The twist-bend nematic liquid crystal phase is a three-dimensional fluid in which achiral bent molecules spontaneously form an orientationally ordered macroscopically chiral heliconical winding of molecular scale pitch, in absence of positional ordering. Here we characterize the structure of the ground state of the twist-bend phase of the bent dimer CB7CB and its mixtures with 5CB over a wide range of concentrations and temperatures, showing that the contour length along the molecular direction for a single turn of the helix is approximately equal to 2{\pi}Rmol, where Rmol is the radius of bend curvature of a single all-trans CB7CB molecule. This relation emerges from a model which simply relates the macroscopic characteristics of the helical structure, which is mostly biaxial twist and has little bend, to the bent molecular shape. This connection comes about through the presence in the fluid of self-assembled oligomer-like correlations of interlocking molecules, arising from the nanosegregation of rigid and flexible molecular subcomponents, forming a brickwork tiling of pairs of molecular strands into a duplex double-helical chain.
@article{arxiv.1703.10787,
title = {Double-Helical Tiled Chain Structure of the Twist-Bend Liquid Crystal phase in CB7CB},
author = {Michael R. Tuchband and Min Shuai and Keri A. Graber and Dong Chen and Chenhui Zhu and Leo Radzihovsky and Arthur Klittnick and Lee M. Foley and Alyssa Scarbrough and Jan H. Porada and Mark Moran and Joseph Yelk and Dmitry Bedrov and Eva Korblova and David M. Walba and Alexander Hexemer and Joseph E. Maclennan and Matthew A. Glaser and Noel A. Clark},
journal= {arXiv preprint arXiv:1703.10787},
year = {2017}
}