English

A superstatistical measure of distance from canonical equilibrium

Statistical Mechanics 2025-03-25 v1

Abstract

Non-equilibrium systems in steady states are commonly described by generalized statistical mechanical theories such as non-extensive statistics and superstatistics. Superstatistics assumes that the inverse temperature β=1/(kBT)\beta = 1/(k_B T) follows some pre-established statistical distribution, however, it has been previously proved (Physica A 505, 864-870 [2018]) that β\beta cannot be associated to an observable function B(Γ)B(\boldsymbol{\Gamma}) of the microstates Γ\boldsymbol{\Gamma}. In this work, we provide an information-theoretical interpretation of this theorem by introducing a new quantity D\mathcal{D}, the mutual information between β\beta and Γ\boldsymbol{\Gamma}. Our results show that D\mathcal{D} is also a measure of departure from canonical equilibrium, and reveal a minimum, non-zero uncertainty about β\beta given Γ\boldsymbol{\Gamma} for every non-canonical superstatistical ensemble. This supports the use of the mutual information as a descriptor of complexity and correlation in complex systems, also providing in some cases a sound basis for the use of Tsallis' entropic index qq as a measure of distance from equilibrium, being in those cases a proxy for D\mathcal{D}.

Keywords

Cite

@article{arxiv.2402.09393,
  title  = {A superstatistical measure of distance from canonical equilibrium},
  author = {Sergio Davis},
  journal= {arXiv preprint arXiv:2402.09393},
  year   = {2025}
}