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In perovskite solar cells, photovoltaic action is created by charge transport layers (CTLs) either side of the light-absorbing metal halide perovskite semiconductor. Hence, the rates for desirable charge extraction and unwanted interfacial…

The charge accumulation properties of p-i-n perovskite solar cells were investigated using three representative organic and inorganic hole transporting layer (HTLs): a) Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS, Al…

Applied Physics · Physics 2018-07-20 Fedros Galatopoulos , Achilleas Savva , Ioannis T. Papadas , Stelios A. Choulis

Interfaces between the perovskite active layer and the charge-transport layers (CTLs) play a critical role in both efficiency and stability of halide-perovskite photovoltaics. One of the major concerns is that surface defects of perovskite…

Perovskite photovoltaics has witnessed an unprecedented increase in power conversion efficiency over the last decade. The choice of transport layers, through which photo-generated electrons and holes are transported to the electrodes, is a…

Applied Physics · Physics 2020-07-10 Eline M. Hutter , Thomas Kirchartz , Bruno Ehrler , David Cahen , Elizabeth von Hauff

We demonstrate an ionically gated planar PS-PV solar cell with ultra-thick fullerene ETL with a porous CNT electron collector on top of it. Perovskite photovoltaic devices usually have undoped electron transport layers, usually thin like…

Fundamental electronic processes such as charge-carrier transport and recombination play a critical role in determining the efficiency of hybrid perovskite solar cells. The presence of mobile ions complicates the development of a clear…

Materials Science · Physics 2020-12-17 Sebastian Reichert , Katelyn Goetz , Christopher Wöpke , Yana Vaynzof , Carsten Deibel

Transition metal oxides (TMOs) like MoOx are increasingly explored as hole transport layers for perovskite-based solar cells. Due to their large work function, the hole collection mechanism of such solar cells are fundamentally different…

Applied Physics · Physics 2021-12-08 Dhyana Sivadas , Swasti Bhatia , Pradeep Nair

Perovskite solar cells have potential to deliver terawatt-scale power via low-cost manufacturing. However, scaling is limited by slow, high-temperature annealing of the inorganic transport layers and the lack of reliable, large-area methods…

Materials Science · Physics 2022-01-25 Julia E. Huddy , Youxiong Ye , William J. Scheideler

Perovskite solar cells (PSCs) are the fastest-growing photovoltaic (PV) technology in the solar cell community and have reached an efficiency close to that of commercial silicon (Si) solar cells. The organic-inorganic halide perovskite…

Materials Science · Physics 2024-11-28 Kashimul Hossain

A modified detailed balance model is built to understand and quantify efficiency loss of perovskite solar cells. The modified model captures the light-absorption dependent short-circuit current, contact and transport-layer modified carrier…

Halide perovskite solar cells have demonstrated a rapid increase in power conversion efficiencies. Understanding and mitigating remaining carrier losses in halide perovskites is now crucial to enable further increases to approach their…

Selecting suitable charge transport layers and suppressing non-radiative recombination at interfaces to the absorber layer are vital to maximize the efficiency of halide perovskite solar cells. In this work, high-quality perovskite thin…

Using cross-correlation current noise spectroscopy, we have investigated carrier dynamics in methylammonium lead triiodide solar cells. This method provides a space selectivity for devices with planar multi-layered structure, effectively…

Applied Physics · Physics 2020-07-15 Kevin Davenport , Fei Zhang , Mark Hayward , Logan Draper , Kai Zhu , Andrey Rogachev

Halide perovskite light absorbers have great advantages for photovoltaics such as efficient solar energy absorption, but charge accumulation and recombination at the interface with an electron transport layer (ETL) remains a major challenge…

Materials Science · Physics 2020-12-18 Nikolai Tsvetkov , Byeong Cheul Moon , Jeung Ku Kang , Muhammad Ejaz Khan , Yong-Hoon Kim

The ability to reduce energy loss at semiconductor surfaces through passivation or surface field engineering has become an essential step in the manufacturing of efficient photovoltaic (PV) and optoelectronic devices. Similarly, surface…

Perovskite solar cells (PSCs) without a hole transport layer (HTL) offer a cost-effective and stable alternative to conventional architectures, utilizing only an absorber layer and an electron transport layer (ETL). This study presents a…

Machine Learning · Computer Science 2025-05-27 Ihtesham Ibn Malek , Hafiz Imtiaz , Samia Subrina

The incorporation of even small amounts of strontium (Sr) into lead-based quadruple cation hybrid perovskite solar cells results in a systematic increase of the open circuit voltage (Voc) in pin-type perovskite solar cells. We demonstrate…

Intrinsic and extrinsic ion migration is a very large threat to the operational stability of perovskite solar cells and is difficult to completely eliminate due to the low activation energy of ion migration and the existence of internal…

Applied Physics · Physics 2020-08-06 Jiangjian Shi , Yiming Li , Yusheng Li , Huijue Wu , Yanhong Luo , Dongmei Li , Qingbo Meng

Charge carrier recombination in the perovskite solar cells (PSCs) has a deep influence on the electrical performance, such as open circuit voltage, short circuit current, fill factor and ultimately power conversion efficiency. The impacts…

Mesoscale and Nanoscale Physics · Physics 2018-03-28 Lin Xing Shi , Zi Shuai Wang , Zengguang Huang , Wei E. I. Sha , Haoran Wang , Zhen Zhou

Non-radiative recombination processes are the biggest hindrance to approaching the radiative limit of the open-circuit voltage for wide-band gap perovskite solar cells. In addition, to high bulk quality, good interfaces and good energy…

Materials Science · Physics 2021-02-09 Zhifa Liu , Johanna Siekmann , Benjamin Klingebiel , Uwe Rau , Thomas Kirchartz
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