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Coherent electronic transport through individual molecules is crucially sensitive to quantum interference. Using exact diagonalization techniques, we investigate the zero-bias and zero-temperature conductance through $\pi$-conjugated…

Strongly Correlated Electrons · Physics 2015-05-14 Julian Rincon , K. Hallberg , S. Ramasesha

The conductance of a molecular junction is commonly determined by either charge-transfer-doping, where alignment of the Fermi energy to the molecular levels is achieved, or tunnelling through the tails of molecular resonances within the…

Mesoscale and Nanoscale Physics · Physics 2016-08-31 R. Gutierrez , G. Fagas , K. Richter , F. Grossmann , R. Schmidt

We examine theoretically coherent electron transport through the single-molecule magnet Mn$_{12}$, bridged between Au(111) electrodes, using the non-equilibrium Green's function method and the density-functional theory. We analyze the…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 Kyungwha Park , Salvador Barraza-Lopez , Victor M. Garcia-Suarez , Jaime Ferrer

This study investigates the potential impact of intramolecular excitations on the active regions of biomolecular chains, which may play a role in physiological processes within living cells. We assumed that an excitation localized in a…

Other Condensed Matter · Physics 2025-10-29 Dalibor Chevizovich , Slobodanka Galovic , Vasilije Matic , Zoran Ivic , Zeljko Przulj

We review the Bethe-Salpeter equation (BSE) approach to the calculation of electronic excitation energies of molecular systems. We recall the general Green's function many-theory formalism and give the working equations of the BSE approach…

Chemical Physics · Physics 2013-04-05 Elisa Rebolini , Julien Toulouse , Andreas Savin

We measure the low bias conductance of a series of substituted benzene diamine molecules while breaking a gold point contact in a solution of the molecules. Transport through these substituted benzenes is by means of nonresonant tunneling…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Latha Venkataraman , Young S. Park , Adam C. Whalley Colin Nuckolls , Mark S. Hybertsen , Michael L. Steigerwald

We consider electronic transport through break-junctions bridged by a single molecule in the Kondo regime. We describe the system by a two-channel Anderson model. We take the tunneling matrix elements to depend on the position of the…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Jernej Mravlje , Anton Ramsak

We examine the dynamics of a correlated quantum dot in the mixed valence regime. We perform numerically exact calculations of the current after a quantum quench from equilibrium by rapidly applying a bias voltage in a wide range of initial…

Strongly Correlated Electrons · Physics 2016-01-27 Andrey E. Antipov , Qiaoyuan Dong , Emanuel Gull

We study numerically the influence of strong Coulomb repulsion on the current through molecular wires that are driven by external electromagnetic fields. The molecule is described by a tight-binding model whose first and last site is…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Franz J. Kaiser , Peter Hänggi , Sigmund Kohler

Quantum transport through single molecules is very sensitive to the strength of the molecule-electrode contact. Here, we investigate the behavior of a model molecular junction weakly coupled to external electrodes in the case where charging…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Bo Song , Dmitry A. Ryndyk , Gianaurelio Cuniberti

We develop a microscopic model to investigate current-induced light emission in single-molecule tunnel junctions, where a two-level system interacts with a plasmonic field. Using the quantum master equation, we explore the transition from…

Mesoscale and Nanoscale Physics · Physics 2025-07-08 Andrés Bejarano , Moritz Frankerl , Rémi Avriller , Thomas Frederiksen , Fabio Pistolesi

We show that two-particle interferences can be used to probe the nuclear motion in a doubly-excited hydrogen molecule. The dissociation of molecular hydrogen by electron impact involves several decay channels, associated to different…

We present a qualitative model for a fundamental process in molecular electronics: the change in conductance upon bond breaking. In our model a diatomic molecule is attached to spin-polarized contacts. Employing a Hubbard Hamiltonian,…

Materials Science · Physics 2008-06-24 Ali Goker , Francois Goyer , Matthias Ernzerhof

The interaction of carbon monoxide molecules with atomic-scale platinum nanojunctions is investigated by low temperature mechanically controllable break junction experiments. Combining plateaus' length analysis, two dimensional…

Mesoscale and Nanoscale Physics · Physics 2016-01-27 Péter Makk , Zoltán Balogh , Szabolcs Csonka , András Halbritter

We propose an entanglement mechanism of nuclear spins in quantum dots driven by the electric current. The current accompanied by the spin flip in quantum dots gradually increases components of larger total spin of nuclei. This entangled…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Mikio Eto

We propose a new method for simulating electron dynamics in open quantum systems out of equilibrium, using a finite atomistic model. The proposed method is motivated by the intuitive and practical nature of the driven Liouville von-Neumann…

Mesoscale and Nanoscale Physics · Physics 2014-09-23 Tamar Zelovich , Leeor Kronik , Oded Hod

Catalysis-driven synthetic molecular motors operate in a loose mechanochemical coupling regime, one in which a decomposition of a fuel molecule does not reliably produce a forward step. In that regime, stochastic backward steps can…

Statistical Mechanics · Physics 2026-01-16 Geyao Gu , Drew Alvarez , John Strahan , Alex Albaugh , Emanuele Penocchio , Todd R. Gingrich

We investigate the quantum many-body dynamics of dissociation of a Bose-Einstein condensate of molecular dimers into pairs of constituent bosonic atoms and analyze the resulting atom-atom correlations. The quantum fields of both the…

Other Condensed Matter · Physics 2007-05-23 C. M. Savage , P. E. Schwenn , K. V. Kheruntsyan

We consider exciton effects on current in molecular nanojunctions, using a model comprising a two two-level sites bridge connecting free electron reservoirs. Expanding the density operator in the many-electron eigenstates of the uncoupled…

Strongly Correlated Electrons · Physics 2015-05-14 GuangQi Li , Boris D. Fainberg , Abraham Nitzan , Sigmund Kohler , Peter Hänggi

We systematically investigate the ground state and elementary excitations of a Bose-Einstein Condensate with a synthetic vector potential, which is induced by the many-body effects and atom-light coupling. For a sufficiently strong…

Quantum Gases · Physics 2015-07-08 Jun-hui Zheng , Bo Xiong , G. Juzeliunas , Daw-Wei Wang