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Although several theories relate the steep slowdown of glass formers to increasing spatial correlations of some sort, standard static correlation functions show no evidence for this. We present results that reveal for the first time a…

Disordered Systems and Neural Networks · Physics 2011-08-31 G. Biroli , J. -P. Bouchaud , A. Cavagna , T. S. Grigera , P. Verrocchio

We consider the stationary state of a fluid comprised of inelastic hard spheres or disks under the influence of a random, momentum-conserving external force. Starting from the microscopic description of the dynamics, we derive a nonlinear…

Statistical Mechanics · Physics 2013-02-25 W. T. Kranz , M. Sperl , A. Zippelius

The ultraslow dynamics of glass-formers has been explained by two views considered as mutually exclusive: one invokes locally hindered mobility, the other rests on the complexity of the configuration space. Here we demonstrate that the…

Disordered Systems and Neural Networks · Physics 2026-02-02 Federico Ghimenti , Ludovic Berthier , Jorge Kurchan , Frédéric van Wijland

We compute the temperature-dependent barrier for alpha-relaxations in several liquids, without adjustable parameters, using experimentally determined elastic, structural, and calorimetric data. We employ the random first order…

Disordered Systems and Neural Networks · Physics 2013-10-17 Pyotr Rabochiy , Peter G. Wolynes , Vassiliy Lubchenko

In this note we revisit the Kovacs effect, concerning the way in which the volume of a glass-forming liquid, which has been driven out of equilibrium, changes with time while the system evolves towards a metastable state. The theoret- ical…

Soft Condensed Matter · Physics 2017-11-16 F. Aliotta , R. C. Ponterio , F. Saija , P. V. Giaquinta

We use Brownian dynamics simulations of a binary mixture of highly charged spherical colloidal particles to illustrate many of the implications of the Random First Order Transition (RFOT) theory (PRA 40 1045 (1989)), which is the only…

Statistical Mechanics · Physics 2015-06-12 Hongsuk Kang , T. R. Kirkpatrick , D. Thirumalai

In this paper the phenomenon of dynamic heterogeneity in supercooled liquid systems is considered in terms of the recently proposed gauge theory of glass transition. The physical interpretation of the dynamic scaling is considered. It is…

Statistical Mechanics · Physics 2015-06-23 Mikhail Vasin

We study by molecular dynamics computer simulation a binary soft-sphere mixture that shows a pronounced decoupling of the species' long-time dynamics. Anomalous, power-law-like diffusion of small particles arises, that can be understood as…

Statistical Mechanics · Physics 2013-05-29 Th. Voigtmann , J. Horbach

Elucidating the nature of the glass transition has been the holy grail of condensed matter physics and statistical mechanics for several decades. A phenomenological aspect that makes glass formation a conceptually formidable problem is that…

Soft Condensed Matter · Physics 2016-08-11 Shreyas Gokhale , K. Hima Nagamanasa , A. K. Sood , Rajesh Ganapathy

An alternative scenario for the glass transition based on the cooperative nature of nucleation processes and the role of entropic effects is presented. The new ingredient is to relate the dissipation during the relaxation process to the…

Statistical Mechanics · Physics 2007-05-23 Andrea Crisanti , Felix Ritort

Equilibrium sampling of the configuration space in disordered systems requires algorithms that bypass the glassy slowing down of the physical dynamics. Irreversible Monte Carlo algorithms breaking detailed balance successfully accelerate…

Disordered Systems and Neural Networks · Physics 2024-07-15 Federico Ghimenti , Ludovic Berthier , Frédéric van Wijland

Despite the use of glasses for thousands of years, the nature of the glass transition is still mysterious. On approaching the glass transition, the growth of dynamic heterogeneity has long been thought to play a key role in explaining the…

Soft Condensed Matter · Physics 2018-03-23 Lijin Wang , Ning Xu , W. H. Wang , Pengfei Guan

Transitions between metabasins in supercooled liquids seem to occur through rapid "democratic" collective particle rearrangements. Here we show that this apparent homogeneous particle motion is a direct consequence of dynamic facilitation.…

Statistical Mechanics · Physics 2008-07-31 Lester O. Hedges , Juan P. Garrahan

Understanding structural glasses using the Random First Order Transition theory requires a description in both real space and in time, taking into account sample history. A variety of nonlinear objects enter this description, in field…

Disordered Systems and Neural Networks · Physics 2022-06-02 Peter G. Wolynes

Dense active matter, in the fluid or amorphous-solid form, has generated intense interest as a model for the dynamics inside living cells and multicellular systems. An extension of the random first-order transition theory (RFOT) to include…

Soft Condensed Matter · Physics 2021-02-16 Rituparno Mandal , Saroj Kumar Nandi , Chandan Dasgupta , Peter Sollich , Nir S. Gov

We perform stringent tests of thermodynamic theories of the glass transition over the experimentally relevant temperature regime for several simulated glass-formers. The swap Monte Carlo algorithm is used to estimate the configurational…

Statistical Mechanics · Physics 2019-10-03 Misaki Ozawa , Camille Scalliet , Andrea Ninarello , Ludovic Berthier

The random first order transition theory of the dynamics of supercooled liquids is extended to treat aging phenomena in nonequilibrium structural glasses. A reformulation of the idea of ``entropic droplets'' in terms of libraries of local…

Soft Condensed Matter · Physics 2009-11-10 Vassiliy Lubchenko , Peter G. Wolynes

Glass transition is accompanied by a rapid growth of the structural relaxation time and a concomitant decrease of configurational entropy. It remains unclear whether the transition has a thermodynamic origin, and whether the dynamic arrest…

Soft Condensed Matter · Physics 2015-10-28 Chengjie Xia , Jindong Li , Yixin Cao , Binquan Kou , Xinaghui Xiao , Kamel Fezzaa , Tiqiao Xiao , Yujie Wang

Granular materials such as sand, powders, and grains are omnipresent in daily life, industrial applications, and earth-science [1]. When unperturbed, they form stable structures that resemble the ones of other amorphous solids like metallic…

Soft Condensed Matter · Physics 2023-01-19 Ye Yuan , Zhikun Zeng , Yi Xing , Houfei Yuan , Shuyang Zhang , Walter Kob , Yujie Wang

A popular Adam--Gibbs scenario has suggested that the excess entropy of glass and liquid over crystal dominates the dynamical arrest at the glass transition with exclusive contribution from configurational entropy over vibrational entropy.…

Soft Condensed Matter · Physics 2020-02-05 Dong Han , Dan Wei , Jie Yang , Hui-Ling Li , Min-Qiang Jiang , Yun-Jiang Wang , Lan-Hong Dai , Alessio Zaccone