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In this work we get insight into the impact of reduced density matrix functionals on the quality of removal/addition energies obtained using the Extended Koopmans' Theorem (EKT). Within reduced density matrix functional theory (RDMFT) the…
For students familiar with equilibrium statistical mechanics, the notion of a positive specific heat, being intimately related to the idea of stability, is both intuitively reasonable and mathematically provable. However, for system in…
Anomaly-diffusing energy balance models (AD-EBM) are routinely employed to analyze and emulate the warming response of both observed and simulated Earth systems. We demonstrate a deficiency in common multi-layer as well as…
Visual Prompt Tuning (VPT) adapts a frozen Vision Transformer (ViT) to downstream tasks by inserting a small number of learnable prompt tokens into the token sequence at each layer. However, we observe that existing VPT variants often…
Earth's atmosphere operates a steam cycle in which water vapor evaporates from the surface, expands, condenses, and returns as precipitation. The Clausius-Clapeyron law relates the incremental expansion work of saturated water vapor to…
Vitrimers offer a promising sustainable alternative to conventional epoxies due to their recyclability. Vitrimers are covalent adaptive networks where some bonds can break and reform above the vitrimer transition temperature. While this can…
This study presents the first systematic investigation of the dynamics of individual water droplets in the context of airtanker firefighting. While previous work has focused on ground-deposition patterns measured in standardized field…
Observational studies indicate that there is a close association between geomagnetic storm and meteorological parameters. Geomagnetic field lines follow closely the isobars of surface pressure . A Physical mechanism linking upper…
Vegetation often understood merely as the result of long-term climate conditions. However, vegetation itself plays a fundamental role in shaping Earth's climate by regulating the energy, water, and biogeochemical cycles across terrestrial…
The steady response of the stratosphere to a sea surface temperature (SST) forcing is considered in two separate theoretical models. It is first shown that anomalies in SST impose a geopotential anomaly at the tropopause. Solutions to the…
Dicke narrowing is a phenomena that dramatically reduces the Doppler width of spectral lines, due to frequent velocity-changing collisions. A similar phenomena occurs for electromagnetically induced transparency (EIT) resonances, and…
Vertical mixing is a crucial disequilibrium process in exoplanet atmospheres, significantly impacting chemical abundance and observed spectra. While current state-of-the-art observations have detected its signatures, the effect of vertical…
We show a parallelism between the expansion and compression of the atmosphere in the secondary cycle of a tropical cyclone with the fast expansion and compression of wet air in a bottle. We present a simple model in order to understand how…
The increasing worldwide population leads to a constant increase in energy and food demand. These increasing demands have led to fierce land-use conflicts as we need agricultural land for food production while striving towards renewable…
We present a quantum framework based on a density matrix of a dimer system to investigate the quantum dynamics of excitation energy transfer (EET) in the presence of the evanescent field from the metal and the phonon bath. Due to the…
Along with the accumulation of atmospheric carbon dioxide, the loss of primary forests and other natural ecosystems is a major disruption of the Earth system causing global concern. Quantifying planetary warming from carbon emissions,…
A density matrix based analytical model is developed to study the coherent probe field propagation through a four-level V type system in presence of a coherent control field. The model allows coupling of the probe field from the upper…
Water management in a hydrogen polymer electrolyte membrane (PEM) fuel cell is critical for performance. The impact of thermal conductivity and water vapor diffusion coefficients in a gas diffusion layer (GDL) has been studied by a…
A variety of metal vacuum systems display the celebrated 1/t pressure, namely power-law dependence on time t, with the exponent close to unity, the origin of which has been a long-standing controversy. Here we propose a chemisorption model…
Considering viscous friction that varies spatially and temporally, the general expressions for entropy production, free energy, and entropy extraction rates are derived to a Brownian particle that walks in an overdamped and underdamped…