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We report the growth and physical properties of single-crystalline Bi$_2$Ta$_3$S$_6$ crystallizing in $P6_3/mcm$ space group, which comprises alternating Ta-S layers and Bi layers with each Bi atom connected with adjacent S atoms.…

Very recent report [1] on observation of superconductivity in Bi4O4S3 could potentially reignite the search for superconductivity in a broad range of layered sulphides. We report here synthesis of Bi4O4S3 at 5000C by vacuum encapsulation…

Superconductivity · Physics 2012-11-21 Shiva Kumar Singh , Anuj Kumar , Bhasker Gahtori , Shruti Kirtan , G. Sharma , S. Patnaik , V. P. S. Awana

van der Waals (vdW) layered transition-metal chalcogenides are attracting significant attention owing to their fascinating physical properties. This group of materials consists of abundant members with various elements, having a variety of…

We report on the synthesis and extensive characterization of layered Bi4O4S3 superconductor. This is the optimally doped sample with Tc ~5.3 K out of a series of Bi6O4S4(SO4)_1-x samples synthesized by solid state reaction. The series was…

Superconductivity · Physics 2013-04-17 P. Srivatsava , Shruti , S. Patnaik

Single crystal of La(O,F)BiSe2 was successfully grown for the first time by the CsCl flux method. Single crystal X-ray structural analysis clearly showed that La(O,F)BiSe2 crystalizes with space group P4/nmm (lattice parameters a =…

A new layered Ti-based pnictide oxide superconductor, Ba1-xNaxTi2Sb2O (0.0 <= x <= 0.33), is reported. X-ray studies reveal it crystallizes in the tetragonal CeCr2Si2C structure. The undoped parent compound, BaTi2Sb2O (P4/mmm;…

We found La2Sb with a layered structure composed of alternate stacking of La square nets and LaSb layers exhibits bulk superconductivity with a critical temperature of 5.3 K. This suggests that the presence of the square net with strong…

Superconductivity · Physics 2011-08-02 Hiroshi Mizoguchi , Hideo Hosono

Layered transition-metal dichalcogenides 1T-TaS2-xSex (0<=x<=2) single crystals have been successfully fabricated by using a chemical vapor transport technique in which Ta locates in octahedral coordination with S and Se atoms. This is the…

Superconductivity · Physics 2013-03-28 Yu Liu , Ran Ang , Wenjian Lu , Wenhai Song , Lijun Li , Yuping Sun

By replacing the alkali element in the newly discovered K2Mo3As3 superconductor, we successfully synthesized ternary molybdenum pnictides Rb2Mo3As3 and Cs2Mo3As3 through solid state reaction method. Powder X-ray diffraction analysis reveals…

Superconductivity · Physics 2018-05-30 Kang Zhao , Qing-Ge Mu , Tong Liu , Bo-Jin Pan , Bin-Bin Ruan , Lei Shan , Gen-Fu Chen , Zhi-An Ren

Identification of superconductivity in the Ruddlesden-Popper phases of nickelates under high pressure remains challenging. Here, we report a comprehensive study of the crystal structure, resistance, and Meissner effect in single crystals of…

The pressure-induced high-temperature superconductivity(Tc) in nickelates La3Ni2O7-x has sparked significant interest to explore its superconductivity at ambient pressure.Lan+1NinO3n+1(n=2,3)adopts an orthorhombic structure with tilted NiO6…

Altermagnets (AMs), characterized by zero net magnetization and momentum-dependent spin splitting, are anticipated to hold significant potential for generating multiple exotic and uncommon superconducting states. However, superconductivity…

Superconductivity · Physics 2026-04-02 Y. Sun , Z. Yin , T. Zhang , L. Wang , B. Ruan , Y. Huang , J. He , W. Zhu , M. Ma , J. Bai , J. Cheng , Q. Dong , C. Li , P. Liu , Q. Liu , C. Zhang , G. Chen

A recent experiment reported the first rare-earth binary oxide superconductor LaO ($T_c $ $\sim$ 5 K) with a rock-salt structure [K. Kaminaga et al., J. Am. Chem. Soc. 140, 6754 (2018)]. Correspondingly, the underlying superconducting…

Superconductivity · Physics 2021-07-14 Pei-Han Sun , Jian-Feng Zhang , Kai Liu , Qiang Han , Zhong-Yi Lu

Here we report the discovery of the first ternary molybdenum pnictide based superconductor K2Mo3As3. Polycrystalline samples were synthesized by the conventional solid state reaction method. X-ray diffraction analysis reveals a…

Superconductivity · Physics 2018-08-02 Qing-Ge Mu , Bin-Bin Ruan , Kang Zhao , Bo-Jin Pan , Tong Liu , Lei Shan , Gen-Fu Chen , Zhi-An Ren

Here, we report the discovery of superconductivity in a new transition metal-chalcogenide compound, i.e. Nb2Pd0.81S5, with a transition temperature Tc > 6.6 K. Despite its relatively low Tc, it displays remarkably high and anisotropic…

Superconductivity · Physics 2013-03-14 Q. Zhang , G. Li , D. Rhodes , A. Kiswandhi , T. Besara , B. Zeng , J. Sun , T. Siegrist , M. D. Johannes , L. Balicas

We report the electrical, magnetic and thermal measurements on a layered cobalt oxyhydrate Na$_{0.31}$CoO$_{2}\cdot$1.3H$_{2}$O. Bulk superconductivity at 4.3 K has been confirmed, however, the measured superconducting fraction is…

Superconductivity · Physics 2009-11-10 Guanghan Cao , Chunmu Feng , Yi Xu , Wen Lu , Jingqin Shen , Minghu Fang , Zhu'an Xu

Novel structural building blocks in compounds could induce interesting physical and chemical properties. Although phosphorus tends to form very different motifs, the existence of lone pair electrons has always prevented the formation of…

Superconductivity · Physics 2022-01-13 Xing Li , Xiaohua Zhang , Aitor Bergara , Guoying Gao , Yong Liu , Guochun Yang

Superconductivity is observed with critical temperatures near 9K in the tetragonal compound Mo5PB2. This material adopts the Cr5B3 structure type common to supercondcuting Nb5Si3-xBx, Mo5SiB2, and W5SiB2, which have critical temperatures of…

Superconductivity · Physics 2016-03-10 Michael A. McGuire , David S. Parker

Polycrystalline samples of F-substituted LnOBiS2 (Ln = La, Ce, Pr, Nd, Yb) compounds were synthesized by solid-state reaction. The samples were characterized by x-ray diffraction measurements and found to have the ZrCuSiAs crystal…

Superconductivity · Physics 2013-01-18 D. Yazici , K. Huang , B. D. White , A. H. Chang , A. J. Friedman , M. B. Maple

Superconductors with a van der Waals (vdW) structure have attracted a considerable interest because of the possibility for truly two-dimensional (2D) superconducting systems. We recently reported NaSn2As2 as a novel vdW-type superconductor…