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A method to calculate the one-body Green's function for ground states of correlated electron materials is formulated by extending the variational Monte Carlo method. We benchmark against the exact diagonalization (ED) for the one- and…

Strongly Correlated Electrons · Physics 2020-11-11 Maxime Charlebois , Masatoshi Imada

The quasiparticle band structures of four polytypes 3C, 6H, 4H, and 2H of GaP, GaAs, GaSb, InP, InAs, and InSb are computed with high accuracy including spin-orbit interaction applying a recently developed approximate calculation scheme,…

Materials Science · Physics 2015-06-05 Abderrezak Belabbes , Christian Panse , Jürgen Furthmüller , Friedhelm Bechstedt

We propose here a single Pfaffian correlated variational ansatz, that dramatically improves the accuracy with respect to the single determinant one, while remaining at a similar computational cost. A much larger correlation energy is indeed…

Chemical Physics · Physics 2020-07-28 Claudio Genovese , Tomonori Shirakawa , Kousuke Nakano , Sandro Sorella

The electronic bands of twisted bilayer graphene (TBLG) with a large-period moir\'e superlattice fracture to form narrow Bloch minibands that are spectrally isolated by forbidden energy gaps from remote dispersive bands. When these gaps are…

Mesoscale and Nanoscale Physics · Physics 2020-10-28 Vo Tien Phong , E. J. Mele

The electronic energy band spectra of the alkali metal chalcogenides M$_2$A (M: Li, Na, K, Rb; A: O, S, Se, Te) have been evaluated within the projector augmented waves (PAW) approach by means of the ABINIT code. The Kohn-Sham…

Materials Science · Physics 2015-10-23 S. V. Syrotyuk , V. M. Shved

Experimental advances in the fabrication and characterization of few-layer materials stacked at a relative twist of small angle have recently shown the emergence of flat energy bands. As a consequence electron interactions become relevant,…

Strongly Correlated Electrons · Physics 2020-03-02 D. M. Kennes , L. Xian , M. Claassen , A. Rubio

We use the moment approach of Nolting (exact sum rules) (Z. Physik 255, 25 (1972)) for the attractive Hubbard model in the superconducting phase. Our diagonal and off - diagonal spectral functions are constructed and evaluated with the sum…

Condensed Matter · Physics 2007-05-23 J. J. Rodriguez - Nunez , C. E. Cordeiro , A. Delfino

We study the electronic states of giant single-shell and the recently discovered nested multi-shell carbon fullerenes within the tight-binding approximation. We use two different approaches, one based on iterations and the other on…

Materials Science · Physics 2009-10-22 Yeong-Lieh Lin , Franco Nori

We use fully self-consistent GW calculations on diamond and silicon carbide to reparametrize the Heyd-Scuseria-Ernzerhof exact exchange density functional for use in band structure calculations of semiconductors and insulators. We show that…

Mesoscale and Nanoscale Physics · Physics 2015-08-05 V. Zólyomi , J. Kürti

We present a method to efficiently combine the computation of electron-electron and electron-phonon self-energies, which enables the evaluation of electron-phonon coupling at the $G_0W_0$ level of theory for systems with hundreds of atoms.…

Materials Science · Physics 2021-12-14 Han Yang , Marco Govoni , Arpan Kundu , Giulia Galli

We extend density matrix embedding theory to periodic systems, resulting in an electronic band structure method for solid-state materials. The electron correlation can be captured by means of a local impurity model using various choices of…

Strongly Correlated Electrons · Physics 2019-09-27 Hung Q. Pham , Matthew R. Hermes , Laura Gagliardi

We compare the classification of the electron bands in graphene, obtained by group theory algebra in the framework of tight-binding model (TBM), with that calculated in the density-functional theory (DFT) framework. Identification in the…

Mesoscale and Nanoscale Physics · Physics 2014-05-01 E. Kogan , V. U. Nazarov , V. M. Silkin , M. Kaveh

Coupled-cluster theories can be used to compute ab initio electronic correlation energies of real materials with systematically improvable accuracy. However, the widely-used coupled cluster singles and doubles plus perturbative triples…

Materials Science · Physics 2024-03-01 Nikolaos Masios , Andreas Irmler , Tobias Schäfer , Andreas Grüneis

The recent experimental synthesis of 2D graphitic C3N5 has attracted lot of interests in its electronic and optical properties and its comparison with other graphitic C3N4 and C3N3. To this end, we performed DFT calculations using more…

Materials Science · Physics 2022-07-19 Shakti Singh , P. Anees , Sharat Chandra , Tapan Ghanty

Density functional theory (DFT) and thermal DFT (thDFT) calculations were used to evaluate the energy band structure, bandgap, and the total energy of various graphene quantum dots (GQDs). The DFT calculations were performed using local…

Materials Science · Physics 2021-12-20 Majid Ghandchi , Ghafar Darvish , Mohammad Kazem Moravvej-Farshi

Coupled-cluster theory with single and double excitations (CCSD) is a promising ab initio method for the electronic structure of three-dimensional metals, for which second-order perturbation theory (MP2) diverges in the thermodynamic limit.…

Materials Science · Physics 2021-06-16 James M. Callahan , Malte F. Lange , Timothy C. Berkelbach

Electron pairing in one-dimensional binary Hubbard chains is studied for different values of the band-filling using the Density Matrix Renormalization Group method. The systems consist of linear arrays of sites with two types of on-site…

Strongly Correlated Electrons · Physics 2015-05-18 Y. Arredondo , O. Navarro

Exploratory variational pseudopotential density functional calculations are performed for the electronic properties of many-electron systems in the 3D cartesian coordinate grid (CCG). The atom-centered localized gaussian basis set,…

Chemical Physics · Physics 2015-05-18 Amlan K Roy

The 2D Fermi surface of 1st stage PdAl2Cl8 acceptor-type graphite intercalation compounds (GICs) has been investigated using the Shubnikov-de Haas (SdH) effect. One fundamental frequency is observed, the angular variation of which confirms…

Materials Science · Physics 2007-05-23 R. T. F. van Schaijk , A. de Visser , E. McRae , B. Sundqvist , T. Wagberg , R. Vangelisti

We present ab initio quasiparticle self-energy calculations in crystalline GaAs for cases of intense electronic excitation (~ 10% of valence electrons excited into conduction band), relevant for high-intensity ultra-short pulsed laser…

Materials Science · Physics 2009-11-10 Catalin D. Spataru , Lorin X. Benedict , Steven G. Louie