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We propose a new form of the Second Law inequality that defines a tight bound for extractable work from the non-equilibrium quantum state. In classical thermodynamics, the optimal work is given by the difference of free energy, what…

Quantum Physics · Physics 2023-02-14 Marcin Łobejko

We present an analysis of the foundations of the well known Clausius inequality. It is shown that, in general, the inequality is not a logical consequence of the Kelvin-Planck formulation of the second law of thermodynamics. Some thought…

Classical Physics · Physics 2012-04-24 Alexey V. Gavrilov

The laws of thermodynamics strongly restrict the performance of thermal machines. Standard thermodynamics, initially developed for uncorrelated macroscopic systems, does not hold for microscopic systems correlated with their environments.…

Quantum Physics · Physics 2025-11-13 Milton Aguilar , Eric Lutz

Underlying the classical thermodynamic principles are analogous microscopic laws, arising from the fundamental axioms of quantum mechanics. These define quantum thermodynamic variables such as quantum work and heat and characterize the…

Quantum Physics · Physics 2023-05-03 Roie Dann , Ronnie Kosloff

We consider the Non-Equilibrium Steady State induced by two infinite quantum thermal reservoirs at different temperatures and derive an inequality giving the upper bound of the work extracted by cyclic operations. This upper bound tends to…

Statistical Mechanics · Physics 2024-06-19 Kazuki Yamaga

The validity of the Second Law of thermodynamics, indisputable in the macroscopic world, is challenged at the mesoscopic level: a mesoscopic isolated system, possessing spatial dimensions of the order of a few microns, is capable, as shown…

Classical Physics · Physics 2007-05-23 B. Crosignani , P. Di Porto , C. Conti

The Kullback-Leibler inequality is a way of comparing any two density matrices. A technique to set up the density matrix for a physical system is to use the maximum entropy principle, given the entropy as a functional of the density matrix,…

Statistical Mechanics · Physics 2009-11-07 A. K. Rajagopal , R. W. Rendell , Sumiyoshi Abe

Thermodynamics at the nanoscale is known to differ significantly from its familiar macroscopic counterpart: the possibility of state transitions is not determined by free energy alone, but by an infinite family of free-energy-like…

Quantum Physics · Physics 2018-12-21 Markus P. Mueller

Several models of quantum open systems are known at present to violate, according to principles of the standard quantum theory of open systems, the second law of thermodynamics. Here, a new and rather trivial model of another type is…

Statistical Mechanics · Physics 2007-05-23 V. Capek

Traditional discussions of the Second Law of Thermodynamics studied the limits of very specific types of devices, such as heat engines, chemical reactions, and molecules channeled by valves. Allahverdyan and Nieuwenhuizen (cond-mat/0110422)…

Statistical Mechanics · Physics 2007-05-23 Paul J. Werbos

Recent research on the thermodynamic arrow of time, at the microscopic scale, has questioned the universality of its direction. Theoretical studies showed that quantum correlations can be used to revert the natural heat flow (from the hot…

Quantum Physics · Physics 2018-06-13 Ivan Henao , Roberto M. Serra

Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble, whereas canonical ones fail in the most interesting, mostly inhomogeneous, situations like phase separations or away from the thermodynamic…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

Recently implemented quantum devices such as quantum processors and quantum simulators combine highly complicated quantum dynamics with high-resolution measurements. We present a passivity deformation methodology that sets thermodynamic…

Quantum Physics · Physics 2021-03-10 Raam Uzdin , Saar Rahav

Clausius' statement of the second law of thermodynamics reads: Heat will flow spontaneously from a hot to cold reservoir. This statement should hold for transport of energy through a quantum network composed of small subsystems each coupled…

Quantum Physics · Physics 2015-04-17 Amikam Levy , Ronnie Kosloff

Two testable schemes for quantum heat engines are investigated under the quantization framework of noncommutative (NC) quantum mechanics (QM). By identifying the phenomenological connection between the phase-space NC driving parameters and…

Quantum Physics · Physics 2017-06-20 Jonas F. G. Santos , Alex E. Bernardini

Thermodynamics allows the application of Statistical Mechanics to finite and even small systems. As surface effects cannot be scaled away, one has to be careful with the standard arguments of splitting a system into two or bringing two…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

In quantum statistical mechanics, equilibrium states have been shown to be the typical states for a system that is entangled with its environment, suggesting a possible identification between thermodynamic and von Neumann entropies. In this…

Quantum Physics · Physics 2017-06-28 Thibaut Josset

For macroscopic systems, the second law of thermodynamics establishes an inequality between the amount of work performed on a system in contact with a thermal reservoir, and the change in its free energy. For microscopic systems, this…

Statistical Mechanics · Physics 2010-02-08 Eliran Boksenbojm , Bram Wynants , Christopher Jarzynski

The second law of thermodynamics for adiabatic operations -- constraints on state transitions in closed systems under external control -- is one of the fundamental principles of thermodynamics. On the other hand, it is recently established…

Statistical Mechanics · Physics 2026-02-09 Yuuya Chiba , Yasushi Yoneta , Ryusuke Hamazaki , Akira Shimizu

Bell's inequalities, in the form given by Cerf and Adami, are derived from the combination of the second law of thermodynamics and the Markov postulate. Violations of these inequalities are discussed in terms of the mixing characteristics…

Quantum Physics · Physics 2007-05-23 Ian T. Durham