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The photoelectron spectrum of water has been recorded in the vicinity of the ${\mathrm {\tilde A^+}}$ $\leftarrow$ $\tilde{\mathrm{X}}$ transition between 112 000 and 116 000 cm$^{-1}$ (13.89-14.38 eV). The high-resolution allowed the…

Chemical Physics · Physics 2017-05-03 Clément Lauzin , Bérenger Gans , Frédéric Merkt

$^{133}\text{Ba}^+$ has been identified as an attractive ion for quantum information processing due to the unique combination of its spin-1/2 nucleus and visible wavelength electronic transitions. Using a microgram source of radioactive…

Quantum Physics · Physics 2017-09-13 David Hucul , Justin E. Christensen , Eric R. Hudson , Wesley C. Campbell

We study the internal state dynamics of optically trapped polyatomic molecules subject to room temperature blackbody radiation. Using rate equations that account for radiative decay and blackbody excitation between rovibrational levels of…

Efficient and reversible optical to microwave coherent transducers are required to enable entanglement transfer between superconducting qubits and light for quantum networks. Rare-earth-doped crystals that possess narrow optical and spin…

We report the measurement of the 1$^{1}\Sigma\longrightarrow$ 2$^{1}\Sigma$ transition of CaH$^+$ by resonance-enhanced photodissociation of CaH$^+$ that is co-trapped with laser-cooled Ca$^+$ . We observe four resonances that we assign to…

Atomic Physics · Physics 2016-09-30 Rene Rugango , Aaron T. Calvin , Smitha Janardan , Gang Shu , Kenneth R. Brown

Following the bichromatic sub-Doppler cooling scheme on the D1 line of 40K recently demonstrated in (Fernandes et al. 2012), we introduce a similar technique for 7Li atoms and obtain temperatures of 60 uK while capturing all of the 5x10^8…

The present work reports the spectroscopic parameters and molecular properties for the ground electronic state, $^1\Sigma^+$, of CdH$^+$, HgH$^{+}$, and YbH$^{+}$ molecular ions. We have used the state-of-the-art relativistic coupled…

Atomic Physics · Physics 2025-11-20 Ankush Thakur , Renu Bala , H. S. Nataraj

The narrow transition from the lowest rovibrational level of the $\mathrm{X}^{1}\Sigma^{+}$ electronic ground state to the lowest vibrational level of the $\mathrm{b}^{3}\Pi_{0}$ potential provides opportunities for achieving…

Laser cooling methods for trapped ions are most commonly studied at low energies, i.e., in the Lamb-Dicke regime. However, ions in experiments are often excited to higher energies for which the Lamb-Dicke approximation breaks down. Here we…

The development of spin qubits for quantum technologies requires their protection from the main source of finite-temperature decoherence: atomic vibrations. Here we eliminate one of the main barriers to the progress in this field by…

Mesoscale and Nanoscale Physics · Physics 2020-04-09 Alessandro Lunghi , Stefano Sanvito

The translational motion of molecular ions can be effectively cooled sympathetically to translational temperatures below 100 mK in ion traps through Coulomb interactions with laser-cooled atomic ions. The ro-vibrational degrees of freedom,…

Atomic Physics · Physics 2009-11-10 I. S. Vogelius , L. B. Madsen , M. Drewsen

Radium-225 (nuclear spin $I=1/2$) ions possess electronic hyperfine transitions that are first-order insensitive to magnetic field noise, which is advantageous for optical clocks and quantum information science. We report on laser cooling…

The direct laser cooling of neutral diatomic molecules in molecular beams suggests that trapped molecular ions can also be laser cooled. The long storage time and spatial localization of trapped molecular ions provides the opportunity for…

We measure the complete set of transition frequencies necessary to laser cool and trap MgF molecules. Specifically, we report the frequency of multiple low $J$ transitions of the $X^2\Sigma^+(v^{\prime\prime}=0,1) \rightarrow…

We report measurements of the lifetimes of the 3d $^2$D$_{5/2}$ and 3d $^2$D$_{3/2}$ metastable states of a single laser-cooled $^{40}$Ca$^+$ ion in a linear Paul trap. We introduce a new measurement technique based on high-efficiency…

Accurate line lists for three molecules, BeH, MgH and CaH, in their ground electronic states are presented. These line lists are suitable for temperatures relevant to exoplanetary atmospheres and cool stars (up to 2000K). A combination of…

Solar and Stellar Astrophysics · Physics 2012-08-22 Benjamin Yadin , Thomas Veness , Pierandrea Conti , Christian Hill , Sergei N. Yurchenko , Jonathan Tennyson

Molecular laser cooling and trapping requires addressing all spontaneous decays to excited vibrational states that occur at the $\gtrsim 10^{-4} - 10^{-5}$ level, which is accomplished by driving repumping transitions out of these states.…

Atomic Physics · Physics 2023-06-06 Nickolas H. Pilgram , Arian Jadbabaie , Chandler J. Conn , Nicholas R. Hutzler

We present a deperturbation analysis of the spin-orbit coupled $\rm A^1\Sigma^+$ and $\rm b^3\Pi_{0^+}$ states of LiRb based on the rovibrational energy levels observed previously by photoassociation spectroscopy in bosonic $^7$Li$^{85}$Rb…

Atomic Physics · Physics 2024-10-15 Yide Yin , Xuhui Bai , Xuechun Li , Xin-Yu Luo , Jie Yu , Gaoren Wang , Yongchang Han

Starting from an ultracold sample of ground-state $^{23}$Na$^{87}$Rb molecules, we investigate the lowest ro-vibrational level of the $b^3\Pi$ state with high resolution laser spectroscopy. This electronic spin-forbidden $X^1\Sigma^+…

Atomic Physics · Physics 2021-11-17 Junyu He , Junyu Lin , Romain Vexiau , Nadia Bouloufa , Olivier Dulieu , Dajun Wang

Experiments with antihydrogen ($\overline{\text{H}}$) for a study of matter--antimatter symmetry and antimatter gravity require ultracold $\overline{\text{H}}$ to reach ultimate precision. A promising path towards anti-atoms much colder…

Atomic Physics · Physics 2018-04-04 G. Cerchiari , A. Kellerbauer , M. S. Safronova , U. I. Safronova , P. Yzombard