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Descriptions of molecular systems usually refer to two distinct theoretical frameworks. On the one hand the quantum pure state, i.e. the wavefunction, of an isolated system which is determined to calculate molecular properties and to…

Statistical Mechanics · Physics 2011-03-17 Barbara Fresch , Giorgio J. Moro

It is shown how classical states, meant as states representing a classical object, can be produced in the thermodynamic limit, retaining the unitary evolution of quantum mechanics. Besides, using a simple model of a single spin interacting…

Quantum Physics · Physics 2011-08-04 Marco Frasca

In classical systems, we reexamine how macroscopic structures in equilibrium state connect with spatial con- straint on the systems: e.g., volume and density as the constraint for liquids in rigid box, and crystal lattice as the constraint…

Disordered Systems and Neural Networks · Physics 2016-05-25 Koretaka Yuge

Quantum thermodynamics with open systems is often based on the quantum optical weak-coupling master equation or on operational repeated interaction models, whereas early works on thermalisation and on decoherence theory were mostly…

Quantum Physics · Physics 2025-06-27 Michael Gaida , Giulio Gasbarri , Stefan Nimmrichter

A system composed of identical spins and described by a quantum mechanical pure state is analyzed within the statistical framework presented in Part I of this work. We explicitly derive the typical values of the entropy, of the energy, and…

Quantum Physics · Physics 2010-07-22 Barbara Fresch , Giorgio J. Moro

We describe a possible general and simple paradigm in a classical thermal setting for discrete time crystals (DTCs), systems with stable dynamics which is subharmonic to the driving frequency thus breaking discrete time-translational…

Statistical Mechanics · Physics 2020-01-22 F. M. Gambetta , F. Carollo , A. Lazarides , I. Lesanovsky , J. P. Garrahan

Investigation on foundational aspects of quantum statistical mechanics recently entered a renaissance period due to novel intuitions from quantum information theory and to increasing attention on the dynamical aspects of single quantum…

Quantum Physics · Physics 2010-07-22 Barbara Fresch , Giorgio J. Moro

Uniformity of the probability measure of phase space is considered in the framework of classical equilibrium thermodynamics. For the canonical and the grand canonical ensembles, relations are given between the phase space uniformities and…

Statistical Mechanics · Physics 2008-11-26 W. Wislicki

The article presents results of preliminary study of solutions to recently offered basic thermodynamic equation for equilibrium in chemical systems with focus on chaotic behavior. Classical part of that equation was investigated earlier in…

Chemical Physics · Physics 2016-09-08 B. Zilbergleyt

We explore the idea that non-equilibrium steady states breaking detailed balance are obtained by deforming trajectories (lines in space-time) that have been sampled in a reference system with stochastic dynamics obeying detailed balance,…

Statistical Mechanics · Physics 2018-04-17 Thomas Speck

Classical thermodynamics treats temperature as a state variable characterizing systems in equilibrium with idealized infinite reservoirs. We argue that this framing, while computationally exact, obscures an essential physical reality: any…

Quantum Physics · Physics 2026-04-14 David Vaknin

We study fluctuations of pressure in equilibrium for classical particle systems. In equilibrium statistical mechanics, pressure for a microscopic state is defined by the derivative of a thermodynamic function or, more mechanically, through…

Statistical Mechanics · Physics 2018-10-05 Ken Hiura , Shin-ichi Sasa

On the basis of information theory, a new formalism of classical non-relativistic mechanics of a mass point is proposed. The particle trajectories of a general dynamical system defined on an (1+n)-dimensional smooth manifold are treated…

Quantum Physics · Physics 2014-07-30 Yoshimasa Kurihara , Khiem Hong Phan , Nhi My Uyen Quach

The dynamical stability of massive thin shells with a given equation of state (EOS) is here compared (both for the barotropic and non-barotropic case) with the results coming from thermodynamical stability. Our results show that the…

General Relativity and Quantum Cosmology · Physics 2020-06-15 Santiago Esteban Perez Bergliaffa , Marcelo Chiapparini , Luz Marina Reyes

There are three levels of description in classical statistical mechanics, the microscopic/dynamic, the macroscopic/statistical and the thermodynamic. At one end there is a well-used concept of equilibrium in thermodynamics and at the other…

Statistical Mechanics · Physics 2007-05-23 D. A. Lavis

Non-equilibrium systems in steady states are commonly described by generalized statistical mechanical theories such as non-extensive statistics and superstatistics. Superstatistics assumes that the inverse temperature $\beta = 1/(k_B T)$…

Statistical Mechanics · Physics 2025-03-25 Sergio Davis

A novel geometric formalism for statistical estimation is applied here to the canonical distribution of classical statistical mechanics. In this scheme thermodynamic states, or equivalently, statistical mechanical states, can be…

Quantum Physics · Physics 2009-10-30 Dorje C. Brody , Lane P. Hughston

This paper investigates the stability and bifurcation of the two-dimensional viscous primitive equations with full diffusion under thermal forcing. The system governs perturbations about a motionless basic state with a linear temperature…

Analysis of PDEs · Mathematics 2025-12-16 Song Jiang , Quan Wang

Spontaneous symmetry-breaking in phase transitions occurs when the system Hamiltonian is symmetric under a certain transformation, but the equilibrium states observed in nature are not. Here, we prove that when a discrete symmetry is…

Quantum Physics · Physics 2024-12-13 Ángel L. Corps , Armando Relaño

We reveal a correspondence between temperature and integrability-breaking in classical and quantum many-body systems through the lens of geometry and adiabatic transformations. Decreasing the temperature, obtained in a standard way through…

Statistical Mechanics · Physics 2026-04-03 Hyeongjin Kim , Souvik Bandyopadhyay , Anatoli Polkovnikov