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Halide perovskites have remarkable properties for relatively crudely processed semiconductors, including large optical absorption coefficients and long charge carrier lifetimes. Thanks to such properties, these materials are now competing…

Applied Physics · Physics 2019-12-03 Géraud Delport , Stuart Macpherson , Samuel D. Stranks

Owing to their exceptional semiconducting properties, hybrid inorganic-organic perovskites show great promise as photovoltaic absorbers. In these materials, long-range diffusion of charge carriers allows for most of the photogenerated…

Organometal halide perovskite has emerged as a promising material for solar cells and optoelectronics. Although the long diffusion length of photo-generated carriers is believed to be a critical factor responsible for the material's high…

Materials Science · Physics 2016-12-30 Shuhao Liu , Lili Wang , Wei-Chun Lin , Sukrit Sucharitakul , Clemens Burda , Xuan. P. A. Gao

Solar cells based on metal-halide perovskite absorber layers have resulted in outstanding photovoltaic devices with long non-radiative lifetimes as a crucial feature enabling high efficiencies. Long non-radiative lifetimes occur if the…

Materials Science · Physics 2018-09-21 Thomas Kirchartz , Tom Markvart , Uwe Rau , David A. Egger

Many optoelectronic properties have been reported for lead halide perovskite polycrystalline films. However, ambiguities in the evaluation of these properties remain, especially for long-range lateral charge transport, where ionic…

The unprecedented rise in power conversion efficiency of solar cells based on metal halide perovskites (MHPs) has led to enormous research effort to understand their photo-physical properties. In this paper, we review the progress in…

Applied Physics · Physics 2020-07-10 Tom J. Savenije , Dengyang Guo , Valentina M. Caselli , Eline M. Hutter

Halide perovskites have shown great potential for light emission and photovoltaic applications due to their remarkable electronic properties and compatibility with cost-effective fabrication techniques. Although the device performances are…

The outstanding performance of organic-inorganic metal trihalide solar cells benefits from the exceptional photo-physical properties of both electrons and holes in the material. Here, we directly probe the free-carrier dynamics in Cs-doped…

Mesoscale and Nanoscale Physics · Physics 2021-09-01 Xuejian Ma , Fei Zhang , Zhaodong Chu , Ji Hao , Xihan Chen , Jiamin Quan , Zhiyuan Huang , Xiaoming Wang , Xiaoqin Li , Yanfa Yan , Kai Zhu , Keji Lai

The measurement and description of the charge-carrier lifetime (tauc) is crucial for the wide-ranging applications of lead-halide perovskites. We present time-resolved microwave-detected photoconductivity decay (TRMCD) measurements and a…

Materials Science · Physics 2024-11-11 A. Bojtor , D. Krisztian , F. Korsos , S. Kollarics , G. Parada , M. Kollar , E. Horvath , X. Mettan , B. G. Markus , L. Forro , F. Simon

Lead-halide perovskites are semiconductor materials with attractive properties for photovoltaic and other optoelectronic applications. However, determining crucial electronic material parameters, such as charge-carrier mobility and…

Materials Science · Physics 2024-11-05 Ye Yuan , Genghua Yan , Samah Akel , Uwe Rau , Thomas Kirchartz

We compare three representative high performance PV materials: halide perovskite MAPbI3, CdTe, and GaAs, in terms of photoluminescence (PL) efficiency, PL lineshape, carrier diffusion, and surface recombination, over multiple orders of…

In high performance perovskite based solar cells, CH3NH3PbI3 is the key material. We carried out a study on charge diffusion in spin-coated CH3NH3PbI3 perovskite thin film by transient fluorescent spectroscopy. A thickness-dependent…

Chemical Physics · Physics 2015-10-02 Yu Li , Weibo Yan , Yunlong Li , Shufeng Wang , Wei Wang , Zuqiang Bian , Lixin Xiao , Qihuang Gong

Organometal halide perovskites are promising solar-cell materials for next-generation photovoltaic applications. The long carrier lifetime and diffusion length of these materials make them very attractive for use in light absorbers and…

Materials Science · Physics 2016-12-21 Fan Zheng , Liang Z. Tan , Shi Liu , Andrew M. Rappe

Due to their exceptional photovoltaic properties, metal halide perovskites (MHPs) are extensively studied for their potential applications in solar cells. In recent years, the power conversion efficiencies of MHPs-based solar cells rapidly…

Materials Science · Physics 2022-08-12 A. Bojtor , S. Kollarics , B. G. Markus , A. Sienkiewicz , M. Kollar , L. Forro , F. Simon

Solar cells based on organometal halide perovskites have recently become very promising among other materials because of their cost-effective character and improvements in efficiency. Such performance is primarily associated with effective…

Materials Science · Physics 2016-03-23 Zhyrair Gevorkian , Vladimir Gasparian , Yurii Lozovik

Lead-halide perovskites exhibit remarkable efficiency in photovoltaics, driven by exceptionally long carrier diffusion lengths and recombination times. Paradoxically, this performance persists even in defect-rich, solution-grown samples.…

Materials Science · Physics 2025-03-17 Dmytro Rak , Dusan Lorenc , Ayan A. Zhumekenov , Osman M. Bakr , Zhanybek Alpichshev

The charge transport properties of hybrid halide perovskites are investigated with a combination of density functional theory including van der Waals interaction and the Boltzmann theory for diffusive transport in the relaxation time…

Materials Science · Physics 2016-01-29 Carlo Motta , Fedwa El Mellouhi , Stefano Sanvito

The outstanding photovoltaic performances of lead halide perovskite (LHP) thin film solar cells are due in particular to the large diffusion length of photocarriers. The mechanism behind this property and its dependence on the various…

In perovskite solar cells, photovoltaic action is created by charge transport layers (CTLs) either side of the light-absorbing metal halide perovskite semiconductor. Hence, the rates for desirable charge extraction and unwanted interfacial…

In optoelectronic applications, metal halide perovskites (MHPs) are compelling materials because of their highly tuneable and intensely competitive optical properties. Colloidal synthesis enables the controlled formation of various…

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