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Related papers: Tuning the Work Function of Si(100) Surface by Hal…

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The oxidation of {\alpha}-Ti(0001) surface was studied using density functional theory. In order to enhance the oxidation resistance, we substituted Ti atoms with Si atoms in Ti(0001) surface. We observe that Si prefers to segregate at the…

We have studied the adsorption of NO, and the coadsorption of N and O, on four physical and hypothetical systems: unstrained and strained Rh(100) surfaces and monolayers of Rh atoms on strained and unstrained MgO(100) surfaces. We find that…

Materials Science · Physics 2008-10-13 Raghani Pushpa , Prasenjit Ghosh , Shobhana Narasimhan , Stefano de Gironcoli

Experiments reveal negative (non-Laplacian) surface stresses in metal oxide nanoparticles, partly associated with humidity during fabrication and annealing. Using a neural network interatomic potential for MgO, we prove that water…

Materials Science · Physics 2025-03-07 Yang Hu , Vladyslav Turlo

We present the results of the modelling of CO adsorption and catalytic CO oxidation on inhomogeneous Pt(100) surfaces which contain structurally different areas. These areas are formed during the CO-induced transition from a reconstructed…

Statistical Mechanics · Physics 2008-02-09 Natalia Pavlenko

Ab initio self-consistent total energy calculations using second order Moller-Plesset perturbation theory and Hay-Wadt effective core potentials with associated basis sets (HWECP's) for gallium and arsenic have been used to investigate the…

Materials Science · Physics 2007-05-23 Michael L. Mayo , Asok K. Ray

The damage growth and surface modifications in Si(100), induced by 25 keV Si$_5^-$ cluster ions, as a function of fluence, $\phi$, has been studied using atomic force microscopy (AFM) and channeling Rutherford backscattering spectrometry…

Materials Science · Physics 2009-11-13 H. P. Lenka , B. Joseph , P. K. Kuiri , G. Sahu , P. Mishra , D. Ghose , D. P. Mahapatra

By using the density functional theory method, we systematically study the influences of the doping of an Al atom on the electronic structures of the Mg(0001) surface and dissociation behaviors of H2 molecules. We find that for the Al-doped…

Chemical Physics · Physics 2015-05-14 Yanfang Li , Yu Yang , Yinghui Wei , Ping Zhang

We present a novel method to measure transient photovoltage at nanointerfaces using ultrafast electron diffraction. In particular, we report our results on the photoinduced electronic excitations and their ensuing relaxations in a…

Materials Science · Physics 2009-11-13 Ryan A. Murdick , Ramani K. Raman , Yoshie Murooka , Chong-Yu Ruan

Ab initio total energy calculations within the framework of density functional theory have been performed for atomic hydrogen and oxygen chemisorption on the (0001) surface of double hexagonal packed americium using a full-potential…

Strongly Correlated Electrons · Physics 2015-05-14 P. P. Dholabhai , R. Atta-Fynn , A. K. Ray

Indium phosphide and derived compound semiconductors are materials often involved in high-efficiency solar water splitting due to their versatile opto-electronic properties. Surface corrosion, however, typically deteriorates the performance…

Chemical Physics · Physics 2022-11-16 Mario Löw , Margot Guidat , Jongmin Kim , Matthias M. May

Surface adsorption of C$_{60}$ affects its chemical and electronic properties. Numerous studies have reported observation of bright and dark fullerenes on metal surfaces that suggest extensive surface reconstruction, however, the…

Materials Science · Physics 2021-12-01 Leonardo Forcieri , Simon Taylor , Philip Moriarty , Samuel P Jarvis

We present a response-augmented machine learning (ML) approach to the energetics of electrified metal surfaces. We leverage local descriptors to learn the work function as the first-order energy change to introduced bias charges and…

Materials Science · Physics 2025-05-27 Nicolas Bergmann , Nicéphore Bonnet , Nicola Marzari , Karsten Reuter , Nicolas G. Hörmann

The fabrication of nanomaterials involves self-ordering processes of functional molecules on inorganic surfaces. To obtain specific molecular arrangements, a common strategy is to equip molecules with functional groups. However, focusing on…

Mesoscale and Nanoscale Physics · Physics 2021-04-28 Andreas Jeindl , Jari Domke , Lukas Hörmann , Falko Sojka , Roman Forker , Torsten Fritz , Oliver T. Hofmann

Surfaces of metal oxides at working conditions are usually electrified due to the acid-base chemistry. The charged interface compensated with counterions forms the so-called electric double layer. The coupling of surface chemistry and…

Soft Condensed Matter · Physics 2019-07-02 Chao Zhang , Jürg Hutter , Michiel Sprik

At the surfaces of materials, the bulk symmetry of the charge density is broken and electron spill-out into the vacuum region creates a surface dipole. Such spill-out has been historically calculated by Lang and Kohn [Phys. Rev. B…

Materials Science · Physics 2022-09-20 Zeyu Jiang , Damien West , Shengbai Zhang

Electron stimulated desorption of cyclopentene from the Si(100)-2x1 surface is studied experimentally with cryogenic UHV STM and theoretically with transport, electronic structure, and dynamical calculations. Unexpectedly for a saturated…

Mesoscale and Nanoscale Physics · Physics 2016-08-31 N. L. Yoder , N. P. Guisinger , M. C. Hersam , R. Jorn , C. -C. Kaun , T. Seideman

Previous experimental observations for H intercalation under graphene on SiC surfaces motivate clarification of configuration stabilities and kinetic processes related to intercalation. From first-principles density-functional-theory (DFT)…

Mesoscale and Nanoscale Physics · Physics 2021-12-08 Yong Han , James W. Evans , Michael C. Tringides

This paper reports a study of the influence of the step at a silicon surface under an uniaxial tensile stress, using an empirical potential. Our aim was to find conditions leading to nucleation of dislocations from the step. We obtained…

Materials Science · Physics 2007-09-12 Julien Godet , Laurent Pizzagalli , Sandrine Brochard , Pierre Beauchamp

Electronic decoupling of graphene from metallic and semiconducting substrates via intercalation of different species is one of the widely used approaches in studies of graphene. In the present work the modification of the electronic and…

Materials Science · Physics 2021-12-24 Yong Zhou , Roman Ovcharenko , Beate Paulus , Yuriy Dedkov , Elena Voloshina

The adsorption and dissociation of H$_2$, O$_2$, and H$_2$O on Ni-Fe alloys with variable Fe:Ni ratio are studied by means of Density Functional Theory calculations. The alloy composition deeply influences the thermochemistry of the…

Materials Science · Physics 2024-10-28 Changyuan Li , Sergio Tosoni