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We report the complex dielectric function of the quasi-one-dimensional chalcogenide Ta$_2$NiSe$_5$, which exhibits a structural phase transition that has been attributed to exciton condensation below $T_c = 326$ K, and of the isostructural…

Strongly Correlated Electrons · Physics 2017-05-24 T. I. Larkin , A. N. Yaresko , D. Pröpper , K. A. Kikoin , Y. F. Lu , T. Takayama , Y. - L. Mathis , A. W. Rost , H. Takagi , B. Keimer , A. V. Boris

Femtosecond time-resolved mid-infrared reflectivity is used to investigate the electron and phonon dynamics occurring at the direct band gap of the excitonic insulator Ta$_2$NiSe$_5$ below the critical temperature of its structural phase…

The layered compound $\mathrm{Ta_2NiSe_5}$ is a quasi-one-dimensional and narrow-gap semiconductor, which is proposed to undergo a transition to an excitonic insulator at $T_\mathrm{c}=326$ K. We found a clear anomaly at $T_\mathrm{c}$ in…

Strongly Correlated Electrons · Physics 2021-09-22 Yuan-Shan Zhang , Jan A. N. Bruin , Yosuke Matsumoto , Masahiko Isobe , Hidenori Takagi

Topological insulators are a novel class of quantum materials characterized by protected gapless surface or edge states but insulating bulk states which is due to presence of spin-orbit interactions and time-reversal symmetry. Such an…

Strongly Correlated Electrons · Physics 2024-07-11 Vivek Kumar , Pradeep Kumar

We present a neutron scattering study of phonons in single crystals of (Pb$_{0.5}$Sn$_{0.5}$)$_{1-x}$In$_x$Te with $x=0$ (metallic, but nonsuperconducting) and $x=0.2$ (nonmetallic normal state, but superconducting). We map the phonon…

Excitons, quasiparticles of electrons and holes bound by Coulombic attraction, are created transiently by light and play an important role in optoelectronics, photovoltaics and photosynthesis. While they are also predicted to form…

Strongly Correlated Electrons · Physics 2021-09-29 Keisuke Fukutani , Roland Stania , Chang Il Kwon , Jun Sung Kim , Ki Jeong Kong , Jaeyoung Kim , Han Woong Yeom

We present an angle-resolved photoemission study of the electronic band structure of the excitonic insulator Ta$_2$NiSe$_5$, as well as its evolution upon Sulfur doping. Our experimental data show that while the excitonic insulating phase…

We present electronic structure calculations, electrical resistivity data and the first specific heat measurements in the normal and superconducting states of quasi-one-dimensional M2Mo6Se6 (M = Tl, In, Rb). Rb2Mo6Se6 undergoes a…

Strongly Correlated Electrons · Physics 2013-03-06 A. P. Petrović , R. Lortz , G. Santi , M. Decroux , H. Monnard , L. Boeri , O. K. Andersen , J. Kortus , D. Salloum , P. Gougeon , M. Potel , Ø. Fischer

We investigate an interesting anisotropic van der Waals material, Ta$_{2}$NiSe$_{5}$, using optical spectroscopy. Ta$_{2}$NiSe$_{5}$ has been known as one of the few excitonic insulators proposed over 50 years ago. Ta$_{2}$NiSe$_{5}$ has…

Materials Science · Physics 2018-08-21 Yu-Seong Seo , Man Jin Eom , Jun Sung Kim , Chang-Jong Kang , Byung Il Min , Jungseek Hwang

We present a combined density-functional-perturbation-theory and inelastic neutron scattering study of the lattice dynamical properties of YNi2B2C. In general, very good agreement was found between theory and experiment for both phonon…

Superconductivity · Physics 2015-06-19 F. Weber , L. Pintschovius , W. Reichardt , R. Heid , K. -P. Bohnen , A. Kreyssig , D. Reznik , K. Hradil

We have built an electron-phonon coupling model to describe the behavior of the NbxSi1-x transition edge sensor (TES) bolometers, fabricated by electron-beam coevaporation and photolithography techniques on a 2-inch silicon wafer. The…

Instrumentation and Methods for Astrophysics · Physics 2014-02-18 Shu-chen Liu , Stefanos Marnieros , Louis Dumoulin , Youri Dolgorouki , Laurent Berge , Sophie Collin

Phonon measurements in the A15-type superconductors were complicated in the past because of the unavailability of large single crystals for inelastic neutron scattering, e.g., in the case of Nb$_3$Sn, or unfavorable neutron scattering…

Superconductivity · Physics 2019-04-19 A. Sauer , D. A. Zocco , A. H. Said , R. Heid , A. Böhmer , F. Weber

The strong coupling between lattice modes and charges which leads to the formation of charge density waves in materials such as the transition-metal dichalcogenides may also give rise to superconductivity in the same materials, mediated by…

Superconductivity · Physics 2015-06-29 Jasper van Wezel , Paul Nahai-Williamson , Siddarth S. Saxena

Excitonic insulators (EI) arise from the formation of bound electron-hole pairs (excitons) in semiconductors and provide a solid-state platform for quantum many-boson physics. Strong exciton-exciton repulsion is expected to stabilize…

CaBi$_2$ is a recently discovered type-I superconductor with $T_c=2$~K and a layered crystal structure. In this work electronic structure, lattice dynamics and electron-phonon interaction are studied, with a special attention paid to the…

Superconductivity · Physics 2019-04-02 Sylwia Gołąb , Bartłomiej Wiendlocha

The optical reflectivity of Pb$_{0.865}$Sn$_{0.135}$Se and Pb$_{0.75}$Sn$_{0.25}$Se solid solutions was measured in the THz spectral region energetically corresponding to bulk optical phonon excitations and in the temperature range from 40…

The crystal structure, stability, electronic and optical properties of the Ta$_2$NiSe$_5$ monolayer have been investigated using first-principles calculations in combination with the Bethe-Salpeter equation. The results show that it is…

Materials Science · Physics 2024-12-20 Miaomiao Guo , Yuanchang Li

The structural phase transition in Ta$_2$NiSe$_5$ has been envisioned as driven by the formation of an excitonic insulating phase. However, the role of structural and electronic instabilities on crystal symmetry breaking has yet to be…

Probing phonons, quasi-particle excitations and their coupling has enriched our understanding of these 2D materials and proved to be crucial for developing their potential applications. Here, we report comprehensive temperature, 4-330 K,…

Materials Science · Physics 2022-03-14 Deepu Kumar , Vivek Kumar , Rahul Kumar , Mahesh Kumar , Pradeep Kumar

Phonon properties of $\mathrm{Mo_3Sb_{7-x}Te_x}$ ($x=0,1.5, 1.7$), a potential high-temperature thermoelectric material, have been studied with inelastic neutron and x-ray scattering, and with first-principles simulations. The substitution…

Materials Science · Physics 2015-12-11 Dipanshu Bansal , Chen W. Li , Ayman H. Said , Douglas L. Abernathy , Jiaqiang Yan , Olivier Delaire