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The analytical solution is considered for the phenomenological theory of the second order ferroelectric or ferroelastic phase transition in a thin film with arbitrary boundary conditions. The general phase-plane portrait for the relevant…

Mesoscale and Nanoscale Physics · Physics 2012-08-27 K. R. Gabbasova , A. L. Pirozerskii , E. V. Charnaya

Ultrathin ferroelectric films with out-of-plane polarization and high Curie temperatures are key to miniaturizing electronic devices. Most ferroelectrics employed in devices are proper ferroelectrics, where spontaneous polarization is the…

Previous studies showed that, as ferroelectric films become thinner, their Curie temperature (Tc) and polarization below Tc both typically decrease. In contrast, a recent experiment [Chang et al., Science 353, 274 (2016)] observed that…

Materials Science · Physics 2018-07-18 Kai Liu , Jinlian Lu , Silvia Picozzi , Laurent Bellaiche , Hongjun Xiang

Going down to the limit of ultrathin films holds promise for a new generation of devices such as ferroelectric tunnel junctions or resistive memories. However, these length scales also make the devices sensitive to parasitic effects related…

The persistence of ferroelectricity in ultrathin HfO$_2$ films challenges conventional theories, particularly given the paradoxical observation that the out-of-plane lattice spacing increases as the film thickness decreases, a reverse size…

Materials Science · Physics 2026-01-08 Tianyuan Zhu , Jingxuan Li , Zuhuang Chen , Shi Liu

The paramagnetic-to-ferromagnetic phase transition is believed to proceed through a critical point, at which power laws and scaling invariance, associated with the existence of one diverging characteristic length scale -- the so called…

Statistical Mechanics · Physics 2016-03-15 N. Saratz , D. A. Zanin , U. Ramsperger , S. A. Cannas , D. Pescia , A. Vindigni

We propose a new scaling law for anomalous Hall effect in ferromagnetic thin films by distinguishing three scattering sources, namely, bulk impurity, phonon, and more importantly a rough surface. This new scaling law fits the recent…

Mesoscale and Nanoscale Physics · Physics 2017-11-01 Vahram L. Grigoryan , Jiang Xiao , Xuhui Wang , Ke Xia

Ferroelectric films usually have phase states and physical properties very different from those of bulk ferroelectrics. Here we propose free-standing ferroelectric-elastic multilayers as a bridge between these two material systems. Using a…

Materials Science · Physics 2011-10-18 S. Prokhorenko , N. A. Pertsev

The films of order-disorder type ferroelectrics were considered in the mean field approximation taking into account depolarization field. It was shown that size effects in this system could be described on the base of bulk system equation…

Materials Science · Physics 2007-05-23 E. A. Eliseev , M. D. Glinchuk

The ferroelectric thin film properties were calculated in phenomenological theory framework. Surface energy that defined boundary conditions for Euler-Lagrange differential equation was written as surface tension energy. The latter was…

Materials Science · Physics 2009-11-10 M. D. Glinchuk , A. N. Morozovska

General features of finite size effects in the ferroelectric-semiconductor film under open-circuited electric boundary conditions are analyzed using Landau-Ginzburg-Devonshire theory and continuum media electrostatics. The temperature…

Materials Science · Physics 2015-06-19 Eugene A. Eliseev , Sergei V. Kalinin , Anna N. Morozovska

For the first time we proposed the model for the calculations of the relaxor ferroelectrics films properties in the framework of the random field theory. We took into account the misfit strain between film and substrate as well as surface…

Materials Science · Physics 2007-05-23 E. A. Eliseev , M. D. Glinchuk

A first-principles-derived approach is developed to study the effects of uncompensated depolarizing electric fields on the properties of Pb(Zr,Ti)O$_3$ ultrathin films for different mechanical boundary conditions. A rich variety of…

Materials Science · Physics 2009-11-10 Igor Kornev , Huaxiang Fu , L. Bellaiche

Against expectations, robust switchable ferroelectricity has been recently observed in ultrathin (1 nm) ferroelectric films exposed to air [V. Garcia $et$ $al.$, Nature {\bf 460}, 81 (2009)]. Based on first-principles calculations, we show…

Mesoscale and Nanoscale Physics · Physics 2012-01-10 N. C. Bristowe , Massimiliano Stengel , P. B. Littlewood , J. M. Pruneda , Emilio Artacho

Using Landau-Ginzburg-Devonshire theory, we considered the impact of the flexoelectro-chemical coupling on the size effects inpolar properties and phase transitions of thin ferroelectric films with a layer of elastic defects. We…

Motivated by the observed thickness-scaling of the coercive field in ferroelectric films over five decades, we develop a statistical approach towards understanding the conceptual underpinnings of this behavior. Here the scaling exponent is…

Materials Science · Physics 2007-05-23 P. Chandra , M. Dawber , P. B. Littlewood , J. F. Scott

Ferroelectricity has recently been demonstrated in germanium-based inorganic halide perovskites. We use atomistic first-principles-based simulations to study ultra-thin CsGeBr$_3$ films with thicknesses of 4-18 nm and develop a theory for…

Materials Science · Physics 2024-04-08 Ravi Kashikar , Arlies Valdespino , Charlton Ogg , Edvin Uppgard , S. Lisenkov , I. Ponomareva

This review covers the important advances in recent years in the physics of thin film ferroelectric oxides, the strongest emphasis being on those aspects particular to ferroelectrics in thin film form. We introduce the current state of…

Materials Science · Physics 2009-11-11 M. Dawber , K. M. Rabe , J. F. Scott

Ferroelectric switching is unambigiously demonstrated for the first time in a III-V semiconductor based material: AlScN -- A discovery which could help to satisfy the urgent demand for thin film ferroelectrics with high performance and good…

Materials Science · Physics 2019-03-27 Simon Fichtner , Niklas Wolff , Fabian Lofink , Lorenz Kienle , Bernhard Wagner

Ferroelectrics are attractive candidate materials for environmentally friendly solid state refrigeration free of greenhouse gases. Their thermal response upon variations of external electric fields is largest in the vicinity of their phase…

Materials Science · Physics 2016-05-20 G. G. Guzmán-Verri , P. B. Littlewood
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