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This article addresses the much debated question whether the degree of hydrophobicity of single-layer graphene (1LG) is different from the one of double-layer graphene (2LG). Knowledge of the water affinity of graphene and its spatial…

Materials Science · Physics 2018-04-27 M. Munz , C. E. Giusca , R. L. Myers-Ward , D. K. Gaskill , O. Kazakova

The interaction of interfacial water with graphitic carbon at the atomic scale is studied as a function of the hydrophobicity of epitaxial graphene. High resolution X-ray reflectivity shows that the graphene-water contact angle is…

The sensitivity of graphene to the surrounding environment is given by its {\pi} electrons, which are directly exposed to molecules in the ambient. The high sensitivity of graphene to the local environment has shown to be both advantageous…

Materials Science · Physics 2018-04-27 Christos Melios , Cristina E. Giusca , Vishal Panchal , Olga Kazakova

The wetting properties of graphene have proven controversial and difficult to assess. The presence of a graphene layer on top of a substrate does not significantly change the wetting properties of the solid substrate, suggesting that a…

Soft Condensed Matter · Physics 2017-02-10 Bijoyendra Bera , Noushine Shahidzadeh , Himanshu Mishra , Daniel Bonn

The effects of humidity on the electronic properties of quasi-free standing one layer graphene (QFS 1LG) are investigated via simultaneous magneto-transport in the van der Pauw geometry and local work function measurements in a controlled…

We demonstrate the temperature-mediated and completely reversible process of desorption-readsorption of water on a few layers of epitaxial graphene on a 4H-SiC(0001) substrate. We show that under ambient conditions water forms solid…

Mesoscale and Nanoscale Physics · Physics 2012-04-17 Tim L. Burnett , Jack Patten , Olga Kazakova

The contact of water with graphene is of fundamental importance and of great interest for numerous promising applications, but how graphene interacts with water remains unclear. Here we used atomic force microscopy to investigate…

Mesoscale and Nanoscale Physics · Physics 2016-04-12 Hsien-Chen Ko , Wei-Hao Hsu , Chih-Wen Yang , Chung-Kai Fang , Yi-Hsien Lu , Ing-Shouh Hwang

Graphene-water interaction has been under scrutiny ever since graphene discovery and realization of its exceptional properties. Several computational and experimental reports exist that have tried to look into the interactions involved,…

Materials Science · Physics 2020-02-19 Priyanka Solanky , Vidushi Sharma , Kamalika Ghatak , Jatin Kashyap , Dibakar Datta

Graphene supported on a substrate in contact with water underpins a wide range of processes and technologies, yet its wettability remains controversial. Understanding how substrate charges and graphene's properties influence water…

Chemical Physics · Physics 2025-11-11 Yongkang Wang , Yair Litman , Minhaeng Cho , Stephen Cox , Mischa Bonn

The interaction of graphene with neighboring materials and structures plays an important role in its behavior, both scientifically and technologically. The interactions are complicated due to the interplay between surface forces and…

Materials Science · Physics 2015-06-05 J. Scott Bunch , Martin L. Dunn

The lubricating ability of graphite largely depends on the environmental humidity, essentially the amount of water in between its layers. In general, intercalated molecules in layered materials modify their extraordinary properties by…

Materials Science · Physics 2019-01-09 A. Qadir , Y. W. Sun , W. Liu , P. Goldberg Oppenheimer , Y. Xu , C. J. Humphreys , D. J. Dunstan

The spatial distributions of the valence-electron density and the total energy reliefs for water (or methanol) migration on the free surface of graphene are obtained, by using the electron density functional and ab initio pseudopotential…

Mesoscale and Nanoscale Physics · Physics 2015-11-30 A. G. Barylka , R. M. Balabai

Water confined between two graphene layers with a small separation forms a two-dimensional ice structure,with an apparent square symmetry [Algara-Siller et al., Nature (London) 519, 443 (2015)], which is poorly understood. A density…

Mesoscale and Nanoscale Physics · Physics 2017-02-06 Niels R. Walet

This article presents a review of epitaxial graphene on silicon carbide, from fabrication to properties, put in the context of other forms of graphene.

Mesoscale and Nanoscale Physics · Physics 2017-04-04 Claire Berger , Edward H. Conrad , Walt A. de Heer

The recent discovery of the ability to perform direct epitaxial growth of graphene layers on semiconductor Ge surfaces led to the huge interest to this topic. One of the reasons for this interest is the chance to overcome several…

Materials Science · Physics 2020-10-20 Yuriy Dedkov , Elena Voloshina

The formation of epitaxial graphene on SiC is monitored in-situ using low-energy electron diffraction (LEED). The possibility of using LEED as an in-situ thickness monitor of the graphene is examined. The ratio of primary diffraction spot…

Materials Science · Physics 2010-11-23 P. J. Fisher , Luxmi , N. Srivastava , S. Nie , R. M. Feenstra

Because of the dominant role of the surface of molecules and their individuality, molecules behave dis-tinctively in a confined space, which has far-reaching implications in many physical, chemical and bio-logical systems. Here, we…

Mesoscale and Nanoscale Physics · Physics 2014-04-29 DaeEung Lee , Gwanghyun Ahn , Sunmin Ryu

The electrical transport properties of epitaxial graphene layers are correlated with the SiC surface morphology. In this study we show by atomic force microscopy and Raman measurements that the surface morphology and the structure of the…

In this work we explore mechanical properties of graphene samples of variable thickness. For this purpose, we coupled a high pressure sapphire anvil cell to a micro-Raman spectrometer. From the evolution of the G band frequency with stress…

We investigate the fine structure of graphene on iridium, which is a model for graphene weakly interacting with a transition metal substrate. Even the highest quality epitaxial graphene displays tiny imperfections, i.e. small biaxial…

Materials Science · Physics 2013-02-25 Nils Blanc , Johann Coraux , Chi Vo-Van , Alpha T. N'Diaye , Olivier Geaymond , Gilles Renaud
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