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The irreversible entropy increase described by the second law of thermodynamics is fundamentally tied to thermalization and the emergence of equilibrium. In the first part of our work (Ref: arXiv.2503.04152), we constructed an isolated gas…

Quantum Physics · Physics 2025-11-24 Xue-Yi Guo

The thermodynamics of quantum systems coupled to periodically modulated heat baths and work reservoirs is developed. By identifying affinities and fluxes, the first and second law are formulated consistently. In the linear response regime,…

Statistical Mechanics · Physics 2016-06-29 Kay Brandner , Udo Seifert

The second law of thermodynamics places a limitation into which states a system can evolve into. For systems in contact with a heat bath, it can be combined with the law of energy conservation, and it says that a system can only evolve into…

Quantum Physics · Physics 2015-11-20 Piotr Ćwikliński , Michał Studziński , Michał Horodecki , Jonathan Oppenheim

Based on quantum statistical mechanics and microscopic quantum dynamics, we prove Planck's and Kelvin's principles for macroscopic systems in a general and realistic setting. We consider a hybrid quantum system that consists of the…

Statistical Mechanics · Physics 2016-05-04 Hal Tasaki

The evolution of an open system is usually associated with the interaction of the system with an environment. A new method to study the open-type system evolution of a qubit (two-level atom) state is established. This evolution is…

We take the view that the standard von Neumann definition, in which the entropy $S^{vN}$ of a pure state is zero, is in evident conflict with the statement of the second law that the entropy of the universe $S_{univ}$ increases in…

Quantum Physics · Physics 2018-10-25 George L. Barnes , Phillip C. Lotshaw , Michael E. Kellman

We present some novel thermodynamic ideas based on the Maupertuis principle. By considering Hamiltonians written in terms of appropriate action-angle variables we show that thermal states can be characterized by the action variables and by…

Statistical Mechanics · Physics 2008-04-15 V. Garcia-Morales , J. Pellicer , J. A. Manzanares

We show that the conservation and the non-additivity of the information, together with the additivity of the entropy make the entropy increase in an isolated system. The collapse of the entangled quantum state offers an example of the…

Quantum Physics · Physics 2009-11-13 Qi-Ren Zhang

The state function entropy and its quantum thermodynamical implication for two typical dissipative systems with anomalous spectral densities are studied by investigating on their low-temperature quantum behavior. In all cases it is found…

Statistical Mechanics · Physics 2015-06-03 Chun-Yang Wang , An-Qi Zhao , Xiang-Mu Kong , Jing-Dong Bao

Why can the world resist the law of entropy increase and produce self-organizing structure? Does the entropy of an isolated system always only increase and never decrease? Can be thermodymamic degradation and self-organizing evolution…

Statistical Mechanics · Physics 2007-10-26 Xiu-San Xing

H-theorem gives necessary conditions for a system to evolve in time with a non-diminishing entropy. In a quantum case the role of H-theorem plays the unitality criteria of a quantum channel transformation describing the evolution of the…

Quantum Physics · Physics 2019-10-30 A. V. Lebedev , G. B. Lesovik

The validity of the Second Law of thermodynamics, indisputable in the macroscopic world, is challenged at the mesoscopic level: a mesoscopic isolated system, possessing spatial dimensions of the order of a few microns, is capable, as shown…

Classical Physics · Physics 2007-05-23 B. Crosignani , P. Di Porto , C. Conti

The second law of thermodynamics states that for a thermally isolated system entropy never decreases. Most physical processes we observe in nature involve variations of macroscopic quantities over spatial and temporal scales much larger…

High Energy Physics - Theory · Physics 2017-02-20 Paolo Glorioso , Hong Liu

For an isolated assembly that comprises a system and its surrounding reservoirs, the total entropy ($S_{a}$) always monotonically increases as time elapses. This phenomenon is known as the second law of thermodynamics ($S_{a}\geq0$). Here…

Computational Physics · Physics 2014-10-22 T. M. Shih , Z. J. Gao , H. Merlitz , L. Rondoni , P. J. Pagni , Z. Chen

Bridging the second law of thermodynamics and microscopic reversible dynamics has been a longstanding problem in statistical physics. We here address this problem on the basis of quantum many-body physics, and discuss how the entropy…

Statistical Mechanics · Physics 2018-01-03 Kazuya Kaneko , Eiki Iyoda , Takahiro Sagawa

Statistical mechanics descriptions of the second law of thermodynamics generally imply point-like particles driven by a dissipative overall mechanism for their simultaneous time-evolution. As the number of involved particles grows larger,…

General Physics · Physics 2016-02-16 Hans R. Moser

We investigate a system of two interacting qubits having one of them isolated and the other coupled to a thermal reservoir. We consider two different models of system-reservoir interaction: i) a "microscopic" model, in which the master…

Quantum Physics · Physics 2021-02-09 G. L. Deçordi , A. Vidiella-Barranco

We review on a recently proposed quantum exception to the second law of thermodynamics. We emphasize that $^4$He superflows, like any other forms of flows, shall carry entropy or heat in a thermal environment. Following that, one can use a…

General Physics · Physics 2016-11-09 Yongle Yu

We review our approach to the second law of thermodynamics, viewed as a theorem asserting the growth of the mean (Gibbs-von Neumann) entropy of quantum spin systems undergoing automorphic (unitary) adiabatic transformations. Non-automorphic…

Mathematical Physics · Physics 2022-08-16 Walter F. Wreszinski

According to the second law of thermodynamics, the arrow of time points to an ever increasing entropy of the Universe. However, exactly how the entropy evolves with time and what drives the growth remain largely unknown. Here, for the first…

Cosmology and Nongalactic Astrophysics · Physics 2012-11-09 Xinghai Zhao , Yuexing Li , Qirong Zhu , Derek Fox