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Geometric graph neural networks (GNNs) have emerged as powerful tools for modeling molecular geometry. However, they encounter limitations in effectively capturing long-range interactions in large molecular systems. To address this…

Machine Learning · Computer Science 2024-09-27 Yusong Wang , Chaoran Cheng , Shaoning Li , Yuxuan Ren , Bin Shao , Ge Liu , Pheng-Ann Heng , Nanning Zheng

Accurate predictions of charge excitation energies of molecules in the disordered condensed phase are central to the chemical reactivity, stability, and optoelectronic properties of molecules and critically depend on the specific…

Chemical Physics · Physics 2021-08-25 Guorong Weng , Vojtech Vlcek

The work presents the detailed analysis of the water dimer properties. Their parameters are investigated on the basis of a multipole interaction potential extended up to the quadrupole--quadrupole and dipole--octupole terms. All main…

Chemical Physics · Physics 2013-05-02 P. V. Makhlaichuk , M. P. Malomuzh , I. V. Zhyganiuk

Highly accurate potential energy surfaces are of key interest for the detailed understanding and predictive modeling of chemical systems. In recent years, several new types of force fields, which are based on machine learning algorithms and…

Chemical Physics · Physics 2019-12-10 Christoph Schran , Jörg Behler , Dominik Marx

We explore different ways to simplify the evaluation of the smooth overlap of atomic positions (SOAP) many-body atomic descriptor [Bart\'{o}k et al., Phys. Rev. B 87, 184115 (2013)]. Our aim is to improve the computational efficiency of…

Computational Physics · Physics 2019-09-16 Miguel A. Caro

A common approach to modeling dispersion interactions and overcoming the inaccurate description of long-range correlation effects in electronic structure calculations is the use of pairwise-additive potentials, as in the…

Materials Science · Physics 2024-07-10 Heikki Muhli , Tapio Ala-Nissila , Miguel A. Caro

Aided by a neural network representation of the density functional theory (DFT) potential energy landscape of water in the RPBE approximation corrected for dispersion, we calculate several structural and thermodynamic properties of its…

Soft Condensed Matter · Physics 2020-10-26 Oliver Wohlfahrt , Christoph Dellago , Marcello Sega

A new empirical potential for efficient, large scale molecular dynamics simulation of water is presented. The HIPPO (Hydrogen-like Intermolecular Polarizable POtential) force field is based upon the model electron density of a hydrogen-like…

Chemical Physics · Physics 2021-09-30 Joshua A. Rackers , Roseane R. Silva , Zhi Wang , Jay W. Ponder

Water is perhaps the most simulated liquid. Recently three water models have been developed following the adaptive force matching (AFM) method that provides excellent predictions of water properties with only electronic structure…

Chemical Physics · Physics 2015-12-02 Hongyi Hu , Zhonghua Ma , Feng Wang

Machine-learning potentials (MLPs) have become important tools for modern molecular simulations. However, developing models that simultaneously achieve high accuracy and high computational efficiency remains a significant challenge. In this…

Chemical Physics · Physics 2026-02-17 Xinze Li , Ruitao Ma , Chen Qu , Dong H. Zhang , Qi Yu

A full-dimensional molecular model of water, HBB2-pol, derived entirely from first principles, is introduced and employed in computer simulations ranging from the dimer to the liquid. HBB2-pol provides excellent agreement with the measured…

Chemical Physics · Physics 2012-10-29 Volodymyr Babin , Gregory R. Medders , Francesco Paesani

Simulating interactions between non-spherical colloidal particles is computationally challenging due to the complex dependency of forces and energies on their geometry. We introduce and evaluate both descriptor-based and end-to-end models…

Soft Condensed Matter · Physics 2025-09-22 B. Rusen Argun , Antonia Statt

We derive the explicit expression of the three self-energies that one encounters in many-body perturbation theory: the well-known $GW$ self-energy, as well as the particle-particle and electron-hole $T$-matrix self-energies. Each of these…

Chemical Physics · Physics 2024-03-01 Roberto Orlando , Pina Romaniello , Pierre-François Loos

The intermolecular potential plays crucial roles in real-fluid interactions away from the ideal-gas equilibrium, such as supercritical fluid, high-enthalpy fluid, plasma interactions, etc. We propose a Boltzmann-weighted Full-dimensional…

Applied Physics · Physics 2024-04-30 Xin Zhang , Junfeng Bai , Bowen Liu , Tong Zhu , Hao Zhao

Electrolyte solutions play critical role in a vast range of important applications, yet an accurate and scalable method of predicting their properties without fitting to experiment has remained out of reach, despite over a century of…

Chemical Physics · Physics 2024-11-18 Junji Zhang , Joshua Pagotto , Tim Gould , Timothy T. Duignan

All-atom dynamics simulations are an indispensable quantitative tool in physics, chemistry, and materials science, but large systems and long simulation times remain challenging due to the trade-off between computational efficiency and…

Materials Science · Physics 2024-03-21 Stephen R. Xie , Matthias Rupp , Richard G. Hennig

Machine learning (ML) strategies are opening the door to faster computer simulations, allowing us to simulate more realistic colloidal systems. Since the interactions in colloidal systems are often highly many-body, stemming from e.g.…

Soft Condensed Matter · Physics 2026-01-09 Rinske M. Alkemade , Rastko Sknepnek , Frank Smallenburg , Laura Filion

The numerical approximation of partial differential equations (PDEs) using neural networks has seen significant advancements through Physics-Informed Neural Networks (PINNs). Despite their straightforward optimization framework and…

Machine Learning · Computer Science 2025-03-19 Namgyu Kang , Jaemin Oh , Youngjoon Hong , Eunbyung Park

A transferable potential energy function for describing the interaction between water molecules is presented. The electrostatic interaction is described rigorously using a multipole expansion. Only one expansion center is used per molecule…

Chemical Physics · Physics 2017-09-13 K. T. Wikfeldt , E. R. Batista , F. D. Vila , H Jonsson

Although a great number of computational models of water are available today, the majority of current biological simulations are done with simple models, such as TIP3P and SPC, developed almost thirty years ago and only slightly modified…

Chemical Physics · Physics 2015-05-07 Igor Leontyev , Alexei Stuchebrukhov
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