Related papers: Can Formamide Be Formed on Interstellar Ice? An At…
In the coldest (10--20 K) regions of the interstellar medium, the icy surfaces of interstellar grains serve as solid-state supports for chemical reactions. Among their plausible roles, that of third body is advocated, in which the reaction…
Column density ratios of complex organic molecules are generally constant across protostellar systems with some low-level scatter. However, the scatter in formamide (NH$_2$CHO) to methanol (CH$_3$OH) column density ratio is one of the…
Carbon disulfide (CS$_2$) is one of the sulfur-bearing species expected to be present in the interstellar medium (ISM). In this study, we investigated the surface reactions of solid CS$_2$ with hydrogen (H) atoms on amorphous solid water…
Glycolaldehyde is a simple monosaccharide sugar linked to prebiotic chemistry. Recently it was detected in a molecular core in the star-forming region G31.41+0.31 at a reasonably high abundance. We investigate the formation of…
In the interstellar medium, the amide-type molecules play an important role in the formation of the prebiotic molecules in the hot molecular cores or high-mass star formation regions. The complex amide-related molecule cyanamide…
Interstellar CO2 is an important reservoir of carbon and oxygen, and one of the major constituents of the icy mantles of dust grains, but it is not observable directly in the cold gas because has no permanent dipole moment. Its protonated…
The knowledge of the binding energy of molecules on astrophysically relevant ices can help to obtain an estimate of the desorption rate, i.e. the molecules residence time on the surface. This represents an important parameter for…
Glycolaldehyde (CH$_{2}$OHCHO) is the simplest monosaccharide sugar in the interstellar medium, and it is directly involved in the origin of life via the 'RNA world' hypothesis. We present the first detection of glycolaldehyde…
[Abridged] The detection of abundant O$_{2}$ ice at 1-10% with respect to H$_{2}$O ice in the comae of comets 1P/Halley and 67P/Churyumov-Gerasimenko motivated attempts to explain the origin of the high O$_{2}$ ice abundance. Recent…
Acetic acid (CH3COOH) was detected in the gas toward interstellar clouds, hot cores, protostars and comets. Its formation in ice mantles was proposed and acetic acid awaits detection in the infrared spectra of the ice as most other COMs…
The mechanisms which could lead to chemo-thermal instabilities and fragmentation during the formation of primordial protostars are investigated analytically. We introduce approximations for H2 cooling rates bridging the optically thin and…
No statistical study of COMs toward a large sample of high-mass protostars with ALMA has been carried out so far. We aim to study six N-bearing species: CH$_3$CN, HNCO, NH$_2$CHO, C$_2$H$_5$CN, C$_2$H$_3$CN and CH$_3$NH$_2$ in a large…
Recent interferometer observations have found that the D2O/HDO abundance ratio is higher than that of HDO/H2O by about one order of magnitude in the vicinity of low-mass protostar NGC 1333-IRAS 2A, where water ice has sublimated. Previous…
Hydrogen sulfide (H$_2$S) is thought to be efficiently formed on grain surfaces through the successive hydrogenation of S atoms. Its non-detection so far in astronomical observations of icy dust mantles thus indicates that effective…
Hexamethylentetramine has drawn a lot of attention due to its potential to produce prebiotic species. This work aims to gain a better understanding in the chemical processes concerning methylamine under astrophysically relevant conditions.…
We present the results of astrochemical modeling of complex organic molecules (COMs) in the ice and gas of the prestellar core L1544 with the recently updated MONACO rate equations-based model. The model includes, in particular,…
Nitrogen-bearing molecules are more difficult to observe than oxygen-bearing ones, mainly due to the lower abundance of nitrogen in the interstellar medium. Therefore, the formation pathways of many of these species is still under debate.…
The synthesis of water is one necessary step in the origin and development of life. It is believed that pristine water is formed and grows on the surface of icy dust grains in dark interstellar clouds. Until now, there has been no…
Sulfur dioxide (SO2) is a sulfur-containing molecule expected to exist as a solid in the interstellar medium (ISM). In this study, we performed laboratory experiments and computational analyses on the surface reactions of solid SO2 with…
Methyl formate, HCOOCH$_3$, and many of its isotopologues have been detected in astrophysical regions with considerable abundances. However, the recipe for the formation of this molecule and its isotopologues is not yet known. In this work,…