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The search for intrinsic excitonic insulators (EI) has long been confounded by coexisting electron-phonon coupling in bulk materials. Although the ground state of an EI may be difficult to differentiate from density-wave orders or other…

Recently, we employed electronic polarization-resolved Raman spectroscopy to reveal the strongly correlated excitonic insulator (EI) nature of Ta2NiSe5, Volkov et al. [arXiv:2007.07344], and also showed that for…

Strongly Correlated Electrons · Physics 2021-07-20 Mai Ye , Pavel A. Volkov , Himanshu Lohani , Irena Feldman , Minsung Kim , Amit Kanigel , Girsh Blumberg

The spontaneous condensation of excitons in the excitonic insulating phase has been reported in Ta$_2$NiSe$_5$ below 325 K. In this context, we present the temperature-dependent optical pump optical probe spectroscopy of Ta$_2$NiSe$_5$,…

Materials Science · Physics 2024-12-02 Vikas Arora , Sukanya Pal , Luminita Harnagea , D. V. S. Muthu , A K Sood

Electron-hole bound pairs, or excitons, are common excitations in semiconductors. They can spontaneously form and ``condense'' into a new insulating ground state -- the so-called excitonic insulator -- when the energy of electron-hole…

The excitonic insulator is an intriguing correlated electron phase formed of condensed excitons. A promising candidate is the small band gap semiconductor Ta2NiSe5. Here we investigate the quasiparticle and coherent phonon dynamics in…

Strongly Correlated Electrons · Physics 2018-08-01 Daniel Werdehausen , Tomohiro Takayama , Gelon Albrecht , Yangfan Lu , Hidenori Takagi , Stefan Kaiser

Using a combination of infrared ellipsometry, time-domain terahertz spectroscopy, and far-infrared reflectometry we have obtained the $ac$-plane complex dielectric function of monoclinic ($C2/c$) Ta$_2$NiSe$_5$ and orthorhombic ($Cmcm$)…

Strongly Correlated Electrons · Physics 2018-09-12 T. I. Larkin , R. D. Dawson , M. Höppner , T. Takayama , M. Isobe , Y. -L. Mathis , H. Takagi , B. Keimer , A. V. Boris

The electronic structures and topological properties of the orthorhombic and monoclinic phases of the quasi-one-dimensional excitonic insulator Ta2NiSe5 are investigated based on density functional theory. In contrast to a single parity or…

Materials Science · Physics 2022-02-02 Xiaobo Ma , Guangwei Wang , Huican Mao , Zhihong Yuan , Tianye Yu , Rui Liu , Yiran Peng , Pengyu Zheng , Zhiping Yin

Coulomb attraction between electrons and holes in a narrow-gap semiconductor or a semimetal is predicted to lead to an elusive phase of matter dubbed 'excitonic insulator'. However, direct observation of such electronic instability remains…

Strongly Correlated Electrons · Physics 2021-08-09 Kwangrae Kim , Hoon Kim , Jonghwan Kim , Changil Kwon , Jun Sung Kim , B. J. Kim

We performed ultrasonic measurements on (Ta$_{0.952}$V$_{0.048}$)$_2$NiSe$_5$ to investigate the contribution of acoustic phonons at the zone center to structural and possible excitonic transitions. The transverse elastic constant $C_{55}$…

Strongly Correlated Electrons · Physics 2022-01-19 Ryosuke Kurihara , Yusuke Hirose , Sumika Sano , Keisuke Mitsumoto , Atsushi Miyake , Masashi Tokunaga , Rikio Settai

Excitonic insulator (EI) was proposed in 60's as a distinct insulating state originating from pure electronic interaction, but its material realization has been elusive with extremely few material candidates and with only limited evidence…

Materials Science · Physics 2019-03-06 Jinwon Lee , Chang-Jong Kang , Man Jin Eom , Jun Sung Kim , Byung Il Min , Han Woong Yeom

Ta$_2$NiSe$_5$ became one of the most investigated candidate materials for hosting an excitonic insulator ground state. Many studies describe the corresponding phase transition as a condensation of excitons breaking a continuous symmetry.…

Strongly Correlated Electrons · Physics 2021-03-04 Min-Jae Kim , Armin Schulz , Tomohiro Takayama , Masahiko Isobe , Hidenori Takagi , Stefan Kaiser

An excitonic insulator (EI) is a charge-neutral bosonic condensate of spontaneously formed electron-hole pairs. Exotic quantum phenomena such as dissipationless charge neutral transport and huge potential for optoelectronic applications…

Strongly Correlated Electrons · Physics 2025-12-03 Seokjin Bae , Arjun Raghavan , Irena Feldman , Amit Kanigel , Vidya Madhavan

Excitonic insulators host a condensate of electron-hole pairs at equilibrium, giving rise to collective many-body effects. Although several materials have emerged as excitonic insulator candidates, evidence of long-range coherence is…

We report high-resolution inelastic x-ray measurements of the soft phonon mode in the charge-density-wave compound TiSe$_2$. We observe a complete softening of a transverse optic phonon at the L point, i.e. q = (0.5, 0, 0.5), at T ~…

Strongly Correlated Electrons · Physics 2015-05-28 F. Weber , S. Rosenkranz , J. -P. Castellan , R. Osborn , G. Karapetrov , R. Hott , R. Heid , K. -P. Bohnen , A. Alatas

We report on electric-field and temperature dependent transport measurements in exfoliated thin crystals of Bi$_{2}$Se$_{3}$ topological insulator. At low temperatures ($< 50$ K) and when the chemical potential lies inside the bulk gap, the…

Mesoscale and Nanoscale Physics · Physics 2015-06-19 M. V. Costache , I. Neumann , J. F. Sierra , V. Marinova , M. M. Gospodinov , S. Roche , S. O. Valenzuela

The high-temperature phase of Ta$_\mathrm{2}$NiSe$_\mathrm{5}$, a near-zero-gap semiconductor ($E_G$ = 0), is a promising candidate for an excitonic insulator. Given the dome-like evolution expected for an excitonic insulator around $E_G$,…

The excitonic insulator is an intriguing electronic phase of quasi-condensed excitons. A prominent candidate is the small bandgap semiconductor Ta2NiSe5, in which excitons are believed to undergo a BEC-like transition. But experimental…

We analyze the measured optical conductivity spectra using the density-functional-theory-based electronic structure calculation and density-matrix renormalization group calculation of an effective model. We show that, in contrast to a…

Strongly Correlated Electrons · Physics 2018-06-18 K. Sugimoto , S. Nishimoto , T. Kaneko , Y. Ohta

Ta$_2$NiSe$_5$ is an excitonic insulator candidate showing the semiconductor/semimetal-to-insulator (SI) transition below $T_{\text{c}}$ = 326 K. However, since a structural transition accompanies the SI transition, deciphering the role of…

The influence of phonons on the formation of the excitonic insulator has hardly been analyzed so far. Recent experiments on $\rm Ta_2NiSe_5$, 1$T$-$\rm TiSe_2$, and $\rm TmSe_{0.45}Te_{0.55}$, being candidates for realizing the…

Strongly Correlated Electrons · Physics 2015-06-22 B. Zenker , H. Fehske , H. Beck
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