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The electronic energy gap and total dipole moment of chemically functionalized hexagonal and triangular graphene quantum dots are investigated by the density functional theory. It has been found that the energy gap can be efficiently tuned…

Mesoscale and Nanoscale Physics · Physics 2018-03-14 Hazem Abdelsalam , Hanan Elhaes , Medhat A. Ibrahim

The structure stability and electronic properties of edge carboxylated hexagonal and triangular graphene quantum dots are investigated by using density functional theory. The calculated binding energies show that the hexagonal clusters with…

Mesoscale and Nanoscale Physics · Physics 2018-03-14 Hazem Abdelsalam , Hanan Elhaes , Medhat A. Ibrahim

We study electronic and optical properties of single layer phosphorene quantum dots with various shapes, sizes, and edge types (including disordered edges) subjected to an external electric field normal to the structure plane. Compared to…

Mesoscale and Nanoscale Physics · Physics 2017-08-29 V. A. Saroka , I. Lukyanchuk , M. E. Portnoi , H. Abdelsalam

We theoretically investigate the electronic and magneto-optical properties of rectangular, hexangular, and triangular monolayer phosphorene quantum dots (MPQDs) utilizing the tight-binding method. The electronic states, density of states,…

Mesoscale and Nanoscale Physics · Physics 2015-12-10 Rui Zhang , X. Y. Zhou , D. Zhang , W. K. Lou , F. Zhai , Kai Chang

The impact of vacancies on spin-resolved electronic properties of quantum dots (QDs) in phosphorene-based junctions, are investigated numerically. Regardless of the crystal orientation, a phosphorene nanoribbon (PNR) containing a…

Mesoscale and Nanoscale Physics · Physics 2024-11-05 Maryam Mahdavifar , Farhad Khoeini , Francois M. Peeters

Recently, black phosphorus quantum dots were fabricated experimentally. Motivated by these experiments, we theoretically investigate the electronic and optical properties of rectangular phosphorene quantum dots (RPQDs) in the presence of an…

Mesoscale and Nanoscale Physics · Physics 2017-01-25 L. L. Li , D. Moldovan , W. Xu , F. M. Peeters

Recent reports on the fabrication of phosphorene, i.e., mono- or few-layer black phosphorus, have raised exciting prospects of an outstanding two-dimensional (2D) material that exhibits excellent properties for nanodevice applications. Here…

Materials Science · Physics 2014-06-11 Liangzhi Kou , Thomas Frauenheim , Changfeng Chen

We have carried out first-principles calculations on electronic properties of graphene quantum dots embedded in hexagonal boron nitride monolayer sheets. The calculations with density functional theory show that the band gaps of quantum…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 Junwen Li , Vivek B. Shenoy

The possibility of an inhomogeneous charge density wave phase is investigated in a system of two coupled electron and hole monolayers separated by a hexagonal boron nitride insulating layer. The charge density wave state is induced through…

Mesoscale and Nanoscale Physics · Physics 2018-12-26 S. Saberi-Pouya , M. Zarenia , T. Vazifehshenas , F. M. Peeters

Spectral and transport properties of electrons in confined phosphorene systems are investigated in a five hopping parameter tight-binding model, using analytical and numerical techniques. The main emphasis is on the properties of the…

Mesoscale and Nanoscale Physics · Physics 2016-03-23 B. Ostahie , A. Aldea

The goal of the present study is to explore how the size and functionalization of graphene quantum dots (GQDs) affect their sensing capabilities. Specifically, we investigated the adsorption of SO$_2$, SOF$_2$, SO$_2$F$_2$, and SF$_6$ on…

Chemical Physics · Physics 2023-04-26 Vaishali Roondhe , Basant Roondhe , Sumit Saxena , Rajeev Ahuja , Alok Shukla

In this work, the electronic properties of phosphorene nanoribbons with different width and edge configurations are studied by using density functional theory. It is found that the armchair phosphorene nanoribbons are semiconducting while…

Mesoscale and Nanoscale Physics · Physics 2015-02-24 J. Zhang , H. J. Liu , L. Cheng , J. Wei , J. H. Liang , D. D. Fan , J. Shi , X. F. Tang , Q. J. Zhang

Phosphorene, the monolayer form of the (black) phosphorus, was recently exfoliated from its bulk counterpart. Phosphorene oxide, by analogy to graphene oxide, is expected to have novel chemical and electronic properties, and may provide an…

Materials Science · Physics 2015-06-22 Gaoxue Wang , Ravindra Pandey , Shashi P. Karna

Phosphorene is a bidimensional material that has properties useful for semiconductor devices. In this work we studied the electronic and optical properties of this material using the $GW$ approximation and the Bethe-Salpeter equation (BSE)…

Mesoscale and Nanoscale Physics · Physics 2017-11-16 Fábio Ferreira , Ricardo Mendes Ribeiro

We present density functional theory calculations of phosphorus dopants in bulk silicon and of several properties relating to their use as spin qubits for quantum computation. Rather than a mixed pseudopotential or a Heitler-London…

Mesoscale and Nanoscale Physics · Physics 2015-06-12 Loren Greenman , Heather D. Whitley , K. Birgitta Whaley

Using the tight-binding approach, we investigate the thermoelectric (TE) properties of rectangular phosphorene nanorings for both symmetrically and asymmetrically attaching to phosphorene nanoribbon leads. We design our phosphorene-based…

Mesoscale and Nanoscale Physics · Physics 2023-08-09 Fatemeh Moghadasi Borojeni , Esmaeil Taghizadeh Sisakht , Farhad Fazileh , F. M. Peeters

Nonmonotonic bending-induced changes of fundamental band gaps and quasiparticle energies are observed for realistic nanoscale phosphorene nanosheets. Calculations using stochastic many-body perturbation theory (sGW) show that even slight…

Materials Science · Physics 2019-06-12 Vojtech Vlcek , Eran Rabani , Roi Baer , Daniel Neuhauser

Recent photoabsorption measurements have revealed a rich fine structure in the collective charge-density excitation spectrum of few-electron quantum dots in the presence of magnetic fields. We have performed systematic computational studies…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 C. A. Ullrich , G. Vignale

We report the quasiparticle band gap, excitons, and highly anisotropic optical responses of few-layer black phosphorous (phosphorene). It is shown that these new materials exhibit unique many-electron effects; the electronic structures are…

Mesoscale and Nanoscale Physics · Physics 2014-06-27 Vy Tran , Ryan Soklaski , Yufeng Liang , Li Yang

Density functional theory has been used to study the adsorption of molecular H2 on a graphene layer. Different adsorption sites on top of atoms, bonds and the center of carbon hexagons have been considered and compared. We conclude that the…

Chemical Physics · Physics 2009-11-06 J. S. Arellano , L. M. Molina , A. Rubio , J. A. Alonso
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