

Strongly Correlated Electrons · Physics 2024-09-04 Shivani Bhardwaj , Antik Sihi , Sudhir K. Pandey

Electrons in zero external magnetic field can be studied with density functional theory (DFT) or with spin-DFT (SDFT). The latter is normally used for open shell systems because its approximations appear to model better the exchange and…

Chemical Physics · Physics 2022-04-06 Timothy Callow , Benjamin Pearce , Nikitas Gidopoulos

Using the DFT+dynamical mean-field theory method we revisit the pressure-temperature phase diagram of the prototypical correlated insulator NiO. We study the pressure-induced evolution of the electronic structure, magnetic state, and…

Strongly Correlated Electrons · Physics 2024-12-03 G. M. Gaifutdinov , I. V. Leonov

Geometrically frustrated magnetic semiconductor $\textrm{CuMnO}_{2}$ has potential applications as photo-catalyst, in photochemical cells and multi-ferroic devices. Electronic band structure in the antiferromagnetic and ferromagnetic phases…

Materials Science · Physics 2024-06-05 Apurba Sarkar , Joydeep Chatterjee , Arghya Taraphder , Nandan Pakhira

The cluster multipole (CMP) expansion for magnetic structures provides a scheme to systematically generate candidate magnetic structures specifically including noncollinear magnetic configurations adapted to the crystal symmetry of a given…

Materials Science · Physics 2021-02-19 Marie-Therese Huebsch , Takuya Nomoto , Michi-To Suzuki , Ryotaro Arita
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