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We combine high-pressure x-ray diffraction, high-pressure Raman scattering, and optical microscope to investigate a series of PMN-xPT solid solutions (x=0.2, 0.3, 0.33, 0.35, 0.37, 0.4) in diamond anvil cells up to 20 GPa at 300 K. The…

We have investigated structural and magnetic phase transitions under high pressures in a quaternary rare earth transition metal arsenide oxide NdCoAsO compound that is isostructural to high temperature superconductor NdFeAsO. Four-probe…

We report the synthesis and characterization of (La0.9Y0.1)H10 superhydrides exhibiting coexisting cubic Fm-3m and hexagonal P63/mmc clathrate phases observed over the pressure range from 168 GPa down to 136 GPa. Using synchrotron-based…

This paper summarizes 0 GPa to 0.6 GPa neutron diffraction measurements of a nickel hexacyanochromate coordination polymer (NiCrPB) that has the face-centered cubic, Prussian blue structure. Deuterated powders of NiCrPB contain ~100 nm…

Materials Science · Physics 2015-06-23 D. M. Pajerowski , S. E. Conklin , J. B. Leão , D. Phelan , L. W. Harriger

Hexagonal boron nitride is a wide bandgap semiconductor with a very high thermal and chemical stability often used in devices operating under extreme conditions. The growth of high-purity crystals has recently revealed the potential of this…

Materials Science · Physics 2016-05-04 G. Cassabois , P. Valvin , B. Gil

We report results of ab initio constant-pressure molecular dynamics simulations of sulfur compression leading to structural transition and pressure-induced amorphization. Starting from the orthorhombic S-I phase composed of S$_8$ ring…

Disordered Systems and Neural Networks · Physics 2015-06-19 Dušan Plašienka , Roman Martoňák

We have carried out a detailed high-pressure investigation on the strongly correlated transition metal chalcogenide $Cr_{3}Te_4$ using Raman spectroscopy and XRD, which is ferromagnetic and metallic at ambient conditions. We find that the…

Using first-principles calculations in combination with special quasirandom structure and occupation control matrix methods, we study the magnetic ordering and the effect of pressure on manganese sulfide polymorphs. At ambient conditions,…

Materials Science · Physics 2022-04-06 Artem Chmeruk , Maribel Núñez-Valdez

The pressure induced quantum phase transition of the weakly itinerant ferromagnet MnSi is studied using zero-field $^{29}Si$ NMR spectroscopy and relaxation. Below $P^*\approx 1.2GPa$, the intensity of the signal and the nuclear…

Strongly Correlated Electrons · Physics 2009-11-10 W. Yu , F. Zamborszky , J. D. Thompson , J. L. Sarrao , M. E. Torelli , Z. Fisk , S. E. Brown

Using X-ray absorption spectroscopy (XAS), we studied the local structure in LaMnO3 under applied pressure across and well above the insulator to metal (IM) transition. A hysteretic behavior points to the coexistence of two phases within a…

A high pressure neutron diffraction study of the oxypnictide NdMnAsO0.95F0.05 has been performed at temperatures of 290 K - 383 K and pressures up to 8.59 GPa. The results demonstrate that the antiferromagnetic order of the Mn spins is…

Strongly Correlated Electrons · Physics 2015-06-24 E. J. Wildman , M. G. Tucker , A. C. Mclaughlin

Raman spectroscopic studies have been carried out on CaCrO4 under pressure up to 26GPa at ambient temperature. The Raman spectra showed CaCrO4 experienced a continuous structural phase transition started at near 6GPa, and finished at about…

Materials Science · Physics 2009-11-11 Y. W. Long , W. W. Zhang , L. X. Yang , Y. Yong , R. C. Yu , S. Ding , Y. L. Liu , C. Q. Jin

By means of powder neutron diffraction we investigate changes in the magnetic structure of the coplanar non-collinear antiferromagnet Mn$_3$Ge caused by an application of hydrostatic pressure up to 5\phantom{ }GPa. At ambient conditions the…

Strongly Correlated Electrons · Physics 2018-06-05 A. S. Sukhanov , Sanjay Singh , L. Caron , Th. Hansen , A. Hoser , V. Kumar , H. Borrmann , A. Fitch , P. Devi , K. Manna , C. Felser , D. S. Inosov

The vibrational and structural properties of a hydrogen-rich Group IVa hydride, Ge(CH$_3$)$_4$, are studied by combining Raman spectroscopy and synchrotron X-ray diffraction measurements at room temperature and at pressures up to 30.2 GPa.…

Superconductivity · Physics 2015-06-11 Zhen-Xing Qin , Chao Zhang , Ling-Yun Tang , Guo-Hua Zhong , Hai-Qing Lin , Xiao-Jia Chen

There has been a recent controversy about the high pressure polymorphism of Hafnium (Hf). Unlike, the earlier known {\alpha} $\rightarrow$ {\omega} structural transition at 38 $\pm$ 8 GPa, Hrubiak et al (2012) did not observe it till 51…

Materials Science · Physics 2015-06-19 K. K. Pandey , Jyoti Gyanchandani , M. Somayazulu , G. K. Dey , Surinder M. Sharma , S. K. Sikka

We present a comprehensive study of the mixed valent compound, EuPd3S4, by electrical transport, X-ray diffraction, time-domain 151Eu synchrotron M\"ossbauer spectroscopy, and X-ray absorption spectroscopy measurements under high pressure.…

Strongly Correlated Electrons · Physics 2024-01-09 S. Huyan , D. H. Ryan , T. J. Slade , B. Lavina , G. C. Jose , H. Wang , J. M. Wilde , R. A. Ribeiro , J. Zhao , W. Xie , W. Bi , E. E. Alp , S. L. Bud'ko , P. C. Canfield

We report high pressure Raman, synchrotron x-ray diffraction and electrical transport studies on Weyl semimetals NbP and TaP along with first-principles density functional theoretical (DFT) analysis. The frequencies of first-order Raman…

Background: Excitations with mixed proton-neutron symmetry have been previously observed in the $N=52$ isotones. Besides the well established quadrupole mixed-symmetry states (MSS), octupole and hexadecapole MSS have been recently proposed…

7M orthorhombic modulated structure in the martensite phase of Ni1.8Pt0.2MnGa is reported by powder neutron diffraction study, which indicates that it is likely to exhibit magnetic field induced strain. The change in the unit cell volume is…

Materials Science · Physics 2012-11-02 Sanjay Singh , K. R. A. Ziebeck , E. Suard , P. Rajput , S. Bhardwaj , A. M. Awasthi , S. R. Barman

The pressure-induced metallic states of light elements attract significant attention, because of potential applications as high-temperature superconductor and high-energy-density material, especially for hydrogen and nitrogen1-10. Several…

Materials Science · Physics 2026-03-04 Kewei Ding , Junyi Miao , Ying Liu , Anxin Yu , Cheng Lu , Wenrui Zhang , Yanchun Li , Haipeng Su , Zhongxue Ge , Xianlong Wang