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The quadrupolar splittings of perdeuteriated n-decane dissolved in nematic phases formed by mesogenic dimers of the CBnCB series, for n=7,9,10,11 are measured throughout the entire temperature range of these phases. The results of the…

We present a comprehensive set of measurements of optical, dielectric, diamagnetic, elastic and viscous properties in the nematic (N) phase formed by a liquid crystalline dimer. The studied dimer, 1,7-bis-4-(4-cyanobiphenyl) heptane…

The twist-bend nematic (Ntb) phase is a recent addition to the nematic (N) phases of liquid crystals (LCs). A net polar order in the Ntb phase under an external electric field was predicted in several recent theoretical studies but yet to…

Soft Condensed Matter · Physics 2022-09-13 Sourav Patranabish , Aloka Sinha , Madhu B. Kanakala , Channabasaveshwar V. Yelamaggad

Freeze Fracture Transmission Electron Microscopy (FFTEM) study of the nanoscale structure of the so-called "twist-bend" nematic (NX) phase of the cyanobiphenyl (CB) dimer molecule CB(CH2)7CB reveals a stripe texture of fluid layers…

The twist-bend nematic liquid crystal phase is a three-dimensional fluid in which achiral bent molecules spontaneously form an orientationally ordered macroscopically chiral heliconical winding of molecular scale pitch, in absence of…

NMR measurements on a selectively deuteriated liquid crystal dimer CB-C9-CB exhibiting two nematic phases show that the molecules in the lower temperature nematic phase, Nx, experience a chiral environment and are ordered about a unique…

Soft Condensed Matter · Physics 2014-07-09 Anke Hoffmann , Alexandros G. Vanakaras , Alexandra Kohlmeier , Georg H. Mehl , Demetri J. Photinos

The dielectric spectra of the twist bend nematic phase of the bent shaped achiral liquid crystal dimer are studied for the determination of the different relaxation modes. The two molecular processes were assigned one to the precessional…

Applied Physics · Physics 2020-01-08 K. Merkel , A. Kocot , C. Welch , G. H. Mehl

Certain nematic liquid crystals, e.g., those formed by banana-shaped molecules, can exhibit a low-temperature twist-bend nematic (Ntb) phase. Upon addition of chiral dopants, a chiral version of the twist-bend phase (N*tb) can be observed…

Soft Condensed Matter · Physics 2021-09-08 Natalia Kasian , Longin Lisetski , Igor Gvozdovskyy

The nanostructure of two novel sulfur containing dimer materials has been investigated experimentally by hard and by resonant tender X-ray scattering techniques. On cooling the dimers through the nematic to twist-bend nematic (N-NTB) phase…

Soft Condensed Matter · Physics 2020-11-20 Rony Saha , Chenrun Feng , Chris Welch , Georg H. Mehl , Jun Feng , Chenhui Zhu , James Gleeson , Samuel Sprunt , Antal Jakli

Dynamic simulations of the isotropic-nematic phase transformation of liquid crystal droplets under homeotropic anchoring are found to predict chiral symmetry-breaking dynamics. These observations occur when using material parameters for…

Soft Condensed Matter · Physics 2017-07-18 Fred Fu , Nasser Mohieddin Abukhdeir

An analysis of the IR absorbance for the segmented functional groups of liquid crystal dimers: mesogen and linker, enabled the orientation order to be determined and information about the dipole interactions in the nematic and twist-bend…

Soft Condensed Matter · Physics 2026-05-19 Antoni Kocot , Barbara Loska , Yuki Arakawa , Katarzyna Merkel

We present a simplified molecular model of mesogenic dimers consisting of two identical uniaxial mesogenic cores separated by a fixed-length spacer and allowed to assume only two, statistically equivalent, conformations which are non-planar…

Soft Condensed Matter · Physics 2016-07-26 Alexandros G. Vanakaras , Demetri J. Photinos

A computational study of morphological instabilities of a two-dimensional nematic front under directional growth was performed using a Landau-de Gennes type quadrupolar tensor order parameter model for the first-order isotropic/nematic…

Soft Condensed Matter · Physics 2009-08-20 Ezequiel R. Soulé , Nasser Mohieddin Abukhdeir. Alejandro D. Rey

Using a novel Se-labelled dimer mixed with DTC5C7 aligned by magnetic field, the twist-bend nematic phase (Ntb) in dimers was studied by hard X-ray resonant scattering and by small and wide angle X-ray scattering (SAXS, WAXS). Resonant…

Soft Condensed Matter · Physics 2017-06-28 W. D. Stevenson , Z. Ahmed , X. B. Zeng , C. Welch , G. Ungar , G. H. Mehl

Binary mixtures of the twist-bend nematic-forming liquid crystal CB7CB with the prototypical rod-like liquid crystal 5CB exhibit a twist-bend nematic phase with properties similar to those reported for neat CB7CB. The mixtures appear…

We report on the temperature dependence of birefringence and of the static dielectric permittivity tensor in a series of binary mixtures between the symmetric, bent-shaped, 1",9"-bis(4-cyanobiphenyl-4'-yl) nonane (CB9CB) dimer and the…

X-ray scattering and polarized microscopic studies of the structure and order parameters in the nematic (N) and heliconical, or the twist-bend nematic (Ntb), phase have been performed as a function of temperature. The nematic orientational…

The understanding of self-organization in the twist-bend nematic $(N_\text{TB})$ phase, identified in 2011 in liquid crystal dimers, is at the forefront of soft matter research worldwide. This new nematic phase develops structural chirality…

Soft Condensed Matter · Physics 2020-10-27 Lech Longa , Wojciech Tomczyk

In this experimental and theoretical study, we examine the equilibrium shapes of quasitwo-dimensional twist-bend nematic (Ntb) drops formed within a planarly aligned nematic layer of the liquid crystal CB7CB. Initially, at the setting point…

A possibility was assessed to modify physico-chemical properties of ferronematic mixtures by introducing additional mesogenic and non-mesogenic components. The mixture, consisting of RM734 and DIO at the 70:30 weight ratio of the…

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