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We describe spatio-temporal correlations and heterogeneities in a kinetically constrained glassy model, the Kob-Andersen model. The kinetic constraints of the model alone induce the existence of dynamic correlation lengths, that increase as…

Disordered Systems and Neural Networks · Physics 2009-11-10 Enzo Marinari , Estelle Pitard

Molecular dynamics computer simulations of a binary Lennard-Jones glass under shear are presented. The mechanical response of glassy states having different thermal histories is investigated by imposing a wide range of external shear rates,…

Soft Condensed Matter · Physics 2016-12-14 Gaurav Prakash Shrivastav , Pinaki Chaudhuri , Jürgen Horbach

We study the relaxation dynamics of a binary Lennard-Jones liquid in the presence of an amorphous wall generated from equilibrium particle configurations. In qualitative agreement with the results presented in Nature Phys. {\bf 8}, 164…

Statistical Mechanics · Physics 2014-06-16 Glen M Hocky , Ludovic Berthier , Walter Kob , David R. Reichman

The $\alpha$-process (segmental motion) of thin polystyrene films supported on glass substrate has been investigated in a wider frequency range from 10$^{-3}$ Hz to 10$^4$ Hz using dielectric relaxation spectroscopy and thermal expansion…

Soft Condensed Matter · Physics 2009-10-31 Koji Fukao , Yoshihisa Miyamoto

We study supercooled dynamics in quantum hard-sphere liquid using quantum mode-coupling formulation. In the moderate quantum regime, classical cage effects lead to slower dynamics compared to strongly quantum regime, where tunneling…

Statistical Mechanics · Physics 2021-02-03 Ankita Das , Eran Rabani , Kunimasa Miyazaki , Upendra Harbola

A model is derived for the viscoelastic response of glasses at isothermal uniaxial deformation with small strains. A glass is treated as an ensemble of relaxing units with various activation energies for rearrangement. With reference to the…

Materials Science · Physics 2007-05-23 A. D. Drozdov , J. deC. Christiansen

Densified SiO2 glasses, obtained from different pressure and temperature routes have been annealed over a wide range of temperature far below the glass transition temperature (500$^\circ$C-900$^\circ$C). Hot and cold compressions were…

Dynamical properties of a Lennard-Jones binary mixture embedded in an off lattice matrix of soft spheres are studied in the direct space upon supercooling by molecular dynamics simulations. On lowering temperature the smaller particles tend…

Soft Condensed Matter · Physics 2009-11-10 P. Gallo , R. Pellarin , M. Rovere

Adding plasticizers is a well-known procedure to reduce the glass transition temperature in polymers. It has been recently shown that this effect shows a non-monotonic dependence on the size of additive molecules [The Journal of Chemical…

Soft Condensed Matter · Physics 2020-06-24 Elias M. Zirdehi , Thomas Voigtmann , Fathollah Varnik

Elastic models of the glass transition relate the relaxation dynamics and the elastic properties of structural glasses. They are based on the assumption that the relaxation dynamics occurs through activated events in the energy landscape…

Soft Condensed Matter · Physics 2015-08-20 M. Pica Ciamarra , Peter Sollich

Many-body systems relaxing to equilibrium can exhibit complex dynamics even if their steady state is trivial. At low temperatures or high densities their evolution is often dominated by steric hindrances affecting particle motion [1,2,3].…

Statistical Mechanics · Physics 2016-05-10 M. M. Valado , C. Simonelli , M. D. Hoogerland , I. Lesanovsky , J. P. Garrahan , E. Arimondo , D. Ciampini , O. Morsch

Using molecular simulations and theory, we develop an explicit mapping of the contribution of molecular relaxation modes in glassy thermosets to the shear modulus, where the relaxations were tuned by altering the polarity of side groups.…

Materials Science · Physics 2019-10-15 Robert M. Elder , Alessio Zaccone , Timothy W. Sirk

By systematically investigating the relaxation behavior of a model metallic glass based on the extensive molecular dynamics (MD) simulations combined with the dynamic mechanical spectroscopy method, a pronounced ultra-low temperature peak…

Materials Science · Physics 2020-02-25 B. Wang , L. J. Wang , B. S. Shang , X. Q. Gao , Y. Yang , H. Y. Bai , M. X. Pan , W. H. Wang , P. F. Guan

The dynamics of glass formation in monatomic and binary liquids are studied numerically using a microscopic field theory for the evolution of the time-averaged atomic number density. A stochastic framework combining phase field crystal free…

Materials Science · Physics 2015-05-27 Joel Berry , Martin Grant

We study by light microscopy a soft glass consisting of a compact arrangement of polydisperse elastic spheres. We show that its slow and non-stationary dynamics results from the unavoidable small fluctuations of temperature, which induce…

Soft Condensed Matter · Physics 2009-11-11 Sylvain Mazoyer , Luca Cipelletti , Laurence Ramos

The aging dynamics of a colloidal glass has been studied by multiangle Dynamic Light Scattering, Neutron Spin Echo, X-ray Photon Correlation Spectroscopy and Molecular Dynamics simulations. The two relaxation processes, microscopic (fast)…

A full understanding of glasses requires an accurate atomistic picture of the complex activated processes that constitute the low-temperature dynamics of these materials. To this end, we generate over five thousand activated events in…

Condensed Matter · Physics 2009-10-31 Normand Mousseau , G. T. Barkema , Simon W. de Leeuw

We develop a mesoscopic model to study the plastic behavior of an amorphous material under cyclic loading. The model is depinning-like and driven by a disordered thresholds dynamics which are coupled by long-range elastic interactions. We…

Soft Condensed Matter · Physics 2023-08-07 Dheeraj Kumar , Sylvain Patinet , Craig E. Maloney , Ido Regev , Damien Vandembroucq , Muhittin Mungan

We report a molecular dynamics (MD) study of the collective dynamics of a simple monatomic liquid -interacting through a two body potential that mimics that of lithium- across the liquid-glass transition. In the glassy phase we find…

Disordered Systems and Neural Networks · Physics 2009-11-07 T. Scopigno , G. Ruocco , F. Sette , G. Viliani

We show that in monomeric supercooled liquids and glasses that are plastically flowing at a constant shear stress $\sigma$ while being deformed with strain rate $\dot{\epsilon}$, the microscopic structural relaxation time $\tau_{\rm str}$…

Soft Condensed Matter · Physics 2018-07-17 Joerg Rottler