Related papers: Ultrafast infrared spectroscopy with single molecu…
We present an all-optical mass spectrometry technique to identify trapped ions. The new method uses laser-cooled ions to determine the mass of a cotrapped dark ion with a sub-dalton resolution within a few seconds. We apply the method to…
Photoelectron spectroscopy in intense laser fields has proven to be a powerful tool for providing detailed insights into molecular structure. The ionizing molecular orbital, however, has not been reconstructed from the photoelectron…
Optical spectroscopy in the gas phase is a key tool to elucidate the structure of atoms and molecules and of their interaction with external fields. The line resolution is usually limited by a combination of first-order Doppler broadening…
A single-atom 'double-slit' experiment is realized by photo-ionizing Rubidium atoms using two independent low power lasers. The photoelectron wave of well-defined energy recedes to the continuum either from the 5P or 6P states in the same…
While it is straightforward to count laser-cooled trapped ions by fluorescence imaging, detecting the number of dark ions embedded and sympathetically cooled in a mixed ion crystal is more challenging. We demonstrate a method to track the…
We describe, realize, and experimentally investigate a method to perform physical rotations of ion chains, trapped in a segmented surface Paul trap, as a building block for large scale quantum computational sequences. Control of trapping…
We investigate in detail the effects of a QND vibrational number measurement made on single ions in a recently proposed measurement scheme for the vibrational state of a register of ions in a linear rf trap [C. D'Helon and G.J. Milburn,…
The coupled motion of ions in a radiofrequency trap has been used to connect the frequency- dependent laser-induced heating of a sympathetically cooled spectroscopy ion with changes in the fluorescence of a laser-cooled control ion. This…
We experimentally demonstrate fast separation of a two-ion crystal in a microstructured segmented Paul trap. By the use of spectroscopic calibration routines for the electrostatic trap potentials, we achieve the required precise control of…
Present photoionization experiments cannot measure molecular frame photoelectron angular distributions (MFPAD) from the outermost valence electrons of molecules. We show that details of the MFPAD can be retrieved with high-order harmonics…
The interaction between the electric dipole moment of a trapped molecular ion and the configuration of the confined Coulomb crystal couples the orientation of the molecule to its motion. We consider the practical feasibility of harnessing…
We have developed a novel scheme to measure the secular motion of trapped ions. Employing pulsed excitation and analysis of the fluorescence of laser cooled ions, we have measured the centre-of-mass mode frequency of single as well as…
By analyzing ``exact'' theoretical results from solving the time-dependent Schr\"odinger equation of atoms in few-cycle laser pulses, we established the general conclusion that differential elastic scattering and photo-recombination cross…
The ion-electron coupling properties for a ion impurity in an electron gas and for a two component plasma are carried out on the basis of a regularized electron-ion potential removing the short-range Coulomb divergence. This work is largely…
A recent expansion of cold and ultracold molecule applications has led to renewed focus on molecular species preparation under ultrahigh vacuum conditions. Meanwhile, molecular beams have been used to study gas phase chemical reactions for…
We report on three-dimensional optical trapping of single ions in an optical lattice formed by two counter-propagating laser beams. We characterize the trapping parameters of the standing wave using the ion as a sensor stored in a hybrid…
Absorption cells filled with diatomic iodine are frequently employed as wavelength reference for high-precision stellar radial velocity determination due their long-term stability and low cost. Despite their wide-spread usage in the…
We coincidently measure the molecular frame photoelectron angular distribution and the ion sum-momentum distribution of single and double ionization of CO molecules by using circularly and elliptically polarized femtosecond laser pulses,…
Modern experiments with cold molecular ions have reached a high degree of complexity requiring frequent sample preparation, state initialization and protocol execution while demanding precise control over multiple devices and laser sources.…
Trapped ions are ideally suited for precision spectroscopy, as is evident from the remarkably low systematic uncertainties of single-ion clocks. The major weakness of these clocks is the long averaging time, necessitated by the low signal…