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Related papers: Ultrafast intermolecular energy transfer from vibr…

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We recently proposed effective normal modes for excitonically coupled aggregates which exactly transform the energy transfer Hamiltonian into a sum of one-dimensional Hamiltonians along the effective normal modes. Identifying physically…

Chemical Physics · Physics 2022-05-25 Sanjoy Patra , Vivek Tiwari

By making use of the Green function concept of quantization of the electromagnetic field in Kramers--Kronig consistent media, a rigorous quantum mechanical derivation of the rate of intermolecular energy transfer in the presence of…

Quantum Physics · Physics 2016-08-16 Ho Trung Dung , Ludwig Knöll , Dirk-Gunnar Welsch

We present a way of partly reincorporate the effects of the localized bonding electrons on the dynamics of their itinerant counterparts in Hubbard-like Hamiltonians. This is done by relaxing the constraint that the former should be entirely…

Strongly Correlated Electrons · Physics 2020-09-23 T. V. Trevisan , Gustavo M. Monteiro , A. O. Caldeira

The nonlinear optical dynamics of nano-materials comprised of plasmons interacting with quantum emitters is investigated by a self-consistent model based on the coupled Maxwell-Liouville-von Neumann equations. It is shown that ultra-short…

Mesoscale and Nanoscale Physics · Physics 2013-12-04 Maxim Sukharev , Tamar Seideman , Robert J. Gordon , Adi Salomon , Yehiam Prior

We show how to teleport reliably an arbitrary superposition of n=0 and n=1 vibrational number state between two distant ions. This is done by first mapping the vibrational state to be teleported into the internal degrees of freedom of a…

Quantum Physics · Physics 2016-09-08 N. G. de Almeida , C. J. Villas-Boas , E. Solano , M. H. Y. Moussa

Photoionization by high-energy photons creates nonthermal electrons with a broad range of energies that heat and chemically transform the atmospheres of planets. The specifics of the interactions are notably different when the gas is atomic…

Earth and Planetary Astrophysics · Physics 2025-06-17 Antonio García Muñoz , Ewan Bataille

Electron transmission through molecules and molecular interfaces has been a subject of intensive research due to recent interest in electron transfer phenomena underlying the operation of the scanning tunneling microscope (STM) on one hand,…

Condensed Matter · Physics 2015-06-24 Abraham Nitzan

Electron transfer at electrode interfaces to molecules in solution or at the electrode surface plays a vital role in numerous technological processes. However, treating these processes requires a unified and accurate treatment of the…

Chemical Physics · Physics 2023-07-19 Kenneth A. Jung , Joseph Kelly , Thomas E. Markland

F\"{o}rster energy transfer underpins modern photonics, yet establishing an analogous vibrational pathway in the mid-infrared (MIR) remains highly challenging, as sub-picosecond intramolecular vibrational redistribution (IVR) suppresses…

Intramolecular energy transfer driven by near-field effects plays an important role in applications ranging from biophysics and chemistry to nano-optics and quantum communications. Advances in strong light-matter coupling in molecular…

Mesoscale and Nanoscale Physics · Physics 2025-07-14 Kristin B. Arnardottir , Piper Fowler-Wright , Christos Tserkezis , Brendon W. Lovett , Jonathan Keeling

In the present work, the analytical description of an intermolecular vibrational energy transfer, analyzed by two dimensional infrared spectroscopy, is established. The energy transfer process takes place between the dark combination states…

Chemical Physics · Physics 2013-09-04 Albert A. Villaeys , Kuo Kan Liang

The roles of the vibration motions played in the excitation energy transfer process are studied. It is found that a strong coherent transfer in the hybrid system emerges when the detuning between the donor and the acceptor equals the…

Biological Physics · Physics 2014-12-18 Xin Wang , Hao Chen , Hong-rong Li

An ultrafast mechanism belonging to the family of interatomic Coulombic decay (ICD) phenomena is proposed. When two excited species are present, an ultrafast energy transfer can take place bringing one of them to its ground state and…

Under certain conditions, the ionization of a molecule may create a superposition of electronic states, leading to ultrafast electron dynamics. If controlled, this motion could be used in attochemistry applications, but it has been shown…

Chemical Physics · Physics 2024-09-26 Alan Scheidegger , Nikolay V. Golubev , Jiří Vaníček

We propose a mechanism which allows one to control the transmission of single electrons through a molecular junction. The principle utilizes the emergence of transmission sidebands when molecular vibrational modes are coupled to the…

Mesoscale and Nanoscale Physics · Physics 2010-03-26 Thomas Olsen , Jakob Schiøtz

The rate of electron transfer between a molecular species and a metal, each at a different local temperature, is examined theoretically through implementation of a bithermal (characterized by two temperatures) Marcus formalism. Expressions…

Mesoscale and Nanoscale Physics · Physics 2019-08-02 Galen T. Craven , Abraham Nitzan

We show that the efficient excitation energy transfer in the Fenna-Matthews-Olson molecular aggregate under realistic physiological conditions is fueled by underdamped vibrations of the embedding proteins. For this, we present numerically…

Chemical Physics · Physics 2013-11-26 P. Nalbach , C. A. Mujica-Martinez , M. Thorwart

The theory of energy transfer dynamics of a pair of donor and acceptor molecules located in the plasmonic hot spots is developed by means of the master equation approach and the electromagnetic Green's tensor technique. A nonlocal effect…

Optics · Physics 2017-12-29 Jun Ren , Tian Chen , Bo Wang , Xiangdong Zhang

The influence of an electron-vibrational coupling on the laser control of electron transport through a molecular wire that is attached to several electronic leads is investigated. These molecular vibrational modes induce an effective…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Jörg Lehmann , Sigmund Kohler , Volkhard May , Peter Hänggi

Dynamical charge transfer processes at molecule-metal interfaces proceed in the few fs time scale that renders them highly relevant to electronic excitations in optoelectronic devices. Yet, knowledge thereof is limited when electronic…

Materials Science · Physics 2021-03-24 Peter Jakob , Sebastian Thussing