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The Bethe-Salpeter equation (BSE) is the key equation in many-body perturbation theory based on Green's functions to access response properties. Within the $GW$ approximation to the exchange-correlation kernel, the BSE has been successfully…

Chemical Physics · Physics 2023-02-15 Roberto Orlando , Pina Romaniello , Pierre-François Loos

We present an ab initio description of optical and shallow-core x-ray absorption spectroscopies in a unified formalism based on the pseudopotential plane-wave method at the level of the Bethe-Salpeter equation (BSE) within Green's functions…

Materials Science · Physics 2023-06-07 M. Laura Urquiza , Matteo Gatti , Francesco Sottile

An optical absorption spectrum constitutes one of the most fundamental material characteristics, with relevant applications ranging from material identification to energy harvesting and optoelectronics. However, the database of both…

Materials Science · Physics 2022-09-20 Ruo Xi Yang , Matthew K. Horton , Jason Munro , Kristin A. Persson

The Immersed Boundary method is a simple, efficient, and robust numerical scheme for solving PDE in general domains, yet for fluid problems it only achieves first-order spatial accuracy near embedded boundaries for the velocity field and…

Numerical Analysis · Mathematics 2017-03-08 David B. Stein , Robert D. Guy , Becca Thomases

Accurate and efficient calculation of optical response properties of solid materials is still challenging. We present a meta-generalized gradient approximation (metaGGA) density functional based time-dependent and dielectric function…

Materials Science · Physics 2024-09-10 Hong Tang , Niraj Pangeni , Adrienn Ruzsinszky

The accurate prediction of singlet and triplet excitation energies is of significant fundamental interest and is critical for many applications. An area of intense research, most calculations of singlet and triplet energies use…

Computational Physics · Physics 2017-05-22 Tonatiuh Rangel , Samia M. Hamed , Fabien Bruneval , Jeffrey B. Neaton

The combination of the many-body Green's function $GW$ approximation and the Bethe-Salpeter equation (BSE) formalism has shown to be a promising alternative to time-dependent density-functional theory (TD-DFT) for computing vertical…

Chemical Physics · Physics 2020-06-05 Pierre-François Loos , Anthony Scemama , Ivan Duchemin , Denis Jacquemin , Xavier Blase

Electrospray ion-beam deposition (ES-IBD) is a versatile tool to study structure and reactivity of molecules from small metal clusters to large protein assemblies. It brings molecules gently into the gas phase where they can be accurately…

A novel finite-element method for calculating the illumination-dependence of absorption in three-dimensional nanostructures is presented based on the RF module of the COMSOL software package. This method is capable of numerically…

Optics · Physics 2015-05-28 Mária Csete , Áron Sipos , Faraz Najafi , Xiaolong Hu , Karl K. Berggren

Accurate and fast treatment of electron-electron interactions remains a central challenge in electronic structure theory because post-Hartree-Fock methods often suffered from the computational cost for 4-index electron repulsion integrals…

Chemical Physics · Physics 2025-12-05 Yueyang Zhang , Xuewei Xiong , Wei Wu , Peifeng Su

We propose a simple many-body based screening mixing strategy to considerably enhance the performance of the Bethe-Salpeter (BS) approach for prediction of excitation energies of molecular systems. This strategy enables us to nearly…

Chemical Physics · Physics 2017-11-15 Vafa Ziaei , Thomas Bredow

Optimizing the photovoltaic efficiency of dye-sensitized solar cells (DSSC) based on staggered gap heterojunctions requires a detailed understanding of sub-band gap transitions in the visible from the dye directly to the substrate's…

Materials Science · Physics 2016-06-22 Duncan John Mowbray , Annapaola Migani

The ab initio description of the spectral interior of the absorption spectrum poses both a theoretical and computational challenge for modern electronic structure theory. Due to the often spectrally dense character of this domain in the…

Computational Engineering, Finance, and Science · Computer Science 2019-03-21 Roel Van Beeumen , David B. Williams-Young , Joseph M. Kasper , Chao Yang , Esmond G. Ng , Xiaosong Li

Electron backscatter diffraction (EBSD) has developed over the last few decades into a valuable crystallographic characterisation method for a wide range of sample types. Despite these advances, issues such as the complexity of sample…

Image and Video Processing · Electrical Eng. & Systems 2024-07-17 Zoë Broad , Alex W. Robinson , Jack Wells , Daniel Nicholls , Amirafshar Moshtaghpour , Angus I. Kirkland , Nigel D. Browning

We delineate an ab initio approach for obtaining x-ray absorption spectra as provided by many-body perturbation theory, together with its realization within an all-electron framework. Employing the Bethe-Salpeter equation, we address…

Materials Science · Physics 2017-09-08 Claudia Draxl , Caterina Cocchi

Mesoscopic numerical simulation has become an important tool in thermal management and energy harvesting at the micro/nano scale, where the Fourier's law failed. However, it is not easy to efficiently solve the phonon Boltzmann transport…

Computational Physics · Physics 2022-12-13 Chuang Zhang , Samuel Huberman , Xinliang Song , Jin Zhao , Songze Chen , Lei Wu

We present a screened exact-exchange (SXX) method for the efficient and accurate calculation of the optical properties of solids, where the screening is achieved through the zero-wavevector limit of the inverse dielectric function. The SXX…

Materials Science · Physics 2015-01-23 Zeng-hui Yang , Francesco Sottile , Carsten A. Ullrich

Bootstrap embedding (BE) is a recently developed electronic structure method that has shown great success at treating electron correlation in molecules. Here, we extend BE to treat surfaces and solids where the wave function is represented…

Strongly Correlated Electrons · Physics 2023-01-18 Oinam Romesh Meitei , Troy Van Voorhis

We examine whether essence and quantitative aspects of electronic excitation spectra are correctly captured by an effective low-energy model constructed from an {\em ab initio} downfolding scheme. A global electronic structure is first…

Strongly Correlated Electrons · Physics 2009-11-13 Kazuma Nakamura , Yoshihide Yoshimoto , Ryotaro Arita , Shinji Tsuneyuki , Masatoshi Imada

A first-principles study on the quasiparticles energy and optical absorption spectrum of fluorographene is presented by employing the GW + Bethe-Salpeter Equation (BSE) method with many-electron effects included. The calculated band gap is…

Mesoscale and Nanoscale Physics · Physics 2019-06-05 Yufeng Liang , Li Yang