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Room temperature ionic liquids are attractive to numerous applications and particularly, to renewable energy devices. As solvent free electrolytes, they demonstrate a paramount connection between the material morphology and Coulombic…

Chemical Physics · Physics 2016-03-15 Nir Gavish , Arik Yochelis

We study the kinetics of the liquid-to-crystal transformation and of gel formation in colloidal suspensions of oppositely charged particles. We analyse, by means of both computer simulations and experiments, the evolution of a fluid…

The equilibrium phase diagram of a 1:1 symmetrical mixture composed of oppositely charged colloids is calculated using Monte Carlo simulations. We model the system by the DLVO effective interaction potential. The phase diagram is similar to…

Soft Condensed Matter · Physics 2007-05-23 José B. Caballero , Antonio M. Puertas

Solid ionic conductors are essential components of batteries and fuel cells. In many cases, ionic conduction through crystalline materials with substitutional disorder can be modeled with atomic-scale lattice model percolation simulations.…

Materials Science · Physics 2023-02-15 Alexander Urban

The structure of ionic adsorption layers is studied via a proper thermodynamic treatment of the electrostatic and non-electrostatic interactions between the surfactant ions as well as of the effect of thermodynamic non-locality. The…

Soft Condensed Matter · Physics 2014-10-28 R. Tsekov

Ionic liquids are solvent-free electrolytes, some of which possess an intriguing self-assembly property. Using a mean-field framework (based on Onsager's relations) we show that bulk nano-structures arise via type-I and II phase transitions…

Soft Condensed Matter · Physics 2017-06-07 Sariel Bier , Nir Gavish , Hannes Uecker , Arik Yochelis

Can liquid-like and gas-like states be distinguished beyond the critical point, where the liquid-gas phase transition no longer exists and conventionally only a single supercritical fluid phase is defined? Recent experiments and simulations…

Statistical Mechanics · Physics 2024-04-30 Xinyang Li , Yuliang Jin

In the last years, the potential of using ionic liquids (IL)s as an environment for nanoparticle (NP) synthesis has been demonstrated and in particular, triggering NP formation in ILs by electron irradiation has been reported as a very…

Chemical Physics · Physics 2023-06-28 Marta Bon , Debora Keller , Rolf Erni , Daniele Passerone

We investigate crystal nucleation in supersaturated colloid suspensions using enhanced molecular dynamics simulations augmented with machine learning techniques. The simulations reveal that crystallization in the model colloidal system…

Soft Condensed Matter · Physics 2024-04-30 Vanessa J. Meraz , Ziyue Zou , Pratyush Tiwary

Liquid-liquid transition is an intriguing phenomenon in which a liquid transforms into another liquid via the first-order transition. For molecular liquids, however, it always takes place in a supercooled liquid state metastable against…

Soft Condensed Matter · Physics 2016-11-23 Mika Kobayashi , Hajime Tanaka

Blue phase liquid crystal (BPLC) has important applications in adaptive lenses and phase modulators due to its polarization-independent property. During our efforts for development of the new materials, we found a novel phenomenology of…

Optics · Physics 2015-10-29 Prasenjit Nayek , Sebastian Gauza , Guoqiang Li

Using Monte Carlo simulations we study crystallization in the three-dimensional Ising model with four-spin interaction. We monitor the morphology of crystals which grow after placing crystallization seeds in a supercooled liquid. Defects in…

Materials Science · Physics 2009-11-07 A. Lipowski , D. Johnston

We study the nonequilibrium dynamics of the linear to zigzag structural phase transition exhibited by an ion chain confined in a trap with periodic boundary conditions. The transition is driven by reducing the transverse confinement at a…

We model molecular cloud fragmentation with thin disk non-ideal magnetohydrodynamic simulations that include ambipolar diffusion and partial ionization that transitions from primarily ultraviolet dominated to cosmic ray dominated regimes.…

Solar and Stellar Astrophysics · Physics 2015-06-17 Nicole D. Bailey , Shantanu Basu

We present a dielectric study on the dynamics of supercooled glycerol during crystallization. We explore the transformation into a solid phase in real time by monitoring the temporal evolution of the amplitude of the dielectric signal.…

Soft Condensed Matter · Physics 2017-03-01 Alejandro Sanz , Kristine Niss

The nucleation of crystals in liquids is one of nature's most ubiquitous phenomena, playing an important role in areas such as climate change and the production of drugs. As the early stages of nucleation involve exceedingly small time and…

We employ a field-theoretical variational approach to study the behavior of ionic solutions in the grand canonical ensemble. To describe properly the hardcore interactions between ions, we use a cutoff in Fourier space for the electrostatic…

Soft Condensed Matter · Physics 2016-10-03 Bastien Loubet , Manoel Manghi , John Palmeri

Liquid crystals are synthetic and biological viscoelastic anisotropic soft matter materials that combine liquid fluidity with crystal anisotropy and find use in optical devices, sensor/actuators, lubrication, super-fibers. Frequently…

Soft Condensed Matter · Physics 2013-11-22 Ezequiel R. Soule , Alejandro D. Rey

A liquid droplet is fragmented by a sudden pressurized-gas blow, and the resulting droplets, adhered to the window of a flatbed scanner, are counted and sized by computerized means. The use of a scanner plus image recognition software…

Statistical Mechanics · Physics 2009-11-13 Cristian F. Moukarzel , Silvia F. Fernandez-Sabido , J. C. Ruiz-Suarez

We experimentally investigate the critical behavior of a phase transition between two topologically different turbulent states of electrohydrodynamic convection in nematic liquid crystals. The statistical properties of the observed…

Statistical Mechanics · Physics 2008-01-14 Kazumasa A. Takeuchi , Masafumi Kuroda , Hugues Chaté , Masaki Sano