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A comprehensive review is presented of single molecule junction conductance measurements across families of molecules measured while breaking a gold point contact in a solution of molecules with amine end groups. A theoretical framework…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Mark S. Hybertsen , Latha Venkataraman , Jennifer E. Klare , Adam C. Whalley , Michael L. Steigerwald , Colin Nuckolls

An accurate description of electron transport at a molecular level requires a precise treatment of quantum effects. These effects play a crucial role in determining the electron transport properties of single molecules, such as…

Quantum Physics · Physics 2020-12-18 Soran Jahangiri , Juan Miguel Arrazola , Alain Delgado

The paper proposes the method to analyze the internal dynamics of nanoscopic systems by periodic modulation of the electrochemical potentials of the attached leads and measuring the time-averaged current. The idea is presented using the…

Mesoscale and Nanoscale Physics · Physics 2017-11-15 Krzysztof Ptaszynski

Formation of a magnetic hysteresis loop with respect to a bias voltage is investigated theoretically in a spin-valve device based on a single magnetic molecule. We consider a device consisting of two ferromagnetic electrodes bridged by a…

Mesoscale and Nanoscale Physics · Physics 2018-05-09 Anna Płomińska , Maciej Misiorny , Ireneusz Weymann

We study the transport through a molecular junction exhibiting interference effects. We show that these effects can still be observed in the presence of molecular vibrations if Coulomb repulsion is taken into account. In the Kondo regime,…

Strongly Correlated Electrons · Physics 2019-09-04 P. Roura-Bas , F. Güller , L. Tosi , A. A. Aligia

We address a molecular dissociation mechanism that is known to occur when a H 2 molecule approaches a catalyst with its molecular axis parallel to the surface. It is found that molecular dissociation is a form of quantum dynamical phase…

Chemical Physics · Physics 2016-05-31 Andres Ruderman , Axel Dente , Elizabeth Santos , Horacio Miguel Pastawski

We study the time evolution and steady state of the charge current in a single-impurity Anderson model, using matrix product states techniques. A nonequilibrium situation is imposed by applying a bias voltage across one-dimensional…

Strongly Correlated Electrons · Physics 2013-07-31 Martin Nuss , Martin Ganahl , Hans Gerd Evertz , Enrico Arrigoni , Wolfgang von der Linden

For the metals Au, Pt and Ir it is possible to form freely suspended monatomic chains between bulk electrodes. The atomic chains sustain very large current densities, but finally fail at high bias. We investigate the breaking mechanism,…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 R. H. M. Smit , C. Untiedt , J. M. van Ruitenbeek

We calculate non-perturbatively the inelastic effects on the conductance through a conjugated molecular wire-metal heterojunction, including realistic electron-phonon coupling. We show that at sub-band-gap energies the current is dominated…

Materials Science · Physics 2009-10-31 H. Ness , A. J. Fisher

Within the framework of master equation, we study decay dynamics of an atom-molecule system strongly coupled by two photoassociation lasers. Summing over the infinite number of electromagnetic vacuum modes that are coupled to the…

Atomic Physics · Physics 2014-05-23 Arpita Rakshit , Saikat Ghosh , Bimalendu Deb

The method of defining quantum joint probabilities of two events is applied to a multimode system of trapped Bose-condensed atoms. The coherent modes are generated by modulating the trapping potential with an alternating field with a…

Quantum Gases · Physics 2015-06-17 V. I. Yukalov , E. P. Yukalova , D. Sornette

Finite-bias electron transport through single molecules generally induces nonequilibrium molecular vibrations (phonons). By a mapping to a Fokker-Planck equation, we obtain analytical scaling forms for the nonequilibrium phonon distribution…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Jens Koch , Matthias Semmelhack , Felix von Oppen , Abraham Nitzan

The dynamics of a single spin embedded in a the tunnel junction between ferromagnetic contacts is strongly affected by the exchange coupling to the tunneling electrons. Moment reversal of the local spin induced by the bias voltage across…

Mesoscale and Nanoscale Physics · Physics 2008-06-04 J. Fransson

The analytical theory for the voltage-current characteristics of the large inductance (L>100 pH) high-T_c DC SQUIDs that has been developed previously is consistently compared with the computer simulations and the experiment. The…

Superconductivity · Physics 2007-05-23 Ya. S. Greenberg , I. L. Novikov

We present a hierarchical quantum master equation (HQME) approach, which allows the numerically exact evaluation of higher-order current cumulants in the framework of full counting statistics for nonequilibrium charge transport in…

Mesoscale and Nanoscale Physics · Physics 2020-02-20 C. Schinabeck , M. Thoss

We analyze the effect of an external electric field on the electronic structure of molecules which have been recently studied as molecular wires or diodes. We use a self-consistent tight binding technique which provides results in good…

Computational Physics · Physics 2011-09-12 Christophe Krzeminski , Christophe Delerue , Guy Allan

We study the motion (translational, vibrational, and rotational) of a diatomic impurity immersed in an electron liquid and exposed to electronic current. An approach based on the linear response time-dependent density functional theory…

Materials Science · Physics 2024-07-12 Vladimir U. Nazarov , Tchavdar N. Todorov , E. K. U. Gross

A conducting bridge of a single hydrogen molecule between Pt electrodes is formed in a break junction experiment. It has a conductance near the quantum unit, G_0 = 2e^2/h, carried by a single channel. Using point contact spectroscopy three…

Mesoscale and Nanoscale Physics · Physics 2017-12-11 D. Djukic , K. S. Thygesen , C. Untiedt , R. H. M. Smit , K. W. Jacobsen , J. M. van Ruitenbeek

We consider a single molecule circuit embedded into solvent. The Born dielectric solvation model is combined with Keldysh nonequilibrium Green's functions to describe the electron transport properties of the system. Depending on the…

Mesoscale and Nanoscale Physics · Physics 2012-01-26 Alan A. Dzhioev , D. S. Kosov

Quantum interference in coherent transport through single molecular rings may provide a mechanism to control current in molecular electronics. We investigate its applicability by using a single-particle Green function method combined with…

Mesoscale and Nanoscale Physics · Physics 2009-08-11 San-Huang Ke , Weitao Yang , Harold U. Baranger
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