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Gas-phase processes were long thought to be the key formation mechanisms for complex organic molecules in star-forming regions. However, recent experimental and theoretical evidence has cast doubt on the efficiency of such processes.…

Astrophysics · Physics 2009-11-13 Robin T. Garrod , Susanna L. Widicus Weaver , Eric Herbst

The study of the chemical evolution of glycine in the interstellar medium is one of challenging topics in astrochemistry. Here, we present the chemical modeling of glycine in hot cores using the state-of-the-art three-phase chemical model…

Astrophysics of Galaxies · Physics 2018-08-15 Taiki Suzuki , Liton Majumdar , Masatoshi Ohishi , Masao Saito , Tomoya Hirota , Valentine Wakelam

The properties of the first-discovered interstellar object (ISO), 1I/2017 (`Oumuamua), differ from both Solar System asteroids and comets, casting doubt on a protoplanetary disk origin. In this study, we investigate the possibility that it…

Earth and Planetary Astrophysics · Physics 2021-05-05 W. Garrett Levine , Gregory Laughlin

The formyl radical HCO has been proposed as the basic precursor of many complex organic molecules such as methanol (CH$_3$OH) or glycolaldehyde (CH$_2$OHCHO). Using ALMA, we have mapped, for the first time at high angular resolution…

Astrophysics of Galaxies · Physics 2018-11-28 V. M. Rivilla , M. T. Beltrán , A. Vasyunin , P. Caselli , S. Viti , F. Fontani , R. Cesaroni

The interaction of carbon atoms with solid carbon monoxide (CO) is a fundamental process in astrochemistry, influencing the formation of complex organic molecules in interstellar environments. This study investigates the adsorption and…

Astrophysics of Galaxies · Physics 2025-09-23 Masashi Tsuge , Germán Molpeceres , Ryota Ichimura , Hideko Nomura , Kenji Furuya , Naoki Watanabe

Aims: To investigate the chemical relations between complex organics based on their spatial distributions and excitation conditions in the low-mass young stellar objects IRAS 16293-2422 A and B. Methods: Interferometric observations with…

Astrophysics · Physics 2009-11-13 S. E. Bisschop , J. K. Jorgensen , T. L. Bourke , S. Bottinelli , E. F. van Dishoeck

UV irradiation of simple ices is proposed to efficiently produce complex organic species during star- and planet-formation. Through a series of laboratory experiments, we investigate the effects of the H2O concentration, the dominant ice…

Astrophysics of Galaxies · Physics 2015-05-19 Karin I. Oberg , Ewine F. van Dishoeck , Harold Linnartz , Stefan Andersson

Water is abundantly present in the Universe. It is the main component of interstellar ice mantles and a key ingredient for life. Water in space is mainly formed through surface reactions. Three formation routes have been proposed in the…

Solar and Stellar Astrophysics · Physics 2017-08-23 H. M. Cuppen , S. Ioppolo , C. Romanzin , H. Linnartz

The formation of complex organic molecules in the interstellar medium (ISM) is central to astrochemistry and prebiotic chemistry, as these species may act as precursors to biomolecules essential for life. Although glyceraldehyde…

Astrophysics of Galaxies · Physics 2025-05-06 Anxo Lema-Saavedra , Antonio Fernández-Ramos , Emilio Martínez-Núñez

The peptide-like molecules, cyanoformamide (NCCONH2), is the cyano (CN) derivative of formamide (NH2CHO). It is known to play a role in the synthesis of nucleic acid precursors under prebiotic conditions. In this paper, we present a…

Icy grain mantles are commonly observed through infrared spectroscopy toward dense clouds, cloud cores, protostellar envelopes and protoplanetary disks. Up to 80% of the available oxygen, carbon and nitrogen are found in such ices; the most…

We investigate the role of carbon monoxide ice in the chemical evolution of prestellar cores using astrochemical rate equation models. We constrain the ratios of the binding energies on CO ice and H$_{2}$O ice for a series of adsorbates…

Astrophysics of Galaxies · Physics 2024-08-14 Germán Molpeceres , Kenji Furuya , Yuri Aikawa

The reactions of cold H atoms with solid O2 molecules were investigated at 10 K. The formation of H2O2 and H2O has been confirmed by in-situ infrared spectroscopy. We found that the reaction proceeds very efficiently and obtained the…

Astrophysics · Physics 2009-11-13 N. Miyauchi , H. Hidaka , T. Chigai , A. Nagaoka , N. Watanabe , A. Kouchi

Propyl cyanide (PrCN) (C3H7CN) with both linear and branched isomers is ubiquitous in interstellar space and is important for astrochemistry as it is one of the most complex molecules found to date in the interstellar medium. Furthermore,…

Astrophysics of Galaxies · Physics 2023-01-31 Boutheina Kerkeni , Victoria Gamez , Ghofrane Ouerfelli , Maria Luisa Senent , Nicole Feautrier

HCN is a molecule central to interstellar chemistry, since it is the simplest molecule containing a carbon-nitrogen bond and its solid state chemistry is rich. The aim of this work was to study the NH3 + HCN -> NH4+CN- thermal reaction in…

Earth and Planetary Astrophysics · Physics 2015-06-11 J. A. Noble , P. Theule , F. Borget , G. Danger , M. Chomat , F. Duvernay , F. Mispelaer , T. Chiavassa

Searches for the prebiotically-relevant cyanamide (NH$_2$CN) towards solar-type protostars have not been reported in the literature. We here present the first detection of this species in the warm gas surrounding two solar-type protostars,…

Astrochemistry is a well-established multidisciplinary field devoted to study molecules in space. While most astrochemists are oriented to observe molecules in the gas phase and reproduce their abundances by modeling the physical conditions…

Astrophysics of Galaxies · Physics 2025-12-10 Guillermo M. Muñoz Caro , Héctor Carrascosa de Lucas , Rafael Martín-Doménech

In star formation regions, the complex organic molecules (COMs) that contain peptide bonds ($-$NH$-$C(=O)$-$) play a major role in the metabolic process because $-$NH$-$C(=O)$-$ is connected to amino acids (R-CHNH$_{2}$$-$COOH). Over the…

Astrophysics of Galaxies · Physics 2024-07-09 Arijit Manna , Sabyasachi Pal

Isomerism in complex organic molecules provides key insights into the formation mechanisms and physical conditions of the interstellar medium (ISM). Among the C$_2$H$_5$NO isomers, only acetamide and trans-N-methylformamide (trans-NMF) have…

The formation of silicon monosulfide (SiS) in space appears to be a difficult process, but the present work is showing that a previously excluded pathway may contribute to its astronomical abundance. Reaction of the radicals SH + SiH…

Astrophysics of Galaxies · Physics 2024-05-21 Ryan C. Fortenberry , Brett A. McGuire