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The second law of thermodynamics is discussed and reformulated from a quantum information theoretic perspective for open quantum systems using relative entropy. Specifically, the relative entropy of a quantum state with respect to…

Quantum Physics · Physics 2020-11-11 Neil Dowling , Stefan Floerchinger , Tobias Haas

In recent years we have witnessed a concentrated effort to make sense of thermodynamics for small-scale systems. One of the main difficulties is to capture a suitable notion of work that models realistically the purpose of quantum machines,…

Quantum Physics · Physics 2016-11-23 R. Gallego , J. Eisert , H. Wilming

We challenge the statement that the principle of Thomson and the principle of Clausius are equivalent. A logical mistake in the supposed textbook proof of their equivalency is indicated. On this account we refine the heat-engine axiomatics.…

General Physics · Physics 2007-05-23 Valery P. Dmitriyev

It is argued the the idea of a single temperature-like variable, introduced in [1], which enters a generalized second law for Markovian open system in non-equilibrium environment is not sufficient for a consistent and useful thermodynamic…

Statistical Mechanics · Physics 2025-03-28 Robert Alicki

Quantum thermodynamics investigates how robust the second law of thermodynamics serves as the unique fundamental law in the small quantum world. To tackle this problem, the quantum coherence constitutes a major difficulty of investigations,…

Quantum Physics · Physics 2025-10-08 Naoto Shiraishi , Ryuji Takagi

We report two results complementing the second law of thermodynamics for Markovian open quantum systems coupled to multiple reservoirs with different temperatures and chemical potentials. First, we derive a nonequilibrium free energy…

Statistical Mechanics · Physics 2019-04-18 Krzysztof Ptaszynski , Massimiliano Esposito

In his ninth memoir Clausius summarizes the two principles of thermodynamics as follows: "The whole mechanical theory of heat rests on two fundamental theorems: that of equivalence of heat and work, and that of equivalence of…

Statistical Mechanics · Physics 2023-06-08 Giovanni Jona-Lasinio

In quantum systems which satisfy the hypothesis of equal weights for eigenstates [4], the maximum work principle (for extremely slow and relatively fast operation) is derived by using quantum dynamics alone. This may be a crucial step in…

Statistical Mechanics · Physics 2007-05-23 Hal Tasaki

Microcanonical thermodynamics allows the application of statistical mechanics both to finite and even small systems and also to the largest, self-gravitating ones. However, one must reconsider the fundamental principles of statistical…

Statistical Mechanics · Physics 2009-11-11 D. H. E. Gross , J. F. Kenney

This paper has been withdrawn by the author. For the reason, see the bottom paragraph of this abstract. By generalizing Tasaki's work on the second law of thermodynamics for an adiabatic process between two equilibrium states of a…

Statistical Mechanics · Physics 2014-05-26 Hiroshi Matsuoka

The first law of thermodynamics restates the law of conservation of energy. It partitions the change in energy of a system into two pieces, heat and work. While there is no ambiguity to define heat and work in classical thermodynamics,…

Quantum Physics · Physics 2023-01-19 Xue-Qun Yan , Yan-Jiao Du , Wen-Tao Hou , Xiao-Ming Liu

We extend the Carath\'{e}odory principle of the Second Law to quantum thermodynamics with energy levels depending on macroscopic variables, such as volume and magnetic field. This extension introduces the concept of Quantum Thermodynamic…

Statistical Mechanics · Physics 2025-09-09 Ruo-Xun Zhai , C. P. Sun

We show that the Cerf-Adami inequalities do not necessarily depend on conditional entropies nor any reference to Markov chains. While the latter are not explicit in the original form, they are often implied in certain derivations. We also…

Quantum Physics · Physics 2008-09-30 Ian T. Durham

Thermodynamics is the phenomenological theory of heat and work. Here we analyze to what extent quantum thermodynamic relations are immune to the underlying mathematical formulation of quantum mechanics. As a main result, we show that the…

Quantum Physics · Physics 2016-04-21 Bartłomiej Gardas , Sebastian Deffner , Avadh Saxena

Microcanonical Thermodynamics allows the application of Statistical Mechanics on one hand to closed finite and even small systems and on the other to the largest,self-gravitating ones. However, one has to reconsider the fundamental…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

The aim of this book chapter is to indicate how quantum phenomena are affecting the operation of microscopic thermal machines, such as engines and refrigerators. As converting heat to work is one of the fundamental concerns in…

Quantum Physics · Physics 2019-05-01 Amikam Levy , David Gelbwaser-Klimovsky

Macroscopic cyclic heat engines have been a major motivation for the emergence of thermodynamics. In the last decade, cyclic heat engines that have large fluctuations and operate at finite time were studied within the more modern framework…

Statistical Mechanics · Physics 2022-10-03 Arya Datta , Patrick Pietzonka , Andre C Barato

Based on quantum statistical mechanics and microscopic quantum dynamics, we prove Planck's and Kelvin's principles for macroscopic systems in a general and realistic setting. We consider a hybrid quantum system that consists of the…

Statistical Mechanics · Physics 2016-05-04 Hal Tasaki

An experimentally inspired model is constructed and rigorously solved from the Hamiltonian level where a dc circular spontaneous flow exists in absence of a magnetic field, irrespective of presence of dissipation causing otherwise proper…

Plasma Physics · Physics 2007-05-23 V. Capek , J. Bok

Quantum Thermodynamics is a continuous dialogue between two independent theories: Thermodynamics and Quantum Mechanics. Whenever the two theories addressed the same phenomena new insight has emerged. We follow the dialogue from equilibrium…

Quantum Physics · Physics 2018-06-04 Robert Alicki , Ronnie Kosloff