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Lattice thermal conductivities (LTCs) of \alpha-, \beta-, and \gamma-Si$_3$N$_4$ single crystals are investigated from ab initio anharmonic lattice dynamics, within the single-mode relaxation-time approximation of the linearized phonon…

Materials Science · Physics 2016-12-28 Kazuyoshi Tatsumi , Atsushi Togo , Isao Tanaka

Understanding heat transport in organic semiconductors is of fundamental and practical relevance. Therefore, we study the lattice thermal conductivities of a series of (oligo)acenes, where an increasing number of rings per molecule leads to…

Materials Science · Physics 2024-12-09 Lukas Legenstein , Lukas Reicht , Sandro Wieser , Michele Simoncelli , Egbert Zojer

We investigate the microscopic mechanism of ultralow lattice thermal conductivity ($\kappa_l$) of TlInTe$_2$ and its weak temperature dependence using a unified theory of lattice heat transport that considers contributions arising from the…

Materials Science · Physics 2020-12-09 Koushik Pal , Yi Xia , Chris Wolverton

Achieving high thermoelectric performance requires efficient manipulation of thermal conductivity and a fundamental understanding of the microscopic mechanisms of phonon transport in crystalline solids. One of the major challenges in…

Materials Science · Physics 2023-05-18 Jiaoyue Yuan , Yubi Chen , Bolin Liao

Phonon size effects induce ballistic transport in nanomaterials, challenging Fourier's law. Nondiffusive heat transport is captured by the Peierls-Boltzmann transport equation (BTE), commonly solved under the relaxation time approximation…

Mesoscale and Nanoscale Physics · Physics 2020-03-10 Giuseppe Romano

Crystalline solids are generally known as excellent heat conductors, amorphous materials or glasses as thermal insulators. It has thus come as a surprise that certain crystal structures defy this paradigm. A prominent example are type-I…

Strongly Correlated Electrons · Physics 2019-02-22 M. Ikeda , H. Euchner , X. Yan , P. Tomes , A. Prokofiev , L. Prochaska , G. Lientschnig , R. Svagera , S. Hartmann , E. Gati , M. Lang , S. Paschen

Thermoelectric effects enable the direct conversion between thermal and electrical energy and provide an alternative route for power generation and refrigeration. The clathrate Ba8Ga16Ge30 has the highest figure of merit (ZT ~ 1) among…

Materials Science · Physics 2011-11-16 Deepa Kasinathan , Vicente Pacheco-Espejel , Helge Rosner

Electron-phonon interactions play a key role in many branches of solid-state physics. Here, our focus is on the transport properties of one-dimensional systems, and we apply efficient real-time matrix-product state methods to compute the…

Strongly Correlated Electrons · Physics 2023-08-21 David Jansen , Fabian Heidrich-Meisner

In this work, we investigate the microscopic mechanisms of anharmonic lattice dynamics and thermal transport in lead-free halide double perovskite Cs2AgBiBr6 from first principles. We combine self-consistent phonon calculations with bubble…

Materials Science · Physics 2024-02-09 Jiongzhi Zheng , Changpeng Lin , Chongjia Lin , Geoffroy Hautier , Ruiqiang Guo , Baoling Huang

We present thermal conductivity measurements on very pure and dense bulk samples, as indicated by residual resistivity values as low as 0.5 mW cm and thermal conductivity values higher than 200 W/mK. In the normal state we found that the…

Materials based on cubic tetrahedrites (Cu$_{12}$Sb$_{4}$S$_{13}$) are useful thermoelectrics with unusual thermal and electrical transport properties, such as very low and nearly temperature-independent lattice thermal conductivity…

Materials Science · Physics 2020-08-28 Yi Xia , Vidvuds Ozolins , Chris Wolverton

The lattice thermal conductivity (LTC) of Ga$_2$O$_3$ is an important property due to the challenge in the thermal management of high-power devices. We develop machine-learned neuroevolution potentials for single-crystalline…

Materials Science · Physics 2024-02-14 Xiaonan Wang , Jinfeng Yang , Penghua Ying , Zheyong Fan , Jin Zhang , Huarui Sun

We report the discovery of temperature-invariant ultralow thermal conductivity ($\kappa$) in monolayer $\beta'$-In$_2$Se$_3$, a two-dimensional ferroelectric crystal with in-plane polarization. Using a combination of generalized Wigner…

Materials Science · Physics 2025-01-24 Wenjie Zhou , Shi Liu

The thermal conductivity of polycrystalline semiconductors with type-I clathrate hydrate crystal structure is reported. Ge clathrates (doped with Sr and/or Eu) exhibit lattice thermal conductivities typical of amorphous materials.…

Materials Science · Physics 2009-10-31 J. L. Cohn , G. S. Nolas , V. Fessatidis , T. H. Metcalf , G. A. Slack

We study the low-temperature electrical and thermal conductivity of CoSi and Co$_{1-x}$M$_x$Si alloys (M = Fe, Ni; $x \leq$ 0.06). Measurements show that the low-temperature electrical conductivity of Co$_{1-x}$Fe$_{x}$Si alloys decreases…

We present the quantitative interpretation for the glass-like behavior of thermal conductivities $\kappa(T)$ for type-I clathrate compounds involving off-centered guest ions. It is shown that the dipole-dipole interaction generated in…

Materials Science · Physics 2009-11-27 Eiji Kaneshita , Tsuneyoshi Nakayama

Peierls-Boltzmann transport equation, coupled with third-order anharmonic lattice dynamics calculations, has been widely used to model lattice thermal conductivity ($\kappa_{l}$) in bulk crystals. However, its application to materials with…

Materials Science · Physics 2018-11-08 Yi Xia , Maria K. Y. Chan

We perform molecular dynamics (MD) simulations with phonon spectral analysis aiming at understanding the two dimensional (2D) thermal transport in suspended and supported graphene. Within the framework of equilibrium MD simulations, we…

Mesoscale and Nanoscale Physics · Physics 2015-06-03 Bo Qiu , Xiulin Ruan

For $\beta$-$\mathrm{Ga_2O_3}$ only little information exist concerning the thermal properties, especially the thermal conductivity $\lambda$. Here, the thermal conductivity is measured by applying the electrical 3$\omega$-method on…

Materials Science · Physics 2015-02-10 Martin Handwerg , Rüdiger Mitdank , Zbigniew Galazka , Saskia F. Fischer

In the present work, we performed calculations of the lattice thermal conductivity (LTC) and electron-phonon interactions in crystalline and amorphous gallium oxide. The calculations were performed by coupling a machine-learned interatomic…

Materials Science · Physics 2026-04-01 Rustam Arabov , Jiaxuan Li , Xiaotong Chen , Nikita Rybin , Alexander Shapeev