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We investigate the adsorption of a Ni monolayer on the $\beta$-SiC(001) surface by means of highly precise first-principles all-electron FLAPW calculations. Total energy calculations for the Si- and C-terminated surfaces reveal high Ni-SiC…

Materials Science · Physics 2009-11-07 G. Profeta , A. Continenza , A. J. Freeman

Here we demonstrate that significant progress in this area may be achieved by introducing structural elements that form hydrogen bonds with environment. Considering several examples of hybrid framework materials with different structural…

Control of dopants in silicon remains the most important approach to tailoring the properties of electronic materials for integrated circuits, with Group V impurities the most important n-type dopants. At the same time, silicon is finding…

We revisit the derivation of multipole contributions to the atom-wall interaction previously presented in [G. Lach et al., Phys. Rev. A 81, 052507 (2010)]. A careful reconsideration of the angular-momentum decomposition of the second-,…

Atomic Physics · Physics 2024-01-12 Ulrich D. Jentschura

Graphene monolayer grown by Si evaporation from the 0001 surface of SiC displays a moir\'e pattern of corrugation whose structure is ambiguous: different measurements and theoretical studies show either protruding bumps surrounded by…

Mesoscale and Nanoscale Physics · Physics 2018-04-27 Tommaso Cavallucci , Valentina Tozzini

Si deposition on H terminated Si(100)-2x1 and 3x1 surfaces at temperatures 300-530 K is studied by scanning tunneling microscopy. Hydrogen apparently hinders Si adatom diffusion and enhances surface roughening. The post-growth annealing…

Materials Science · Physics 2009-11-10 Jeong-Young Ji , T. -C. Shen

Metal-organic molecular adsorbates on metallic surfaces offer the potential to both generate materials for future (spin-)electronics applications as well as a better fundamental understanding of molecule-substrate interaction, provided that…

Materials Science · Physics 2024-09-17 A. Eschenlohr , R. Shi , J. Chen , P. Zhou , U. Bovensiepen , W. Hübner , G. Lefkidis

The thermal transport across inorganic/organic interfaces attracts interest for both academic and industry due to its widely applications in flexible electronics etc. Here, the interfacial thermal conductance of inorganic/organic interfaces…

Materials Science · Physics 2023-06-13 Zhicheng Zong , Shichen Deng , Yangjun Qin , Xiao Wan , Jiahong Zhan , Dengke Ma , Nuo Yang

In this work we investigate the effects of the environment on the X-ray photoelectron spectra of hydrogen chloride and the chloride ions adsorbed on ice surfaces, as well as of chloride ions in water droplets. In our approach, we combine a…

Chemical Physics · Physics 2023-09-18 Richard A. Opoku , Céline Toubin , André Severo Pereira Gomes

Density functional theory calculations for the electronic structures of the 4H-SiC(0001)/SiO$_2$ interface with atomic-scale steps are carried out to investigate the effect of NO annealing. The characteristic behavior of the conduction band…

Materials Science · Physics 2024-01-09 Mitsuharu Uemoto , Nahoto Funaki , Kazuma Yokota , Takuji Hosoi , Tomoya Ono

Computational studies of electrochemical interfaces based on density-functional theory (DFT) play an increasingly important role in present research on electrochemical processes for energy conversion and storage. The homogeneous background…

Materials Science · Physics 2022-04-26 Arthur Hagopian , Marie-Liesse Doublet , Jean-Sébastien Filhol , Tobias Binninger

Designing metal-semiconductor junctions is essential for optimizing the performance of modern nanoelectronic devices. A widely used material is TiSi$_2$, which combines low electronic resistivity with good endurance. However, its multitude…

Materials Science · Physics 2026-01-16 Lukas Hückmann , Jonathon Cottom , Jörg Meyer , Emilia Olsson

We report an experimental refinement of the local charge density at the Si (111) 7x7 surface utilizing a combination of x-ray and high energy electron diffraction. By perturbing about a bond-centered pseudoatom model, we find experimentally…

Materials Science · Physics 2015-05-13 J. Ciston , A. Subramanian , I. K. Robinson , L. D. Marks

For the most precise incorporation of single impurities in silicon, which is utilized to create quantum devices, a monolayer of adatoms on the Si(100) surface and a dopant-containing molecule are used. Here we studied the interaction of a…

Materials Science · Physics 2023-11-30 T. V. Pavlova , V. M. Shevlyuga

Metal-organic interfaces determine critical processes in organic electronic devices. The frontier molecular orbitals (highest occupied and lowest unoccupied molecular orbital, HOMO and LUMO) are crucial in determining charge-injection and…

Materials Science · Physics 2025-04-09 Anubhab Chakraborty , Oliver L. A. Monti

Atomic and electronic structures of TiO_2(110) surface with possible adsorptional, substitutional and interstitial Au or Pt elemental impurities at full and one-sixth monolayer concentrations were investigated by density functional theory…

Strongly Correlated Electrons · Physics 2012-11-19 Ersen Mete , Oğuz Gülseren , Şinasi Ellialtıoğlu

We investigate the chemical and structural configuration of acetophenone on Si(001) using synchrotron radiation core-level spectroscopy techniques and density functional theory calculations. Samples were prepared by vapour phase dosing of…

Materials Science · Physics 2015-06-22 Kane M. O'Donnell , Oliver Warschkow , Asif Suleman , Adam Fahy , Lars Thomsen , Steven R. Schofield

The dissociation of hydrogen molecules on the \gamma-U(100) surface is systematically studied with the density functional theory method. Through potential energy surface calculations, we find that hydrogen molecules can dissociate without…

Materials Science · Physics 2011-10-27 Yu Yang , Ping Zhang , Peng Shi , Xiaolin Wang

We study the relaxations, surface energies, and work functions of low index metallic surfaces using pseudopotential plane-wave density-functional calculations within the generalized gradient approximation. We study here the (100), (110),…

Materials Science · Physics 2015-05-13 Nicholas E. Singh-Miller , Nicola Marzari

Renewed focus on the P-Si system due to its potential application in quantum computing and self-directed growth of molecular wires, has led us to study structural changes induced by P upon placement on Si(001)-$p(2\times 1)$. Using…

Materials Science · Physics 2009-11-11 Prasenjit Sen , Bikash C Gupta , Inder P. Batra
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